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Pearson AJ, Sun H. An iron-promoted aldehyde-diene cyclocoupling reaction. J Org Chem. 2007;72(20):7693-700doi: 10.1021/jo071124y.
Pearson, A. J., & Sun, H. (2007). An iron-promoted aldehyde-diene cyclocoupling reaction. The Journal of organic chemistry, 72(20), 7693-700. https://doi.org/10.1021/jo071124y
Pearson, Anthony J, and Sun, Huikai. "An iron-promoted aldehyde-diene cyclocoupling reaction." The Journal of organic chemistry vol. 72,20 (2007): 7693-700. doi: https://doi.org/10.1021/jo071124y
Pearson AJ, Sun H. An iron-promoted aldehyde-diene cyclocoupling reaction. J Org Chem. 2007 Sep 28;72(20):7693-700. doi: 10.1021/jo071124y. Epub 2007 Sep 07. PMID: 17824648.
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J Org Chem. 2007 Sep 28;72(20):7693-700. doi: 10.1021/jo071124y. Epub 2007 Sep 07.

An iron-promoted aldehyde-diene cyclocoupling reaction.

The Journal of organic chemistry

Anthony J Pearson, Huikai Sun

Affiliations

  1. Department of Chemistry, Case Western Reserve University, Cleveland, Ohio 44106, USA. [email protected]

PMID: 17824648 DOI: 10.1021/jo071124y

Abstract

A stereospecific intramolecular iron tricarbonyl-promoted aldehyde-diene cyclocoupling reaction was investigated by using simple substrates 6 and more complicated substrates 30a/30b. Demetalation of the initial products converts all complexed dienes to their pure organic counterparts. In addition, the nickel-catalyzed carbonyl-ene reaction and the Prins reaction were investigated with two different substrates.

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