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Jones C, Aldridge S, Gans-Eichler T, et al. Synthesis and characterisation of complexes of Group 13 metal amidinate heterocycles with the CpFe(CO)2 fragment. Dalton Trans. 2006;(45):5357-61doi: 10.1039/b611758a.
Jones, C., Aldridge, S., Gans-Eichler, T., & Stasch, A. (2006). Synthesis and characterisation of complexes of Group 13 metal amidinate heterocycles with the CpFe(CO)2 fragment. Dalton transactions (Cambridge, England : 2003), (45), 5357-61. https://doi.org/10.1039/b611758a
Jones, Cameron, et al. "Synthesis and characterisation of complexes of Group 13 metal amidinate heterocycles with the CpFe(CO)2 fragment." Dalton transactions (Cambridge, England : 2003) vol. ,45 (2006): 5357-61. doi: https://doi.org/10.1039/b611758a
Jones C, Aldridge S, Gans-Eichler T, Stasch A. Synthesis and characterisation of complexes of Group 13 metal amidinate heterocycles with the CpFe(CO)2 fragment. Dalton Trans. 2006 Dec 07;(45):5357-61. doi: 10.1039/b611758a. Epub 2006 Sep 29. PMID: 17102861.
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Dalton Trans. 2006 Dec 07;(45):5357-61. doi: 10.1039/b611758a. Epub 2006 Sep 29.

Synthesis and characterisation of complexes of Group 13 metal amidinate heterocycles with the CpFe(CO)2 fragment.

Dalton transactions (Cambridge, England : 2003)

Cameron Jones, Simon Aldridge, Timo Gans-Eichler, Andreas Stasch

Affiliations

  1. Centre for Fundamental and Applied Main Group Chemistry, School of Chemistry, Main Building, Cardiff University, Cardiff, UK CF10 3AT. [email protected]

PMID: 17102861 DOI: 10.1039/b611758a

Abstract

The first examples of complexes between a 4-membered amidinato-Group 13 metal(III) heterocycle and a transition metal fragment are formed in salt elimination reactions between Na[CpFe(CO)2] and [MX2(amid)], M=Al, Ga or In; X=Cl or Br; amid-=[(RN)2CBut]-; R=Pri or cyclohexyl (Cy). The formed complexes, [CpFe(CO)2M(X)(amid)] (4 examples) have been crystallographically characterised and subject to halide abstraction reactions. In one case, the cationic complex, [CpFe(CO)2Ga(OEt2){(CyN)2CBut}][BArf4], was isolated and crystallographically characterised. A hydrolysis product of this complex, [{CpFe(CO)2Ga[(CyN)2CBut]}2(micro-OH)][BArf4], was also isolated in low yield from this reaction and structurally characterised.

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