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Chem Commun (Camb). 2001 Sep 07;(17):1542-3. doi: 10.1039/b103635c.

Tuning metal coordination number by ancillary ligand steric effects: synthesis of a three-coordinate iron(II) complex.

Chemical communications (Cambridge, England)

J M Smith, R J Lachicotte, P L Holland

Affiliations

  1. Department of Chemistry, University of Rochester, Rochester, NY 14627, USA.

PMID: 12240372 DOI: 10.1039/b103635c

Abstract

The coordination number of the metal in iron(II) beta-diketiminate complexes can be tuned through the size of the alkyl substituents on the ligand backbone.

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