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Wang Y, Deyris PA, Caneque T, et al. A Simple Synthesis of Triangular All-Metal Aromatics Allowing Access to Isolobal All-Metal Heteroaromatics. Chemistry. 2015;21(35):12271-4doi: 10.1002/chem.201501239.
Wang, Y., Deyris, P. A., Caneque, T., Blanchard, F., Li, Y., Bigi, F., Maggi, R., Blanchard, S., Maestri, G., & Malacria, M. (2015). A Simple Synthesis of Triangular All-Metal Aromatics Allowing Access to Isolobal All-Metal Heteroaromatics. Chemistry (Weinheim an der Bergstrasse, Germany), 21(35), 12271-4. https://doi.org/10.1002/chem.201501239
Wang, Yanlan, et al. "A Simple Synthesis of Triangular All-Metal Aromatics Allowing Access to Isolobal All-Metal Heteroaromatics." Chemistry (Weinheim an der Bergstrasse, Germany) vol. 21,35 (2015): 12271-4. doi: https://doi.org/10.1002/chem.201501239
Wang Y, Deyris PA, Caneque T, Blanchard F, Li Y, Bigi F, Maggi R, Blanchard S, Maestri G, Malacria M. A Simple Synthesis of Triangular All-Metal Aromatics Allowing Access to Isolobal All-Metal Heteroaromatics. Chemistry. 2015 Aug 24;21(35):12271-4. doi: 10.1002/chem.201501239. Epub 2015 Jul 06. PMID: 26149891.
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Chemistry. 2015 Aug 24;21(35):12271-4. doi: 10.1002/chem.201501239. Epub 2015 Jul 06.

A Simple Synthesis of Triangular All-Metal Aromatics Allowing Access to Isolobal All-Metal Heteroaromatics.

Chemistry (Weinheim an der Bergstrasse, Germany)

Yanlan Wang, Pierre-Alexandre Deyris, Tatiana Caneque, Florent Blanchard, Yanling Li, Franca Bigi, Raimondo Maggi, Sebastien Blanchard, Giovanni Maestri, Max Malacria

Affiliations

  1. ICSN CNRS (UPR 2301), 1 Av. de la Terrasse, Bat. 27, 91198 Gif s/Yvette (France).
  2. UPMC Sorbonne Universités, IPCM (UMR CNRS 7201), 4 place Jussieu, C. 229, 75005 Paris (France).
  3. Università degli Studi di Parma, Dipartimento di Chimica, 17A Parco Area delle Scienze, 43124 Parma (Italy).
  4. ICSN CNRS (UPR 2301), 1 Av. de la Terrasse, Bat. 27, 91198 Gif s/Yvette (France). [email protected].
  5. Università degli Studi di Parma, Dipartimento di Chimica, 17A Parco Area delle Scienze, 43124 Parma (Italy). [email protected].

PMID: 26149891 DOI: 10.1002/chem.201501239

Abstract

A simple synthetic method allows the one-pot assembly of C3 -symmetric, 44-core-valence-electron, triangular Pd or Pt clusters and their heterobimetallic mixed Pd/Pt analogues. These mixed metal complexes are the first examples of stable triangular all-metal heteroaromatics. In contrast to traditional heteroaromatic molecules formed combining main-group elements, they actually retain structural and electronic features of their homonuclear analogues.

© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: aromaticity; cluster compounds; heterocycles; metal-metal bonds; metallacycles

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