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Wang X, Pang H, Chen W, et al. Controllable fabrication of zinc borate hierarchical nanostructure on brucite surface for enhanced mechanical properties and flame retardant behaviors. ACS Appl Mater Interfaces. 2014;6(10):7223-35doi: 10.1021/am500380n.
Wang, X., Pang, H., Chen, W., Lin, Y., Zong, L., & Ning, G. (2014). Controllable fabrication of zinc borate hierarchical nanostructure on brucite surface for enhanced mechanical properties and flame retardant behaviors. ACS applied materials & interfaces, 6(10), 7223-35. https://doi.org/10.1021/am500380n
Wang, Xuesong, et al. "Controllable fabrication of zinc borate hierarchical nanostructure on brucite surface for enhanced mechanical properties and flame retardant behaviors." ACS applied materials & interfaces vol. 6,10 (2014): 7223-35. doi: https://doi.org/10.1021/am500380n
Wang X, Pang H, Chen W, Lin Y, Zong L, Ning G. Controllable fabrication of zinc borate hierarchical nanostructure on brucite surface for enhanced mechanical properties and flame retardant behaviors. ACS Appl Mater Interfaces. 2014 May 28;6(10):7223-35. doi: 10.1021/am500380n. Epub 2014 May 19. PMID: 24813539.
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ACS Appl Mater Interfaces. 2014 May 28;6(10):7223-35. doi: 10.1021/am500380n. Epub 2014 May 19.

Controllable fabrication of zinc borate hierarchical nanostructure on brucite surface for enhanced mechanical properties and flame retardant behaviors.

ACS applied materials & interfaces

Xuesong Wang, Hongchang Pang, Wendan Chen, Yuan Lin, Lishuai Zong, Guiling Ning

Affiliations

  1. Faculty of Chemical, Environmental & Biological Science and Technology, Dalian University of Technology , Dalian 116024, China.

PMID: 24813539 DOI: 10.1021/am500380n

Abstract

A novel and efficient halogen-free composite flame retardant (CFR) consisting of a brucite core and a fine zinc borate [Zn6O(OH)(BO3)3] hierarchical nanostructure shell was designed and synthesized via a facile nanoengineering route. It had been demonstrated that this unique hybrid structure possessed a high BET specific surface area (65 m(2)/g) and could significantly enhance the interfacial interaction when mixing with ethylene-vinyl acetate (EVA). This improved the transfer of stress between CFR particles and EVA matrix and increased the viscosity of EVA/EVA blends, which was beneficial for droplet inhibition and char forming. The mechanical properties and flammability behaviors of the EVA/CFR blends had been compared with the EVA/physical mixture (PM, with the given proportion of brucite and Zn6O(OH)(BO3)3). The mechanical properties of EVA/CFR blends, especially the tensile strength (TS), presented a remarkable increase reaching at least a 20% increment. Meanwhile, with the same 45 wt % of fillers, the EVA/CFR formulation could achieve a limiting oxygen index (LOI) value of 33 (37.5 % higher than that of EVA/PM blends) and UL-94 V-0 rating. Moreover, the heat release rate (HRR), peak heat release rate (PHRR), total heat released (THR), smoke production rate (SPR) and mass loss rate (MLR) were considerably reduced, especially PHRR and SPR for EVA/CFR blends were reduced to 32%. According to this study, the design of fine structure might pave the way for the future development of halogen-free flame retardants combining both enhanced mechanical properties and excellent flame retardant behaviors.

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