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Taglang C, Martínez-Prieto LM, del Rosal I, et al. Enantiospecific C-H Activation Using Ruthenium Nanocatalysts. Angew Chem Int Ed Engl. 2015;54(36):10474-7doi: 10.1002/anie.201504554.
Taglang, C., Martínez-Prieto, L. M., del Rosal, I., Maron, L., Poteau, R., Philippot, K., Chaudret, B., Perato, S., Sam Lone, A., Puente, C., Dugave, C., Rousseau, B., & Pieters, G. (2015). Enantiospecific C-H Activation Using Ruthenium Nanocatalysts. Angewandte Chemie (International ed. in English), 54(36), 10474-7. https://doi.org/10.1002/anie.201504554
Taglang, Céline, et al. "Enantiospecific C-H Activation Using Ruthenium Nanocatalysts." Angewandte Chemie (International ed. in English) vol. 54,36 (2015): 10474-7. doi: https://doi.org/10.1002/anie.201504554
Taglang C, Martínez-Prieto LM, del Rosal I, Maron L, Poteau R, Philippot K, Chaudret B, Perato S, Sam Lone A, Puente C, Dugave C, Rousseau B, Pieters G. Enantiospecific C-H Activation Using Ruthenium Nanocatalysts. Angew Chem Int Ed Engl. 2015 Sep 01;54(36):10474-7. doi: 10.1002/anie.201504554. PMID: 26371960.
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Angew Chem Int Ed Engl. 2015 Sep 01;54(36):10474-7. doi: 10.1002/anie.201504554.

Enantiospecific C-H Activation Using Ruthenium Nanocatalysts.

Angewandte Chemie (International ed. in English)

Céline Taglang, Luis Miguel Martínez-Prieto, Iker del Rosal, Laurent Maron, Romuald Poteau, Karine Philippot, Bruno Chaudret, Serge Perato, Anaïs Sam Lone, Céline Puente, Christophe Dugave, Bernard Rousseau, Grégory Pieters

Affiliations

  1. CEA Saclay, SCBM, iBiTec-S, Building 547, PC # 108, 91191 Gif sur Yvette (France).
  2. LPCNO; Laboratoire de Physique et Chimie de Nano-Objets, UMR 5215 INSA-CNRS-UPS, Institut National des Sciences Appliquées, 135, Avenue de Rangueil, 31077 Toulouse (France).
  3. CNRS; LCC (Laboratoire de Chimie de Coordination), 205, Route de Narbonne, 31077 Toulouse (France).
  4. CEA Saclay, SCBM, iBiTec-S, Building 547, PC # 108, 91191 Gif sur Yvette (France). [email protected].

PMID: 26371960 DOI: 10.1002/anie.201504554

Abstract

The activation of C-H bonds has revolutionized modern synthetic chemistry. However, no general strategy for enantiospecific C-H activation has been developed to date. We herein report an enantiospecific C-H activation reaction followed by deuterium incorporation at stereogenic centers. Mechanistic studies suggest that the selectivity for the α-position of the directing heteroatom results from a four-membered dimetallacycle as the key intermediate. This work paves the way to novel molecular chemistry on nanoparticles.

© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: CH activation; ab initio calculations; deuterium; isotopic labeling; nanoparticles

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