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Showing 1 to 12 of 153 entries
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Enantiomeric separations of chiral sulfonic and phosphoric acids with barium-doped cyclofructan selectors via an ion interaction mechanism.

Analytical chemistry

Smuts JP, Hao XQ, Han Z, Parpia C, Krische MJ, Armstrong DW.
PMID: 24372088
Anal Chem. 2014 Jan 21;86(2):1282-90. doi: 10.1021/ac403686a. Epub 2013 Dec 27.

New cyclofructan-6 (CF6)-based chiral stationary phases (CSPs) bind barium cations. As a result, the barium-complexed CSPs exhibit enantioselectivity toward 16 chiral phosphoric and sulfonic acids in the polar organic mode (e.g., methanol or ethanol mobile phase containing a barium...

Redox regulation by reversible protein S-thiolation in bacteria.

Frontiers in microbiology

Loi VV, Rossius M, Antelmann H.
PMID: 25852656
Front Microbiol. 2015 Mar 16;6:187. doi: 10.3389/fmicb.2015.00187. eCollection 2015.

Low molecular weight (LMW) thiols function as thiol-redox buffers to maintain the reduced state of the cytoplasm. The best studied LMW thiol is the tripeptide glutathione (GSH) present in all eukaryotes and Gram-negative bacteria. Firmicutes bacteria, including Bacillus and...

Supported Sulfonic Acids: Solid Catalysts for Batch and Continuous-Flow Synthetic Processes.

ChemistryOpen

Piscopo CG.
PMID: 26247001
ChemistryOpen. 2015 Jun;4(3):383-8. doi: 10.1002/open.201402148. Epub 2015 Jan 16.

No abstract available.

Calixarene assembly with enhanced photocurrents using P(SNS-NH2)/CdS nanoparticle structure modified Au electrode systems.

Physical chemistry chemical physics : PCCP

Sayin S, Azak H, Yildiz HB, Camurlu P, Akkus GU, Toppare L, Ersoz M.
PMID: 26166614
Phys Chem Chem Phys. 2015 Aug 14;17(30):19911-8. doi: 10.1039/c5cp01932j. Epub 2015 Jul 13.

Two novel calix[n]arene-adorned gold electrodes producing high photocurrent intensities were successfully constructed by embedding gold electrode surfaces with both P(4-(2,5-di(thiophen-2-yl)-1H-pyrrol-1-yl)benzenamine) conducting polymer and 4-mercaptoboronic acid-functionalized semiconductor CdS nanoparticles to facilitate the binding of calix[n]arene sulfonic acids with nanoparticles. This...

Hydrophobic, low-loading and alkylated polystyrene-supported sulfonic acid for several organic reactions in water: remarkable effects of both the polymer structures and loading levels of sulfonic acids.

Organic & biomolecular chemistry

Iimura S, Manabe K, Kobayashi S.
PMID: 12956054
Org Biomol Chem. 2003 Jul 21;1(14):2416-8. doi: 10.1039/b305622h.

A hydrophobic, low-loading and alkylated polystyrene-supported sulfonic acid (LL-ALPS-SO3H) has been developed for several organic reactions such as the hydrolysis of thioesters, the deprotection of acetals and an acetonide, and the hydration of an epoxide and an alkyne in...

Hydrogen bonding in proton-transfer compounds of 8-quinolinol (oxine) with aromatic sulfonic acids.

Acta crystallographica. Section C, Crystal structure communications

Smith G, Wermuth UD, Healy PC.
PMID: 15295198
Acta Crystallogr C. 2004 Aug;60:o600-3. doi: 10.1107/S0108270104015057. Epub 2004 Jul 31.

No abstract available.

Determination of electroinactive organic acids with LC and amperometric detection, using a PPy coated electrode.

Talanta

Staes E, Nagels LJ.
PMID: 18967986
Talanta. 2000 Jun 21;52(2):277-84. doi: 10.1016/s0039-9140(00)00329-5.

This paper reports on the amperometric detection of electroinactive sulfonic acids, organic acids and phosphate esters subsequent to chromatographic separation. The working electrode consisted of a 3 mm diameter glassy carbon electrode, coated with electrochemically deposited polypyrrole. The electrode...

Electrospray ionization tandem mass spectrometric study of three isomeric substituted aromatic sulfonic acids; differentiation via ortho effects.

Rapid communications in mass spectrometry : RCM

Nagi Reddy P, Srikanth R, Venkateswarlu N, Nageswara Rao R, Srinivas R.
PMID: 15570575
Rapid Commun Mass Spectrom. 2005;19(1):72-6. doi: 10.1002/rcm.1743.

No abstract available.

Significant enhancement on selectivity in silica supported sulfonic acids catalyzed reactions.

Chemical communications (Cambridge, England)

Karam A, Gu Y, Jérôme F, Douliez JP, Barrault J.
PMID: 17534497
Chem Commun (Camb). 2007 Jun 14;(22):2222-4. doi: 10.1039/b702997g. Epub 2007 Apr 05.

Thanks to strong hydrophilic interactions between reaction products and the catalyst surface, mesoporous silica supported sulfonic sites were found to be much more selective than homogeneous and common solid acid catalysts.

The effects of chemical substitution and polymerization on the pKa values of sulfonic acids.

The journal of physical chemistry. B

Dong H, Du H, Wickramasinghe SR, Qian X.
PMID: 19780534
J Phys Chem B. 2009 Oct 29;113(43):14094-101. doi: 10.1021/jp906087c.

The effects of ring substitution on the pK(a) value of benzenesulfonic acid (BSA) were investigated using a combined quantum mechanical and classical approach. Ring substitution with strong electron-withdrawing elements such as F, Cl, and Br is found to enhance...

THE COMBINATION OF DIVALENT MANGANESE WITH CERTAIN PROTEINS, AMINO ACIDS, AND RELATED COMPOUNDS.

The Journal of general physiology

Main RK, Schmidt CL.
PMID: 19872906
J Gen Physiol. 1935 Sep 20;19(1):127-47. doi: 10.1085/jgp.19.1.127.

1. A study of the mode of combination which takes place between certain amino acids, proteins, various carboxylic acids, and certain sulfonic acids and manganous ions to form complexes is reported. 2. Three criteria for complex formation were used:...

Dynamics and lithium binding energies of polyelectrolytes based on functionalized poly(para-phenylene terephthalamide).

The journal of physical chemistry. B

Grozema FC, Best AS, van Eijck L, Stride J, Kearley GJ, de Leeuw SW, Picken SJ.
PMID: 16851895
J Phys Chem B. 2005 Apr 28;109(16):7705-12. doi: 10.1021/jp044453s.

Polyelectrolyte materials are an interesting class of electrolytes for use in fuel cell and battery applications. Poly(para-phenylene terephthalamide) (PPTA, Kevlar) is a liquid crystalline polymer that, when sulfonated, is a polyelectrolyte that exhibits moderate ion conductivity at elevated temperatures....

Showing 1 to 12 of 153 entries