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J Colloid Interface Sci. 2014 Nov 15;434:98-103. doi: 10.1016/j.jcis.2014.07.006. Epub 2014 Aug 13.

Fabrication of colloidal photonic crystal heterostructures free of interface imperfection based on solvent vapor annealing.

Journal of colloid and interface science

Xiaomiao Liu, Duobiao Zhao, Chong Geng, Lijing Zhang, Tianya Tan, Mingzhe Hu, Qingfeng Yan

Affiliations

  1. Department of Chemistry, Tsinghua University, Beijing 100084, China.
  2. Department of Physics, Liaoning University, Shenyang 110036, China.
  3. College of Science, Guizhou University, Guiyang 550025, China.
  4. Department of Chemistry, Tsinghua University, Beijing 100084, China. Electronic address: [email protected].

PMID: 25170602 DOI: 10.1016/j.jcis.2014.07.006

Abstract

We describe the transformation of a colloidal photonic crystal into a photonic crystal heterostructure. It was achieved by annealing a polystyrene multilayer colloidal photonic crystal partially immersed in water using a solvent vapor. The floating polystyrene colloidal photonic crystal was divided into two parts by the liquid level, which can be manipulated by the addition of ethanol into the water. The top part protruding out of the water experienced a uniform lattice stretching upon exposure to the solvent vapor. The bottom part that stayed immersed in the water remained unaffected due to the protection by the water. The inconsistent behaviors of the two parts resulted in the formation of a colloidal photonic crystal heterostructure. Such a heterostructure was free of interface imperfection since it was a direct descendant of the original colloidal crystal. Meanwhile, optical measurements demonstrated the presence of a wider photonic band gap along the crystallographic [111] direction in these photonic crystal heterostructures compared with the original colloidal photonic crystals.

Copyright © 2014 Elsevier Inc. All rights reserved.

Keywords: Colloidal self-assembly; Interface imperfection; Photonic crystal heterostructure; Solvent vapor annealing

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