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Yang X, Schipper D, Zhang L, et al. Anion dependent self-assembly of 56-metal Cd-Ln nanoclusters with enhanced near-infrared luminescence properties. Nanoscale. 2014;6(18):10569-73doi: 10.1039/c4nr03075c.
Yang, X., Schipper, D., Zhang, L., Yang, K., Huang, S., Jiang, J., Su, C., & Jones, R. A. (2014). Anion dependent self-assembly of 56-metal Cd-Ln nanoclusters with enhanced near-infrared luminescence properties. Nanoscale, 6(18), 10569-73. https://doi.org/10.1039/c4nr03075c
Yang, Xiaoping, et al. "Anion dependent self-assembly of 56-metal Cd-Ln nanoclusters with enhanced near-infrared luminescence properties." Nanoscale vol. 6,18 (2014): 10569-73. doi: https://doi.org/10.1039/c4nr03075c
Yang X, Schipper D, Zhang L, Yang K, Huang S, Jiang J, Su C, Jones RA. Anion dependent self-assembly of 56-metal Cd-Ln nanoclusters with enhanced near-infrared luminescence properties. Nanoscale. 2014 Sep 21;6(18):10569-73. doi: 10.1039/c4nr03075c. Epub 2014 Aug 14. PMID: 25144568.
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Nanoscale. 2014 Sep 21;6(18):10569-73. doi: 10.1039/c4nr03075c. Epub 2014 Aug 14.

Anion dependent self-assembly of 56-metal Cd-Ln nanoclusters with enhanced near-infrared luminescence properties.

Nanoscale

Xiaoping Yang, Desmond Schipper, Lijie Zhang, Keqin Yang, Shaoming Huang, Jijun Jiang, Chengyong Su, Richard A Jones

Affiliations

  1. College of Chemistry and Materials Engineering, Wenzhou University, Zhejiang Key Laboratory of Carbon Materials, Wenzhou 325035, China. [email protected].

PMID: 25144568 DOI: 10.1039/c4nr03075c

Abstract

Two series of Cd-Ln clusters: nano-drum [Ln₈Cd₂₄L₁₂(OAc)₄₈] and nano-double-drum [Ln₁₂Cd₄₄L₂₀Cl₃₀(OAc)₅₄] (Ln = Nd and Yb) were prepared using a flexible Schiff base ligand bearing two aryl-Br groups. Chloride (Cl(-)) ions, together with the interactions of Br with other electronegative atoms, play a key role in the formation of the nano-double-drums. The structures were studied by TEM and photophysical properties were determined.

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