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Wu D, Zhang J, Cui J, et al. AgNO2-mediated direct nitration of the quinoxaline tertiary benzylic C-H bond and direct conversion of 2-methyl quinoxalines into related nitriles. Chem Commun (Camb). 2014;50(74):10857-60doi: 10.1039/c4cc01327a.
Wu, D., Zhang, J., Cui, J., Zhang, W., & Liu, Y. (2014). AgNO2-mediated direct nitration of the quinoxaline tertiary benzylic C-H bond and direct conversion of 2-methyl quinoxalines into related nitriles. Chemical communications (Cambridge, England), 50(74), 10857-60. https://doi.org/10.1039/c4cc01327a
Wu, Degui, et al. "AgNO2-mediated direct nitration of the quinoxaline tertiary benzylic C-H bond and direct conversion of 2-methyl quinoxalines into related nitriles." Chemical communications (Cambridge, England) vol. 50,74 (2014): 10857-60. doi: https://doi.org/10.1039/c4cc01327a
Wu D, Zhang J, Cui J, Zhang W, Liu Y. AgNO2-mediated direct nitration of the quinoxaline tertiary benzylic C-H bond and direct conversion of 2-methyl quinoxalines into related nitriles. Chem Commun (Camb). 2014 Sep 25;50(74):10857-60. doi: 10.1039/c4cc01327a. PMID: 25089911.
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Chem Commun (Camb). 2014 Sep 25;50(74):10857-60. doi: 10.1039/c4cc01327a.

AgNO2-mediated direct nitration of the quinoxaline tertiary benzylic C-H bond and direct conversion of 2-methyl quinoxalines into related nitriles.

Chemical communications (Cambridge, England)

Degui Wu, Jian Zhang, Jianhai Cui, Wei Zhang, Yunkui Liu

Affiliations

  1. State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, P. R. China. [email protected].

PMID: 25089911 DOI: 10.1039/c4cc01327a

Abstract

A unique method for AgNO2-mediated direct nitration of the quinoxaline tertiary C-H bond and direct conversion of 2-methyl quinoxalines into 2-quinoxaline nitriles under oxidative conditions has been developed. This protocol provides an efficient way to access quinoxaline containing nitroalkanes and nitriles depending on different substrate selection.

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