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Jeon HJ, Matsuda R, Kanoo P, et al. The densely fluorinated nanospace of a porous coordination polymer composed of perfluorobutyl-functionalized ligands. Chem Commun (Camb). 2014;50(74):10861-3doi: 10.1039/c4cc04505j.
Jeon, H. J., Matsuda, R., Kanoo, P., Kajiro, H., Li, L., Sato, H., Zheng, Y., & Kitagawa, S. (2014). The densely fluorinated nanospace of a porous coordination polymer composed of perfluorobutyl-functionalized ligands. Chemical communications (Cambridge, England), 50(74), 10861-3. https://doi.org/10.1039/c4cc04505j
Jeon, Hyung Joon, et al. "The densely fluorinated nanospace of a porous coordination polymer composed of perfluorobutyl-functionalized ligands." Chemical communications (Cambridge, England) vol. 50,74 (2014): 10861-3. doi: https://doi.org/10.1039/c4cc04505j
Jeon HJ, Matsuda R, Kanoo P, Kajiro H, Li L, Sato H, Zheng Y, Kitagawa S. The densely fluorinated nanospace of a porous coordination polymer composed of perfluorobutyl-functionalized ligands. Chem Commun (Camb). 2014 Sep 25;50(74):10861-3. doi: 10.1039/c4cc04505j. PMID: 25089888.
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Chem Commun (Camb). 2014 Sep 25;50(74):10861-3. doi: 10.1039/c4cc04505j.

The densely fluorinated nanospace of a porous coordination polymer composed of perfluorobutyl-functionalized ligands.

Chemical communications (Cambridge, England)

Hyung Joon Jeon, Ryotaro Matsuda, Prakash Kanoo, Hiroshi Kajiro, Liangchun Li, Hiroshi Sato, Yongtai Zheng, Susumu Kitagawa

Affiliations

  1. Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan. [email protected].

PMID: 25089888 DOI: 10.1039/c4cc04505j

Abstract

A perfluorobutyl-functionalized two-dimensional porous coordination polymer (PCP), {[Cu(bpbtp)(L)(DMF)]·(DMF)}n (H2bpbtp = 2,5-bis(perfluorobutyl)terephthalic acid, L = 2,5-bis(perfluorobutyl)-1,4-bis(4-pyridyl)benzene, DMF = N,N-dimethylformamide) has been synthesized and structurally characterized. The pore surface of the PCP is decorated with pendant perfluorobutyl groups which fabricate a densely fluorinated nanospace resulting in unique gas sorption properties.

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