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Maass JS, Chen Z, Zeller M, et al. Expanding molecular transition metal cubane clusters of the form [M4(μ3)-O)4]12+: syntheses, spectroscopic and structural characterizations of molecules M4(μ3-O)4(O2P(Bn)2)4(O4), M = V(V) and W(V). Dalton Trans. 2011;40(43):11356-8doi: 10.1039/c1dt11375e.
Maass, J. S., Chen, Z., Zeller, M., & Luck, R. L. (2011). Expanding molecular transition metal cubane clusters of the form [M4(μ3)-O)4]12+: syntheses, spectroscopic and structural characterizations of molecules M4(μ3-O)4(O2P(Bn)2)4(O4), M = V(V) and W(V). Dalton transactions (Cambridge, England : 2003), 40(43), 11356-8. https://doi.org/10.1039/c1dt11375e
Maass, John S, et al. "Expanding molecular transition metal cubane clusters of the form [M4(μ3)-O)4]12+: syntheses, spectroscopic and structural characterizations of molecules M4(μ3-O)4(O2P(Bn)2)4(O4), M = V(V) and W(V)." Dalton transactions (Cambridge, England : 2003) vol. 40,43 (2011): 11356-8. doi: https://doi.org/10.1039/c1dt11375e
Maass JS, Chen Z, Zeller M, Luck RL. Expanding molecular transition metal cubane clusters of the form [M4(μ3)-O)4]12+: syntheses, spectroscopic and structural characterizations of molecules M4(μ3-O)4(O2P(Bn)2)4(O4), M = V(V) and W(V). Dalton Trans. 2011 Nov 21;40(43):11356-8. doi: 10.1039/c1dt11375e. Epub 2011 Oct 06. PMID: 21976014.
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Dalton Trans. 2011 Nov 21;40(43):11356-8. doi: 10.1039/c1dt11375e. Epub 2011 Oct 06.

Expanding molecular transition metal cubane clusters of the form [M4(μ3)-O)4]12+: syntheses, spectroscopic and structural characterizations of molecules M4(μ3-O)4(O2P(Bn)2)4(O4), M = V(V) and W(V).

Dalton transactions (Cambridge, England : 2003)

John S Maass, Zhichao Chen, Matthias Zeller, Rudy L Luck

Affiliations

  1. Department of Chemistry, Michigan Technological University, 1400 Townsend Drive, Houghton, MI 49931, USA.

PMID: 21976014 DOI: 10.1039/c1dt11375e

Abstract

Oxidizing the trimer V(3)(μ(3)-O)(O(2))(μ(2)-O(2)P(Bn)(2))(6)(H(2)O) in the presence of excess (t)BuOOH results in V(4)(μ(3)-O)(4)(μ(2)-O(2)P(Bn)(2))(4)(O(4)) and heating W(CO)(6) and bis(benzyl)phosphinic acid in 1:1 EtOH/THF at 120 °C produces W(4)(μ(3)-O)(4)(μ(2)-O(2)P(Bn)(2))(4)(O(4)).

This journal is © The Royal Society of Chemistry 2011

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