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McDonald KP, Qiao B, Twum EB, et al. Quantifying chloride binding and salt extraction with poly(methyl methacrylate) copolymers bearing aryl-triazoles as anion receptor side chains. Chem Commun (Camb). 2014;50(87):13285-8doi: 10.1039/c4cc03362k.
McDonald, K. P., Qiao, B., Twum, E. B., Lee, S., Gamache, P. J., Chen, C. H., Yi, Y., & Flood, A. H. (2014). Quantifying chloride binding and salt extraction with poly(methyl methacrylate) copolymers bearing aryl-triazoles as anion receptor side chains. Chemical communications (Cambridge, England), 50(87), 13285-8. https://doi.org/10.1039/c4cc03362k
McDonald, Kevin P, et al. "Quantifying chloride binding and salt extraction with poly(methyl methacrylate) copolymers bearing aryl-triazoles as anion receptor side chains." Chemical communications (Cambridge, England) vol. 50,87 (2014): 13285-8. doi: https://doi.org/10.1039/c4cc03362k
McDonald KP, Qiao B, Twum EB, Lee S, Gamache PJ, Chen CH, Yi Y, Flood AH. Quantifying chloride binding and salt extraction with poly(methyl methacrylate) copolymers bearing aryl-triazoles as anion receptor side chains. Chem Commun (Camb). 2014 Nov 11;50(87):13285-8. doi: 10.1039/c4cc03362k. Epub 2014 Sep 18. PMID: 25233076.
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Chem Commun (Camb). 2014 Nov 11;50(87):13285-8. doi: 10.1039/c4cc03362k. Epub 2014 Sep 18.

Quantifying chloride binding and salt extraction with poly(methyl methacrylate) copolymers bearing aryl-triazoles as anion receptor side chains.

Chemical communications (Cambridge, England)

Kevin P McDonald, Bo Qiao, Eric B Twum, Semin Lee, Patrick J Gamache, Chun-Hsing Chen, Yi Yi, Amar H Flood

Affiliations

  1. Department of Chemistry, Indiana University, 800 E. Kirkwood Ave., Bloomington, IN 47405, USA. [email protected].

PMID: 25233076 DOI: 10.1039/c4cc03362k

Abstract

Copolymers of methyl methacrylate and aryl-triazole based anion receptors were quantitatively analyzed. Transfer of structural features (1 : 1 and 2 : 1 complexes) and Cl(-) affinities from the parent receptors was demonstrated. Cl(-)-induced cross-linking changed the polymer's hydrodynamic radius. Extraction of tetrapropylammonium Cl(-) from water to dichloromethane was enhanced over PMMA.

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