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Nat Commun. 2013;4:2491. doi: 10.1038/ncomms3491.

Dispersant-free conducting pastes for flexible and printed nanocarbon electrodes.

Nature communications

Joong Tark Han, Bo Hwa Jeong, Seon Hee Seo, Kwang Chul Roh, Sumi Kim, Sua Choi, Jong Seok Woo, Ho Young Kim, Jeong In Jang, Du-Chul Shin, Sooyeon Jeong, Hee Jin Jeong, Seung Yol Jeong, Geon-Woong Lee

Affiliations

  1. 1] Nano Carbon Materials Research Group, Creative and Fundamental Research Division, Korea Electrotechnology Research Institute, 12, Bulmosan-ro 10beon-gil, Seongsan-gu, Changwon 642-120, South Korea [2] Department of Electrical Functionality Material Engineering, University of Science and Technology, 12, Bulmosan-ro 10beon-gil, Seongsan-gu, Changwon 642-120, South Korea.

PMID: 24096376 DOI: 10.1038/ncomms3491

Abstract

The dispersant-free fabrication of highly conducting pastes based on organic solvents with nanocarbon materials such as carbon nanotubes and graphene nanoplatelets has been hindered by severe agglomeration. Here we report a straightforward method for fabricating nanocarbon suspensions with >10% weight concentrations in absence of organic dispersants. The method involves introducing supramolecular quadruple hydrogen-bonding motifs into the nanocarbon materials without sacrificing the electrical conductivity. Printed films of these materials show high electrical conductivity of ~500,000 S m(-1) by hybridization with 5 vol% silver nanowires. In addition, the printed nanocarbon electrodes provide high-performance alternatives to the platinum catalytic electrodes commonly used in dye-sensitized solar cells and electrochemical electrodes in supercapacitors. The judicious use of supramolecular interactions allows fabrication of printable, spinnable and chemically compatible conducting pastes with high-quality nanocarbon materials, useful in flexible electronics and textile electronics.

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