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Showing 1 to 12 of 276 entries
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Preparation of Novel Pyridine-Based Aromatic Polyimides and Effect of Fluorine Functionality.

Journal of nanoscience and nanotechnology

Jang H, Lee S, Jin L, Pyo J, Tan F, Kim K, Kim W, Jeon HS.
PMID: 26726533
J Nanosci Nanotechnol. 2015 Nov;15(11):8451-9. doi: 10.1166/jnn.2015.11444.

Novel pyridine-containing linear and branched polyimides (Li-PIs and Br-PIs) were prepared by aromatic diamine and triamine monomers. The fluorinated, non-fluorinated and trifunctional pyridine-based monomers, 4-(4-(trifluoromethylphenyl))-2,6-bis(4-aminophenyl)pyridine (FDAPP), 4-phenyl-2,6-bis(4-aminophenyl)pyridine (DAPP) and 4,4',4"-(pyridine-2,4,6-triyl)tribenzenamine (TAPP) amino compounds were synthesized by a modified Chichibabin...

Cooperative organocatalysis of Mukaiyama-type aldol reactions by thioureas and nitro compounds.

Chemical communications (Cambridge, England)

Bukhryakov KV, Desyatkin VG, Rodionov VO.
PMID: 27216276
Chem Commun (Camb). 2016 Jun 18;52(48):7576-9. doi: 10.1039/c6cc01984f. Epub 2016 May 24.

A unique organocatalytic system for Mukaiyama-type aldol reactions based on the cooperative action of nitro compounds and thioureas has been identified. This system is compatible with a wide range of substrates and does not require low temperatures, inert atmospheres,...

Steric-Hindrance-Induced Regio- and Chemoselective Oxidation of Aromatic Amines.

The Journal of organic chemistry

Patil VV, Shankarling GS.
PMID: 26212905
J Org Chem. 2015 Aug 21;80(16):7876-83. doi: 10.1021/acs.joc.5b00582. Epub 2015 Aug 03.

Unusual regio- and chemoselective oxidation of aromatic amines hindered with ortho substituents (except -NH2, -NHCH3, and -OH) to the corresponding nitro compounds is described by use of nonanebis(peroxoic acid). The mechanistic investigation for selective oxidation of amines ortho-substituted with...

Electrochemical construction of hierarchically ordered CdSe-sensitized TiO2 nanotube arrays: towards versatile photoelectrochemical water splitting and photoredox applications.

Nanoscale

Xiao FX, Miao J, Wang HY, Yang H, Chen J, Liu B.
PMID: 24821322
Nanoscale. 2014 Jun 21;6(12):6727-37. doi: 10.1039/c4nr01380h.

Recent years have witnessed quite a number of worldwide efforts for fabricating CdSe/TiO2 nanotube arrays (CdSe/TNTAs) nanocomposites; however, the construction of a well-defined CdSe/TNTAs binary nanostructure for versatile photocatalytic and photoelectrochemical applications still poses a big challenge. In this...

CHARMM Force Field Parameters for Nitroalkanes and Nitroarenes.

Journal of chemical theory and computation

Klauda JB, Brooks BR.
PMID: 26619984
J Chem Theory Comput. 2008 Jan;4(1):107-15. doi: 10.1021/ct700191v.

New CHARMM force field (FF) parameters are developed for nitro compounds, referred to here as C27rn, for subsequent use in molecular dynamics (MD) simulations. The nonbonded terms are adjusted to best fit densities and hydration energies of nitropropane and...

From Umpolung to Alternation: Modified Reactivity of Donor-Acceptor Cyclopropanes Towards Nucleophiles in Reaction with Nitroalkanes.

Chemistry (Weinheim an der Bergstrasse, Germany)

Budynina EM, Ivanov KL, Chagarovskiy AO, Rybakov VB, Trushkov IV, Melnikov MY.
PMID: 26880270
Chemistry. 2016 Mar 07;22(11):3692-6. doi: 10.1002/chem.201504593. Epub 2016 Feb 16.

A conceptually new type of donor-acceptor cyclopropane reactivity towards nucleophiles has been disclosed. An essential characteristic of the process is an unusual nucleophilic attack on the C(3)-position of a cyclopropane, combined with typical small ring-opening by cleavage of the...

Correction to "A New Approach to Nitrones through Cascade Reaction of Nitro Compounds Enabled by Visible Light Photoredox Catalysis".

Organic letters

Lin CW, Hong BC, Chang WC, Lee GH.
PMID: 26075499
Org Lett. 2015 Jul 02;17(13):3378. doi: 10.1021/acs.orglett.5b01663. Epub 2015 Jun 15.

No abstract available.

Correlations between theoretical and experimental determination of heat of formation of certain aromatic nitro compounds.

Computers & chemistry

Chen C, Wu JC.
PMID: 11219427
Comput Chem. 2001 Mar;25(2):117-24. doi: 10.1016/s0097-8485(00)00073-5.

Heats of formation of energetic materials can be obtained either experimentally or theoretically. In order to compare the results of the two methods, some correlation methods were proposed in this study. The molecular structures and heats of formation of...

Novel transformations of gamma-silyl nitro compounds.

Organic letters

Hwu JR, Sambaiah T, Liao JH, Chen KL, Wen YS.
PMID: 11784194
Org Lett. 2001 Dec 27;3(26):4267-9. doi: 10.1021/ol010237f.

Introduction of a gamma-silyl group into nitro compounds of dihydrobenzofuran, dihydrobenzo[b]thiophene, and dihydrofuran allowed new transformations to take place in the presence of a Lewis acid to give the corresponding alpha,beta-unsaturated oximes or multisubstituted dihydrofurans, respectively, in good to...

(n-Nitrophenyl)acetonitrile, with n = 2, 3 and 4.

Acta crystallographica. Section C, Crystal structure communications

Boitsov S, Songstad J, Törnroos KW.
PMID: 12154320
Acta Crystallogr C. 2002 Aug;58:o528-32. doi: 10.1107/s0108270102011514. Epub 2002 Jul 31.

The molecular structures of the three title nitro-substituted phenylacetonitriles, C(8)H(6)N(2)O(2), at 123 K show that the molecules are linked together very differently. In the 2- and 4-nitro compounds, there are both O...H and N(cyano)...H interactions, whereas the crystal lattice...

Catalytic enantioselective addition of indoles to arylnitroalkenes: an effective route to enantiomerically enriched tryptamine precursors.

Chirality

Bandini M, Garelli A, Rovinetti M, Tommasi S, Umani-Ronchi A.
PMID: 16170793
Chirality. 2005 Nov;17(9):522-9. doi: 10.1002/chir.20189.

A new valuable catalytic protocol for the preparation of synthetically useful beta-indolyl nitro compounds bearing benzhydryl stereocenters is presented. The combined use of catalytic amounts of a commercially available chiral [SalenAlCl] complex and pyridine allowed, for the Friedel-Crafts alkylation...

[Not Available].

Talanta

Bartos J.
PMID: 18961602
Talanta. 1974 Dec;21(12):1303-4. doi: 10.1016/0039-9140(74)80154-2.

Aromatic nitro compounds are reduced to aromatic amines by iron(II) in alkaline medium. The dye obtained by reacting the amine with 1,2-naphthoquinone-4-sulphonic acid is extractable into methylene chloride. Reduction by potassium borohydride yields a fluorescent o-diphenol, thus allowing the...

Showing 1 to 12 of 276 entries