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Perrin A, Flaud JM, Keller F, et al. The v(1)+v(3) Bands of the (16)O(17)O(16)O and (16)O(16)O(17)O Isotopomers of Ozone. J Mol Spectrosc. 2001;207(1):54-59doi: 10.1006/jmsp.2001.8320.
Perrin, A., Flaud, J. M., Keller, F., Smith, M. A., Rinsland, C. P., Devi, V. M., Benner, D. C., Stephen, T. M., & Goldman, A. (2001). The v(1)+v(3) Bands of the (16)O(17)O(16)O and (16)O(16)O(17)O Isotopomers of Ozone. Journal of molecular spectroscopy, 207(1), 54-59. https://doi.org/10.1006/jmsp.2001.8320
Perrin, A., et al. "The v(1)+v(3) Bands of the (16)O(17)O(16)O and (16)O(16)O(17)O Isotopomers of Ozone." Journal of molecular spectroscopy vol. 207,1 (2001): 54-59. doi: https://doi.org/10.1006/jmsp.2001.8320
Perrin A, Flaud JM, Keller F, Smith MA, Rinsland CP, Devi VM, Benner DC, Stephen TM, Goldman A. The v(1)+v(3) Bands of the (16)O(17)O(16)O and (16)O(16)O(17)O Isotopomers of Ozone. J Mol Spectrosc. 2001 May;207(1):54-59. doi: 10.1006/jmsp.2001.8320. PMID: 11336520.
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J Mol Spectrosc. 2001 May;207(1):54-59. doi: 10.1006/jmsp.2001.8320.

The v(1)+v(3) Bands of the (16)O(17)O(16)O and (16)O(16)O(17)O Isotopomers of Ozone.

Journal of molecular spectroscopy

A. Perrin, J.-M. Flaud, F. Keller, M. A. H. Smith, C. P. Rinsland, V. Malathy Devi, D. Chris Benner, T. M. Stephen, A. Goldman

Affiliations

  1. Laboratoire de Photophysique Moléculaire, CNRS, Université Paris Sud, Bat. 350, Campus d'Orsay, Orsay Cedex, 91405, France

PMID: 11336520 DOI: 10.1006/jmsp.2001.8320

Abstract

Using 0.002 cm(-1) resolution Fourier transform absorption spectra of an (17)O enriched ozone sample, an extensive analysis of the v(1)+v(3) bands of the (16)O(17)O(16)O and (16)O(16)O(17)O isotopomers of ozone has been performed for the first time. The experimental rotational levels of the (101) vibrational states were satisfactorily reproduced using a Hamiltonian matrix that takes into account the observed rovibrational resonances. More precisely, for (16)O(17)O(16)O, as for the other C(2v)-type ozone isotopomers, it was necessary to account for the Coriolis type resonances linking the (101) rotational levels with the levels of the (200) and (002) vibrational states and the Darling-Dennison interaction coupling the levels of (200) with those of (002). For the C(s)-type isotopomer, namely (16)O(16)O(17)O, as for (16)O(16)O(18)O and (16)O(18)O(18)O, it proved necessary to also account for an additional DeltaK(a)&equals+/-2 resonance involving the rotational levels from (101) and (002) (J.-M. Flaud and R. Bacis, Spectrochimica Acta Part A 54, 3-16 (1998)). Using a Hamiltonian matrix which takes these resonances explicitly into account, precise vibrational energies and rotational and coupling constants were deduced, leading to the following band centers: v(0)(v(1)+v(3))=2078.3496 cm(-1) for (16)O(17)O(16)O and v(0)(v(1)+v(3))=2098.8631 cm(-1) for (16)O(16)O(17)O. Copyright 2001 Academic Press.

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