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Sun JK, Zhan WW, Akita T, et al. Toward Homogenization of Heterogeneous Metal Nanoparticle Catalysts with Enhanced Catalytic Performance: Soluble Porous Organic Cage as a Stabilizer and Homogenizer. J Am Chem Soc. 2015;137(22):7063-6doi: 10.1021/jacs.5b04029.
Sun, J. K., Zhan, W. W., Akita, T., & Xu, Q. (2015). Toward Homogenization of Heterogeneous Metal Nanoparticle Catalysts with Enhanced Catalytic Performance: Soluble Porous Organic Cage as a Stabilizer and Homogenizer. Journal of the American Chemical Society, 137(22), 7063-6. https://doi.org/10.1021/jacs.5b04029
Sun, Jian-Ke, et al. "Toward Homogenization of Heterogeneous Metal Nanoparticle Catalysts with Enhanced Catalytic Performance: Soluble Porous Organic Cage as a Stabilizer and Homogenizer." Journal of the American Chemical Society vol. 137,22 (2015): 7063-6. doi: https://doi.org/10.1021/jacs.5b04029
Sun JK, Zhan WW, Akita T, Xu Q. Toward Homogenization of Heterogeneous Metal Nanoparticle Catalysts with Enhanced Catalytic Performance: Soluble Porous Organic Cage as a Stabilizer and Homogenizer. J Am Chem Soc. 2015 Jun 10;137(22):7063-6. doi: 10.1021/jacs.5b04029. Epub 2015 Jun 02. PMID: 26020572.
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J Am Chem Soc. 2015 Jun 10;137(22):7063-6. doi: 10.1021/jacs.5b04029. Epub 2015 Jun 02.

Toward Homogenization of Heterogeneous Metal Nanoparticle Catalysts with Enhanced Catalytic Performance: Soluble Porous Organic Cage as a Stabilizer and Homogenizer.

Journal of the American Chemical Society

Jian-Ke Sun, Wen-Wen Zhan, Tomoki Akita, Qiang Xu

Affiliations

  1. National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563-8577, Japan.

PMID: 26020572 DOI: 10.1021/jacs.5b04029

Abstract

Organic molecular cage (CC3-R) with intrinsically porous skeleton is used as a support for immobilizing Rh nanoparticles (NPs) in an ultrasmall size of ∼1.1 nm for the first time. The CC3-R with the unique characteristic of high solubility can be utilized to homogenize the heterogeneous catalyst in solution. The obtained homogenized heterogeneous catalyst Rh/CC3-R-homo exhibits significantly enhanced catalytic performance toward various liquid-phase catalytic reactions, as compared with the heterogeneous counterpart Rh/CC3-R-hetero. Moreover, Rh/CC3-R-homo shows excellent durability and recyclability. The advantage of combining homogeneous and heterogeneous catalysts is likely to be beneficial for many applications.

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