Display options
Share it on

Carbohydr Polym. 2015 May 05;121:147-54. doi: 10.1016/j.carbpol.2014.12.030. Epub 2014 Dec 31.

Effects of inorganic cations on the rheology of aqueous welan, xanthan, gellan solutions and their mixtures.

Carbohydrate polymers

Long Xu, Mingzhe Dong, Houjian Gong, Mengjiao Sun, Yajun Li

Affiliations

  1. School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, PR China.
  2. School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, PR China; Department of Chemical and Petroleum Engineering, University of Calgary, Calgary, AB, Canada T2N 1N4. Electronic address: [email protected].

PMID: 25659683 DOI: 10.1016/j.carbpol.2014.12.030

Abstract

The effects of different inorganic cations (Na(+), K(+), Ca(2+) and Al(3+)) on the rheological properties of single and mixture polysaccharide solutions have been systematically investigated. The apparent viscosity and viscoelasticity of welan solutions decrease with the addition of inorganic cations. Meanwhile, the addition of Al(3+) and K(+), respectively, enhances the apparent viscosity and viscoelasticity of xanthan and gellan solutions by promoting the gelation. The viscosity retention rate of welan/xanthan mixtures is higher than that of the single components in Na(+), K(+) and Ca(2+) solutions, and the viscosity retention rate of welan/gellan mixtures is higher than that of the single components in Ca(2+) solutions. The salt induced gelation expands the application for polysaccharides, and it is also believed that the method of combining welan and xanthan (or gellan) is an effective strategy to control the rheology and morphology of solutions in the presence of inorganic salts.

Copyright © 2014 Elsevier Ltd. All rights reserved.

Keywords: Gellan; Inorganic cation; Rheology; Viscosity retention rate; Welan; Xanthan

Publication Types