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Cotton FA, Lin C, Murillo CA. Connecting pairs of dimetal units to form molecular loops. Inorg Chem. 2001;40(3):472-7doi: 10.1021/ic0010151.
Cotton, F. A., Lin, C., & Murillo, C. A. (2001). Connecting pairs of dimetal units to form molecular loops. Inorganic chemistry, 40(3), 472-7. https://doi.org/10.1021/ic0010151
Cotton, F A, et al. "Connecting pairs of dimetal units to form molecular loops." Inorganic chemistry vol. 40,3 (2001): 472-7. doi: https://doi.org/10.1021/ic0010151
Cotton FA, Lin C, Murillo CA. Connecting pairs of dimetal units to form molecular loops. Inorg Chem. 2001 Jan 29;40(3):472-7. doi: 10.1021/ic0010151. PMID: 11209603.
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Inorg Chem. 2001 Jan 29;40(3):472-7. doi: 10.1021/ic0010151.

Connecting pairs of dimetal units to form molecular loops.

Inorganic chemistry

F A Cotton, C Lin, C A Murillo

Affiliations

  1. Department of Chemistry and Laboratory for Molecular Structure and Bonding, P.O. Box 30012, Texas, A&M University, College Station, Texas 77842-3012, USA. [email protected]

PMID: 11209603 DOI: 10.1021/ic0010151

Abstract

Four compounds consisting of molecular loops formed from two quadruply bonded Mo2(DAniF)2 (DAniF = N,N'-di-p-anisylformamidinate) units linked by two dicarboxylate anions have been prepared in high purity and essentially quantitative yields. These compounds have been characterized by crystallography and NMR spectroscopy and display electrochemical behavior dependent on the nature of the dicarboxylate anion. However, the electronic communication between the two Mo2(4+) units is not strong. As denoted by the dicarboxylate linkers, the compounds are malonate, 1, 1,4-phenylendiacetate, 2, homophthalate, 3, and trans-cyclopentane-1,2-dicarboxylate, 4.

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