Advanced Search
Display options
Filter resources
Text Availability
Article type
Publication date
Species
Language
Sex
Age
Showing 1 to 12 of 56 entries
Sorted by: Best Match Show Resources per page
Aromatization of enamines promoted by a stoichiometric amount of palladium(II) salts: a novel method for the synthesis of aromatic amines.

The Journal of organic chemistry

Ishikawa T, Uedo E, Tani R, Saito S.
PMID: 11429898
J Org Chem. 2001 Jan 12;66(1):186-91. doi: 10.1021/jo001331x.

Enamines (1a-r) prepared from cyclohexanones, cyclohexane-1,3-diones, or tetralones led to arylamines (2a-r) in one pot when treated with a stoichiometric amount of palladium salts [PdCl2-(MeCN)2] in acetonitrile in the presence of triethylamine at room temperature or at elevated temperature,...

Cite
Ishikawa T, Uedo E, Tani R, et al. Aromatization of enamines promoted by a stoichiometric amount of palladium(II) salts: a novel method for the synthesis of aromatic amines. J Org Chem. 2001;66(1):186-91doi: 10.1021/jo001331x.
Ishikawa, T., Uedo, E., Tani, R., & Saito, S. (2001). Aromatization of enamines promoted by a stoichiometric amount of palladium(II) salts: a novel method for the synthesis of aromatic amines. The Journal of organic chemistry, 66(1), 186-91. https://doi.org/10.1021/jo001331x
Ishikawa, T, et al. "Aromatization of enamines promoted by a stoichiometric amount of palladium(II) salts: a novel method for the synthesis of aromatic amines." The Journal of organic chemistry vol. 66,1 (2001): 186-91. doi: https://doi.org/10.1021/jo001331x
Ishikawa T, Uedo E, Tani R, Saito S. Aromatization of enamines promoted by a stoichiometric amount of palladium(II) salts: a novel method for the synthesis of aromatic amines. J Org Chem. 2001 Jan 12;66(1):186-91. doi: 10.1021/jo001331x. PMID: 11429898.
Copy Download .nbib Format: NLM
alpha-Nitration of Ketones via Enol Silyl Ethers. Radical Cations as Reactive Intermediates in Thermal and Photochemical Processes.

The Journal of organic chemistry

Rathore R, Kochi JK.
PMID: 11666984
J Org Chem. 1996 Jan 26;61(2):627-639. doi: 10.1021/jo9515687.

Highly colored (red) solutions of various enol silyl ethers and tetranitromethane (TNM) are readily bleached to afford good yields of alpha-nitro ketones in the dark at room temperature or below. Spectral analysis show the red colors to be associated...

Cite
Rathore R, Kochi JK. alpha-Nitration of Ketones via Enol Silyl Ethers. Radical Cations as Reactive Intermediates in Thermal and Photochemical Processes. J Org Chem. 1996;61(2):627-639doi: 10.1021/jo9515687.
Rathore, R., & Kochi, J. K. (1996). alpha-Nitration of Ketones via Enol Silyl Ethers. Radical Cations as Reactive Intermediates in Thermal and Photochemical Processes. The Journal of organic chemistry, 61(2), 627-639. https://doi.org/10.1021/jo9515687
Rathore, Rajendra, and Kochi, Jay K.. "alpha-Nitration of Ketones via Enol Silyl Ethers. Radical Cations as Reactive Intermediates in Thermal and Photochemical Processes." The Journal of organic chemistry vol. 61,2 (1996): 627-639. doi: https://doi.org/10.1021/jo9515687
Rathore R, Kochi JK. alpha-Nitration of Ketones via Enol Silyl Ethers. Radical Cations as Reactive Intermediates in Thermal and Photochemical Processes. J Org Chem. 1996 Jan 26;61(2):627-639. doi: 10.1021/jo9515687. PMID: 11666984.
Copy Download .nbib Format: NLM
Air Oxidation of 2-Aryl-1-tetralones in Basic, Neutral, and Acidic Media: An Unprecedented Oxidative Aryl Migration to 2-Aryloxy-1-naphthols under Acidic Condition.

The Journal of organic chemistry

Ishikawa T, Hino K, Yoneda T, Murota M, Yamaguchi K, Watanabe T.
PMID: 11674642
J Org Chem. 1999 Jul 23;64(15):5691-5695. doi: 10.1021/jo9824854.

No abstract available.

Cite
Ishikawa T, Hino K, Yoneda T, et al. Air Oxidation of 2-Aryl-1-tetralones in Basic, Neutral, and Acidic Media: An Unprecedented Oxidative Aryl Migration to 2-Aryloxy-1-naphthols under Acidic Condition. J Org Chem. 1999;64(15):5691-5695doi: 10.1021/jo9824854.
Ishikawa, T., Hino, K., Yoneda, T., Murota, M., Yamaguchi, K., & Watanabe, T. (1999). Air Oxidation of 2-Aryl-1-tetralones in Basic, Neutral, and Acidic Media: An Unprecedented Oxidative Aryl Migration to 2-Aryloxy-1-naphthols under Acidic Condition. The Journal of organic chemistry, 64(15), 5691-5695. https://doi.org/10.1021/jo9824854
Ishikawa, Tsutomu, et al. "Air Oxidation of 2-Aryl-1-tetralones in Basic, Neutral, and Acidic Media: An Unprecedented Oxidative Aryl Migration to 2-Aryloxy-1-naphthols under Acidic Condition." The Journal of organic chemistry vol. 64,15 (1999): 5691-5695. doi: https://doi.org/10.1021/jo9824854
Ishikawa T, Hino K, Yoneda T, Murota M, Yamaguchi K, Watanabe T. Air Oxidation of 2-Aryl-1-tetralones in Basic, Neutral, and Acidic Media: An Unprecedented Oxidative Aryl Migration to 2-Aryloxy-1-naphthols under Acidic Condition. J Org Chem. 1999 Jul 23;64(15):5691-5695. doi: 10.1021/jo9824854. PMID: 11674642.
Copy Download .nbib Format: NLM
Rh-catalyzed [4 + 2] carbocyclization of vinylarylaldehydes with alkenes and alkynes leading to substituted tetralones and 1-naphthols.

Organic letters

Tanaka K, Hojo D, Shoji T, Hagiwara Y, Hirano M.
PMID: 17458973
Org Lett. 2007 May 24;9(11):2059-62. doi: 10.1021/ol0704587. Epub 2007 Apr 26.

Regio-, diastereo-, and enantioselective intermolecular [4 + 2] carbocyclizations of vinylarylaldehydes with alkenes and alkynes leading to substituted tetralones and 1-naphthols have been developed by using a cationic rhodium(I)/dppb or dppp complex as a catalyst.

Cite
Tanaka K, Hojo D, Shoji T, et al. Rh-catalyzed [4 + 2] carbocyclization of vinylarylaldehydes with alkenes and alkynes leading to substituted tetralones and 1-naphthols. Org Lett. 2007;9(11):2059-62doi: 10.1021/ol0704587.
Tanaka, K., Hojo, D., Shoji, T., Hagiwara, Y., & Hirano, M. (2007). Rh-catalyzed [4 + 2] carbocyclization of vinylarylaldehydes with alkenes and alkynes leading to substituted tetralones and 1-naphthols. Organic letters, 9(11), 2059-62. https://doi.org/10.1021/ol0704587
Tanaka, Ken, et al. "Rh-catalyzed [4 + 2] carbocyclization of vinylarylaldehydes with alkenes and alkynes leading to substituted tetralones and 1-naphthols." Organic letters vol. 9,11 (2007): 2059-62. doi: https://doi.org/10.1021/ol0704587
Tanaka K, Hojo D, Shoji T, Hagiwara Y, Hirano M. Rh-catalyzed [4 + 2] carbocyclization of vinylarylaldehydes with alkenes and alkynes leading to substituted tetralones and 1-naphthols. Org Lett. 2007 May 24;9(11):2059-62. doi: 10.1021/ol0704587. Epub 2007 Apr 26. PMID: 17458973.
Copy Download .nbib Format: NLM
A RuH(2)(CO)(PPh(3))(3)-catalyzed regioselective arylation of aromatic ketones with arylboronates via carbon-hydrogen bond cleavage.

Journal of the American Chemical Society

Kakiuchi F, Matsuura Y, Kan S, Chatani N.
PMID: 15839693
J Am Chem Soc. 2005 Apr 27;127(16):5936-45. doi: 10.1021/ja043334n.

When the reaction of aromatic ketones with arylboronates (arylboronic acid esters) using RuH(2)(CO)(PPh(3))(3) (3) as a catalyst was conducted in toluene, the corresponding arylation product was obtained in moderate yields. In this case, a nearly equivalent amount of a...

Cite
Kakiuchi F, Matsuura Y, Kan S, et al. A RuH(2)(CO)(PPh(3))(3)-catalyzed regioselective arylation of aromatic ketones with arylboronates via carbon-hydrogen bond cleavage. J Am Chem Soc. 2005;127(16):5936-45doi: 10.1021/ja043334n.
Kakiuchi, F., Matsuura, Y., Kan, S., & Chatani, N. (2005). A RuH(2)(CO)(PPh(3))(3)-catalyzed regioselective arylation of aromatic ketones with arylboronates via carbon-hydrogen bond cleavage. Journal of the American Chemical Society, 127(16), 5936-45. https://doi.org/10.1021/ja043334n
Kakiuchi, Fumitoshi, et al. "A RuH(2)(CO)(PPh(3))(3)-catalyzed regioselective arylation of aromatic ketones with arylboronates via carbon-hydrogen bond cleavage." Journal of the American Chemical Society vol. 127,16 (2005): 5936-45. doi: https://doi.org/10.1021/ja043334n
Kakiuchi F, Matsuura Y, Kan S, Chatani N. A RuH(2)(CO)(PPh(3))(3)-catalyzed regioselective arylation of aromatic ketones with arylboronates via carbon-hydrogen bond cleavage. J Am Chem Soc. 2005 Apr 27;127(16):5936-45. doi: 10.1021/ja043334n. PMID: 15839693.
Copy Download .nbib Format: NLM
CO-trapping reaction under thermolysis of alkoxyamines: application to the synthesis of 3,4-cyclopenta-1-tetralones.

Organic letters

Uenoyama Y, Tsukida M, Doi T, Ryu I, Studer A.
PMID: 15987186
Org Lett. 2005 Jul 07;7(14):2985-8. doi: 10.1021/ol050951n.

[reaction: see text] An efficient one-pot sequence comprising a PRE-mediated radical 5-exo-cyclization, a radical carbonylation, a nitroxide trapping reaction, and a subsequent acid-catalyzed Friedel-Craft-type acylation provides a new entry into 3,4-cyclopenta-1-tetralones. Eight examples are presented.

Cite
Uenoyama Y, Tsukida M, Doi T, et al. CO-trapping reaction under thermolysis of alkoxyamines: application to the synthesis of 3,4-cyclopenta-1-tetralones. Org Lett. 2005;7(14):2985-8doi: 10.1021/ol050951n.
Uenoyama, Y., Tsukida, M., Doi, T., Ryu, I., & Studer, A. (2005). CO-trapping reaction under thermolysis of alkoxyamines: application to the synthesis of 3,4-cyclopenta-1-tetralones. Organic letters, 7(14), 2985-8. https://doi.org/10.1021/ol050951n
Uenoyama, Yoshitaka, et al. "CO-trapping reaction under thermolysis of alkoxyamines: application to the synthesis of 3,4-cyclopenta-1-tetralones." Organic letters vol. 7,14 (2005): 2985-8. doi: https://doi.org/10.1021/ol050951n
Uenoyama Y, Tsukida M, Doi T, Ryu I, Studer A. CO-trapping reaction under thermolysis of alkoxyamines: application to the synthesis of 3,4-cyclopenta-1-tetralones. Org Lett. 2005 Jul 07;7(14):2985-8. doi: 10.1021/ol050951n. PMID: 15987186.
Copy Download .nbib Format: NLM
Mechanistic studies on the CAN-mediated intramolecular cyclization of δ-aryl-β-dicarbonyl compounds.

Beilstein journal of organic chemistry

Casey BM, Sadasivam DV, Flowers Ii RA.
PMID: 23946845
Beilstein J Org Chem. 2013 Jul 23;9:1472-9. doi: 10.3762/bjoc.9.167. eCollection 2013.

The synthesis of 2-tetralones through the cyclization of δ-aryl-β-dicarbonyl substrates by using CAN is described. Appropriately functionalized aromatic substrates undergo intramolecular cyclizations generating 2-tetralone derivatives in moderate to good yields. DFT computational studies indicate that successful formation of 2-tetralones...

Cite
Casey BM, Sadasivam DV, Flowers Ii RA. Mechanistic studies on the CAN-mediated intramolecular cyclization of δ-aryl-β-dicarbonyl compounds. Beilstein J Org Chem. 2013;9:1472-9doi: 10.3762/bjoc.9.167.
Casey, B. M., Sadasivam, D. V., & Flowers Ii, R. A. (2013). Mechanistic studies on the CAN-mediated intramolecular cyclization of δ-aryl-β-dicarbonyl compounds. Beilstein journal of organic chemistry, 91472-9. https://doi.org/10.3762/bjoc.9.167
Casey, Brian M, et al. "Mechanistic studies on the CAN-mediated intramolecular cyclization of δ-aryl-β-dicarbonyl compounds." Beilstein journal of organic chemistry vol. 9 (2013): 1472-9. doi: https://doi.org/10.3762/bjoc.9.167
Casey BM, Sadasivam DV, Flowers Ii RA. Mechanistic studies on the CAN-mediated intramolecular cyclization of δ-aryl-β-dicarbonyl compounds. Beilstein J Org Chem. 2013 Jul 23;9:1472-9. doi: 10.3762/bjoc.9.167. eCollection 2013. PMID: 23946845; PMCID: PMC3740710.
Copy Download .nbib Format: NLM
Tandem Oxidative Ring-Opening/Cyclization Reaction in Seconds in Open Atmosphere for the Synthesis of 1-Tetralones in Water-Acetonitrile.

Organic letters

Fang J, Li L, Yang C, Chen J, Deng GJ, Gong H.
PMID: 30398881
Org Lett. 2018 Nov 16;20(22):7308-7311. doi: 10.1021/acs.orglett.8b03246. Epub 2018 Nov 06.

A mild and practical tandem oxidative ring-opening/cyclization reaction mediated by Ce

Cite
Fang J, Li L, Yang C, et al. Tandem Oxidative Ring-Opening/Cyclization Reaction in Seconds in Open Atmosphere for the Synthesis of 1-Tetralones in Water-Acetonitrile. Org Lett. 2018;20(22):7308-7311doi: 10.1021/acs.orglett.8b03246.
Fang, J., Li, L., Yang, C., Chen, J., Deng, G. J., & Gong, H. (2018). Tandem Oxidative Ring-Opening/Cyclization Reaction in Seconds in Open Atmosphere for the Synthesis of 1-Tetralones in Water-Acetonitrile. Organic letters, 20(22), 7308-7311. https://doi.org/10.1021/acs.orglett.8b03246
Fang, Jingxian, et al. "Tandem Oxidative Ring-Opening/Cyclization Reaction in Seconds in Open Atmosphere for the Synthesis of 1-Tetralones in Water-Acetonitrile." Organic letters vol. 20,22 (2018): 7308-7311. doi: https://doi.org/10.1021/acs.orglett.8b03246
Fang J, Li L, Yang C, Chen J, Deng GJ, Gong H. Tandem Oxidative Ring-Opening/Cyclization Reaction in Seconds in Open Atmosphere for the Synthesis of 1-Tetralones in Water-Acetonitrile. Org Lett. 2018 Nov 16;20(22):7308-7311. doi: 10.1021/acs.orglett.8b03246. Epub 2018 Nov 06. PMID: 30398881.
Copy Download .nbib Format: NLM
Bifunctional Brønsted Base Catalyst Enables Regio-, Diastereo-, and Enantioselective C.

Angewandte Chemie (International ed. in English)

Urruzuno I, Mugica O, Oiarbide M, Palomo C.
PMID: 28097751
Angew Chem Int Ed Engl. 2017 Feb 13;56(8):2059-2063. doi: 10.1002/anie.201612332. Epub 2017 Jan 18.

The catalytic asymmetric synthesis of both α-substituted and α,α-disubstituted (quaternary) β-tetralones through direct α-functionalization of the corresponding β-tetralone precursor remains elusive. A designed Brønsted base-squaramide bifunctional catalyst promotes the conjugate addition of either unsubstituted or α-monosubstituted β-tetralones to nitroalkenes....

Cite
Urruzuno I, Mugica O, Oiarbide M, et al. Bifunctional Brønsted Base Catalyst Enables Regio-, Diastereo-, and Enantioselective C. Angew Chem Int Ed Engl. 2017;56(8):2059-2063doi: 10.1002/anie.201612332.
Urruzuno, I., Mugica, O., Oiarbide, M., & Palomo, C. (2017). Bifunctional Brønsted Base Catalyst Enables Regio-, Diastereo-, and Enantioselective C. Angewandte Chemie (International ed. in English), 56(8), 2059-2063. https://doi.org/10.1002/anie.201612332
Urruzuno, Iñaki, et al. "Bifunctional Brønsted Base Catalyst Enables Regio-, Diastereo-, and Enantioselective C." Angewandte Chemie (International ed. in English) vol. 56,8 (2017): 2059-2063. doi: https://doi.org/10.1002/anie.201612332
Urruzuno I, Mugica O, Oiarbide M, Palomo C. Bifunctional Brønsted Base Catalyst Enables Regio-, Diastereo-, and Enantioselective C. Angew Chem Int Ed Engl. 2017 Feb 13;56(8):2059-2063. doi: 10.1002/anie.201612332. Epub 2017 Jan 18. PMID: 28097751.
Copy Download .nbib Format: NLM
Tandem Pummerer-Diels-Alder Reaction Sequence. A Novel Cascade Process for the Preparation of 1-Arylnaphthalene Lignans.

The Journal of organic chemistry

Padwa A, Cochran JE, Kappe CO.
PMID: 11667219
J Org Chem. 1996 May 31;61(11):3706-3714. doi: 10.1021/jo960295s.

The alpha-thiocarbocation generated from the Pummerer reaction of an o-benzoyl-substituted sulfoxide is intercepted by the adjacent keto group to produce an alpha-thio isobenzofuran as a transient intermediate which undergoes a subsequent Diels-Alder cycloaddition with added dienophiles. Acid-catalyzed ring-opening of...

Cite
Padwa A, Cochran JE, Kappe CO. Tandem Pummerer-Diels-Alder Reaction Sequence. A Novel Cascade Process for the Preparation of 1-Arylnaphthalene Lignans. J Org Chem. 1996;61(11):3706-3714doi: 10.1021/jo960295s.
Padwa, A., Cochran, J. E., & Kappe, C. O. (1996). Tandem Pummerer-Diels-Alder Reaction Sequence. A Novel Cascade Process for the Preparation of 1-Arylnaphthalene Lignans. The Journal of organic chemistry, 61(11), 3706-3714. https://doi.org/10.1021/jo960295s
Padwa, Albert, et al. "Tandem Pummerer-Diels-Alder Reaction Sequence. A Novel Cascade Process for the Preparation of 1-Arylnaphthalene Lignans." The Journal of organic chemistry vol. 61,11 (1996): 3706-3714. doi: https://doi.org/10.1021/jo960295s
Padwa A, Cochran JE, Kappe CO. Tandem Pummerer-Diels-Alder Reaction Sequence. A Novel Cascade Process for the Preparation of 1-Arylnaphthalene Lignans. J Org Chem. 1996 May 31;61(11):3706-3714. doi: 10.1021/jo960295s. PMID: 11667219.
Copy Download .nbib Format: NLM
Carbopalladation of nitriles: synthesis of benzocyclic ketones and cyclopentenones via Pd-catalyzed cyclization of omega-(2-iodoaryl)alkanenitriles and related compounds.

The Journal of organic chemistry

Pletnev AA, Larock RC.
PMID: 12492349
J Org Chem. 2002 Dec 27;67(26):9428-38. doi: 10.1021/jo0262006.

An efficient procedure for the synthesis of 2,2-disubstituted benzocyclic ketones by intramolecular carbopalladation of nitriles has been developed. The cyclization of substituted 3-(2-iodoaryl)propanenitriles affords indanones in high yields. The reaction is compatible with a wide variety of functional groups....

Cite
Pletnev AA, Larock RC. Carbopalladation of nitriles: synthesis of benzocyclic ketones and cyclopentenones via Pd-catalyzed cyclization of omega-(2-iodoaryl)alkanenitriles and related compounds. J Org Chem. 2002;67(26):9428-38doi: 10.1021/jo0262006.
Pletnev, A. A., & Larock, R. C. (2002). Carbopalladation of nitriles: synthesis of benzocyclic ketones and cyclopentenones via Pd-catalyzed cyclization of omega-(2-iodoaryl)alkanenitriles and related compounds. The Journal of organic chemistry, 67(26), 9428-38. https://doi.org/10.1021/jo0262006
Pletnev, Alexandre A, and Larock, Richard C. "Carbopalladation of nitriles: synthesis of benzocyclic ketones and cyclopentenones via Pd-catalyzed cyclization of omega-(2-iodoaryl)alkanenitriles and related compounds." The Journal of organic chemistry vol. 67,26 (2002): 9428-38. doi: https://doi.org/10.1021/jo0262006
Pletnev AA, Larock RC. Carbopalladation of nitriles: synthesis of benzocyclic ketones and cyclopentenones via Pd-catalyzed cyclization of omega-(2-iodoaryl)alkanenitriles and related compounds. J Org Chem. 2002 Dec 27;67(26):9428-38. doi: 10.1021/jo0262006. PMID: 12492349.
Copy Download .nbib Format: NLM
α-Arylation and Ring Expansion of Annulated Cyclobutanones: Stereoselective Synthesis of Functionalized Tetralones.

Angewandte Chemie (International ed. in English)

Chang S, Holmes M, Mowat J, Meanwell M, Britton R.
PMID: 27976511
Angew Chem Int Ed Engl. 2017 Jan 16;56(3):748-752. doi: 10.1002/anie.201608449. Epub 2016 Dec 15.

α-Arylcyclobutanones display unique reactivity that makes them valuable synthetic intermediates and target molecules. We describe the preparation of α-aryl- and α-heteroarylcyclobutanones through a direct α-arylation reaction. Problematic fragmentations are avoided by the use of LiO

Cite
Chang S, Holmes M, Mowat J, et al. α-Arylation and Ring Expansion of Annulated Cyclobutanones: Stereoselective Synthesis of Functionalized Tetralones. Angew Chem Int Ed Engl. 2016;56(3):748-752doi: 10.1002/anie.201608449.
Chang, S., Holmes, M., Mowat, J., Meanwell, M., & Britton, R. (2017). α-Arylation and Ring Expansion of Annulated Cyclobutanones: Stereoselective Synthesis of Functionalized Tetralones. Angewandte Chemie (International ed. in English), 56(3), 748-752. https://doi.org/10.1002/anie.201608449
Chang, Stanley, et al. "α-Arylation and Ring Expansion of Annulated Cyclobutanones: Stereoselective Synthesis of Functionalized Tetralones." Angewandte Chemie (International ed. in English) vol. 56,3 (2017): 748-752. doi: https://doi.org/10.1002/anie.201608449
Chang S, Holmes M, Mowat J, Meanwell M, Britton R. α-Arylation and Ring Expansion of Annulated Cyclobutanones: Stereoselective Synthesis of Functionalized Tetralones. Angew Chem Int Ed Engl. 2017 Jan 16;56(3):748-752. doi: 10.1002/anie.201608449. Epub 2016 Dec 15. PMID: 27976511.
Copy Download .nbib Format: NLM
Showing 1 to 12 of 56 entries