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Enantiospecific C-H Activation Using Ruthenium Nanocatalysts.

Angewandte Chemie (International ed. in English)

Taglang C, Martínez-Prieto LM, del Rosal I, Maron L, Poteau R, Philippot K, Chaudret B, Perato S, Sam Lone A, Puente C, Dugave C, Rousseau B, Pieters G.
PMID: 26371960
Angew Chem Int Ed Engl. 2015 Sep 01;54(36):10474-7. doi: 10.1002/anie.201504554.

The activation of C-H bonds has revolutionized modern synthetic chemistry. However, no general strategy for enantiospecific C-H activation has been developed to date. We herein report an enantiospecific C-H activation reaction followed by deuterium incorporation at stereogenic centers. Mechanistic...

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Taglang C, Martínez-Prieto LM, del Rosal I, et al. Enantiospecific C-H Activation Using Ruthenium Nanocatalysts. Angew Chem Int Ed Engl. 2015;54(36):10474-7doi: 10.1002/anie.201504554.
Taglang, C., Martínez-Prieto, L. M., del Rosal, I., Maron, L., Poteau, R., Philippot, K., Chaudret, B., Perato, S., Sam Lone, A., Puente, C., Dugave, C., Rousseau, B., & Pieters, G. (2015). Enantiospecific C-H Activation Using Ruthenium Nanocatalysts. Angewandte Chemie (International ed. in English), 54(36), 10474-7. https://doi.org/10.1002/anie.201504554
Taglang, Céline, et al. "Enantiospecific C-H Activation Using Ruthenium Nanocatalysts." Angewandte Chemie (International ed. in English) vol. 54,36 (2015): 10474-7. doi: https://doi.org/10.1002/anie.201504554
Taglang C, Martínez-Prieto LM, del Rosal I, Maron L, Poteau R, Philippot K, Chaudret B, Perato S, Sam Lone A, Puente C, Dugave C, Rousseau B, Pieters G. Enantiospecific C-H Activation Using Ruthenium Nanocatalysts. Angew Chem Int Ed Engl. 2015 Sep 01;54(36):10474-7. doi: 10.1002/anie.201504554. PMID: 26371960.
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Soluble Platinum Nanoparticles Ligated by Long-Chain N-Heterocyclic Carbenes as Catalysts.

Chemistry (Weinheim an der Bergstrasse, Germany)

Martínez-Prieto LM, Rakers L, López-Vinasco AM, Cano I, Coppel Y, Philippot K, Glorius F, Chaudret B, van Leeuwen PWNM.
PMID: 28612457
Chemistry. 2017 Sep 18;23(52):12779-12786. doi: 10.1002/chem.201702288. Epub 2017 Jul 26.

Soluble platinum nanoparticles (Pt NPs) ligated by two different long-chain N-heterocyclic carbenes (LC-IPr and LC-IMe) were synthesized and fully characterized by TEM, high-resolution TEM, wide-angle X-ray scattering (WAXS), X-ray photoelectron spectroscopy (XPS), and solution NMR. The surface chemistry of...

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Martínez-Prieto LM, Rakers L, López-Vinasco AM, et al. Soluble Platinum Nanoparticles Ligated by Long-Chain N-Heterocyclic Carbenes as Catalysts. Chemistry. 2017;23(52):12779-12786doi: 10.1002/chem.201702288.
Martínez-Prieto, L. M., Rakers, L., López-Vinasco, A. M., Cano, I., Coppel, Y., Philippot, K., Glorius, F., Chaudret, B., & van Leeuwen, P. W. N. M. (2017). Soluble Platinum Nanoparticles Ligated by Long-Chain N-Heterocyclic Carbenes as Catalysts. Chemistry (Weinheim an der Bergstrasse, Germany), 23(52), 12779-12786. https://doi.org/10.1002/chem.201702288
Martínez-Prieto, Luis M, et al. "Soluble Platinum Nanoparticles Ligated by Long-Chain N-Heterocyclic Carbenes as Catalysts." Chemistry (Weinheim an der Bergstrasse, Germany) vol. 23,52 (2017): 12779-12786. doi: https://doi.org/10.1002/chem.201702288
Martínez-Prieto LM, Rakers L, López-Vinasco AM, Cano I, Coppel Y, Philippot K, Glorius F, Chaudret B, van Leeuwen PWNM. Soluble Platinum Nanoparticles Ligated by Long-Chain N-Heterocyclic Carbenes as Catalysts. Chemistry. 2017 Sep 18;23(52):12779-12786. doi: 10.1002/chem.201702288. Epub 2017 Jul 26. PMID: 28612457.
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Organometallic Ruthenium Nanoparticles: Synthesis, Surface Chemistry, and Insights into Ligand Coordination.

Accounts of chemical research

Martínez-Prieto LM, Chaudret B.
PMID: 29308876
Acc Chem Res. 2018 Feb 20;51(2):376-384. doi: 10.1021/acs.accounts.7b00378. Epub 2018 Jan 08.

Although there has been for the past 20 years great interest in the synthesis and use of metal nanoparticles, little attention has been paid to the complexity of the surface of these species. In particular, the different aspects concerning...

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Martínez-Prieto LM, Chaudret B. Organometallic Ruthenium Nanoparticles: Synthesis, Surface Chemistry, and Insights into Ligand Coordination. Acc Chem Res. 2018;51(2):376-384doi: 10.1021/acs.accounts.7b00378.
Martínez-Prieto, L. M., & Chaudret, B. (2018). Organometallic Ruthenium Nanoparticles: Synthesis, Surface Chemistry, and Insights into Ligand Coordination. Accounts of chemical research, 51(2), 376-384. https://doi.org/10.1021/acs.accounts.7b00378
Martínez-Prieto, Luis M, and Chaudret, Bruno. "Organometallic Ruthenium Nanoparticles: Synthesis, Surface Chemistry, and Insights into Ligand Coordination." Accounts of chemical research vol. 51,2 (2018): 376-384. doi: https://doi.org/10.1021/acs.accounts.7b00378
Martínez-Prieto LM, Chaudret B. Organometallic Ruthenium Nanoparticles: Synthesis, Surface Chemistry, and Insights into Ligand Coordination. Acc Chem Res. 2018 Feb 20;51(2):376-384. doi: 10.1021/acs.accounts.7b00378. Epub 2018 Jan 08. PMID: 29308876.
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Iris yellow spot virus: A New Onion Disease in Spain.

Plant disease

Córdoba-Sellés C, Martínez-Priego L, Muńoz-Gómez R, Jordá-Gutiérrez C.
PMID: 30786456
Plant Dis. 2005 Nov;89(11):1243. doi: 10.1094/PD-89-1243A.

So far, only three viral diseases have been identified in onion crops grown in Spain. These are Tomato spotted wilt virus (TSWV), Onion yellow dwarf virus (OYDV), and Leek yellow stripe virus (LYSV). In September 2003, unusual virus-like symptoms...

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Córdoba-Sellés C, Martínez-Priego L, Muńoz-Gómez R, et al. Iris yellow spot virus: A New Onion Disease in Spain. Plant Dis. 2005;89(11):1243doi: 10.1094/PD-89-1243A.
Córdoba-Sellés, C., Martínez-Priego, L., Muńoz-Gómez, R., & Jordá-Gutiérrez, C. (2005). Iris yellow spot virus: A New Onion Disease in Spain. Plant disease, 89(11), 1243. https://doi.org/10.1094/PD-89-1243A
Córdoba-Sellés, C, et al. "Iris yellow spot virus: A New Onion Disease in Spain." Plant disease vol. 89,11 (2005): 1243. doi: https://doi.org/10.1094/PD-89-1243A
Córdoba-Sellés C, Martínez-Priego L, Muńoz-Gómez R, Jordá-Gutiérrez C. Iris yellow spot virus: A New Onion Disease in Spain. Plant Dis. 2005 Nov;89(11):1243. doi: 10.1094/PD-89-1243A. PMID: 30786456.
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Ruthenium-catalyzed hydrogen isotope exchange of C(sp.

Chemical communications (Cambridge, England)

Gao L, Perato S, Garcia-Argote S, Taglang C, Martínez-Prieto LM, Chollet C, Buisson DA, Dauvois V, Lesot P, Chaudret B, Rousseau B, Feuillastre S, Pieters G.
PMID: 29505052
Chem Commun (Camb). 2018 Mar 25;54(24):2986-2989. doi: 10.1039/c8cc00653a. Epub 2018 Mar 05.

We present here the first example of C(sp

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Gao L, Perato S, Garcia-Argote S, et al. Ruthenium-catalyzed hydrogen isotope exchange of C(sp. Chem Commun (Camb). 2018;54(24):2986-2989doi: 10.1039/c8cc00653a.
Gao, L., Perato, S., Garcia-Argote, S., Taglang, C., Martínez-Prieto, L. M., Chollet, C., Buisson, D. A., Dauvois, V., Lesot, P., Chaudret, B., Rousseau, B., Feuillastre, S., & Pieters, G. (2018). Ruthenium-catalyzed hydrogen isotope exchange of C(sp. Chemical communications (Cambridge, England), 54(24), 2986-2989. https://doi.org/10.1039/c8cc00653a
Gao, Longhui, et al. "Ruthenium-catalyzed hydrogen isotope exchange of C(sp." Chemical communications (Cambridge, England) vol. 54,24 (2018): 2986-2989. doi: https://doi.org/10.1039/c8cc00653a
Gao L, Perato S, Garcia-Argote S, Taglang C, Martínez-Prieto LM, Chollet C, Buisson DA, Dauvois V, Lesot P, Chaudret B, Rousseau B, Feuillastre S, Pieters G. Ruthenium-catalyzed hydrogen isotope exchange of C(sp. Chem Commun (Camb). 2018 Mar 25;54(24):2986-2989. doi: 10.1039/c8cc00653a. Epub 2018 Mar 05. PMID: 29505052.
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Monitoring of nanoparticle reactivity in solution: interaction of l-lysine and Ru nanoparticles probed by chemical shift perturbation parallels regioselective H/D exchange.

Chemical communications (Cambridge, England)

Martínez-Prieto LM, Baquero EA, Pieters G, Flores JC, de Jesús E, Nayral C, Delpech F, van Leeuwen PWNM, Lippens G, Chaudret B.
PMID: 28504805
Chem Commun (Camb). 2017 May 30;53(43):5850-5853. doi: 10.1039/c7cc02445b.

Thanks to new water-soluble Ru nanoparticles (NPs) stabilized by sulfonated NHC ligands, we demonstrate that it is possible to monitor the catalyst/substrate interaction using NMR chemical shift perturbations (CSPs), under conditions that closely resemble those applied during the enantiospecific...

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Martínez-Prieto LM, Baquero EA, Pieters G, et al. Monitoring of nanoparticle reactivity in solution: interaction of l-lysine and Ru nanoparticles probed by chemical shift perturbation parallels regioselective H/D exchange. Chem Commun (Camb). 2017;53(43):5850-5853doi: 10.1039/c7cc02445b.
Martínez-Prieto, L. M., Baquero, E. A., Pieters, G., Flores, J. C., de Jesús, E., Nayral, C., Delpech, F., van Leeuwen, P. W. N. M., Lippens, G., & Chaudret, B. (2017). Monitoring of nanoparticle reactivity in solution: interaction of l-lysine and Ru nanoparticles probed by chemical shift perturbation parallels regioselective H/D exchange. Chemical communications (Cambridge, England), 53(43), 5850-5853. https://doi.org/10.1039/c7cc02445b
Martínez-Prieto, Luis M, et al. "Monitoring of nanoparticle reactivity in solution: interaction of l-lysine and Ru nanoparticles probed by chemical shift perturbation parallels regioselective H/D exchange." Chemical communications (Cambridge, England) vol. 53,43 (2017): 5850-5853. doi: https://doi.org/10.1039/c7cc02445b
Martínez-Prieto LM, Baquero EA, Pieters G, Flores JC, de Jesús E, Nayral C, Delpech F, van Leeuwen PWNM, Lippens G, Chaudret B. Monitoring of nanoparticle reactivity in solution: interaction of l-lysine and Ru nanoparticles probed by chemical shift perturbation parallels regioselective H/D exchange. Chem Commun (Camb). 2017 May 30;53(43):5850-5853. doi: 10.1039/c7cc02445b. PMID: 28504805.
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Ultrastable Magnetic Nanoparticles Encapsulated in Carbon for Magnetically Induced Catalysis.

ACS applied nano materials

Martínez-Prieto LM, Marbaix J, Asensio JM, Cerezo-Navarrete C, Fazzini PF, Soulantica K, Chaudret B, Corma A.
PMID: 32743352
ACS Appl Nano Mater. 2020 Jul 24;3(7):7076-7087. doi: 10.1021/acsanm.0c01392. Epub 2020 Jun 23.

Magnetically induced catalysis using magnetic nanoparticles (MagNPs) as heating agents is a new efficient method to perform reactions at high temperatures. However, the main limitation is the lack of stability of the catalysts operating in such harsh conditions. Normally,...

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Martínez-Prieto LM, Marbaix J, Asensio JM, et al. Ultrastable Magnetic Nanoparticles Encapsulated in Carbon for Magnetically Induced Catalysis. ACS Appl Nano Mater. 2020;3(7):7076-7087doi: 10.1021/acsanm.0c01392.
Martínez-Prieto, L. M., Marbaix, J., Asensio, J. M., Cerezo-Navarrete, C., Fazzini, P. F., Soulantica, K., Chaudret, B., & Corma, A. (2020). Ultrastable Magnetic Nanoparticles Encapsulated in Carbon for Magnetically Induced Catalysis. ACS applied nano materials, 3(7), 7076-7087. https://doi.org/10.1021/acsanm.0c01392
Martínez-Prieto, Luis M, et al. "Ultrastable Magnetic Nanoparticles Encapsulated in Carbon for Magnetically Induced Catalysis." ACS applied nano materials vol. 3,7 (2020): 7076-7087. doi: https://doi.org/10.1021/acsanm.0c01392
Martínez-Prieto LM, Marbaix J, Asensio JM, Cerezo-Navarrete C, Fazzini PF, Soulantica K, Chaudret B, Corma A. Ultrastable Magnetic Nanoparticles Encapsulated in Carbon for Magnetically Induced Catalysis. ACS Appl Nano Mater. 2020 Jul 24;3(7):7076-7087. doi: 10.1021/acsanm.0c01392. Epub 2020 Jun 23. PMID: 32743352; PMCID: PMC7386363.
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Zwitterionic amidinates as effective ligands for platinum nanoparticle hydrogenation catalysts.

Chemical science

Martínez-Prieto LM, Cano I, Márquez A, Baquero EA, Tricard S, Cusinato L, Del Rosal I, Poteau R, Coppel Y, Philippot K, Chaudret B, Cámpora J, van Leeuwen PWNM.
PMID: 28451359
Chem Sci. 2017 Apr 01;8(4):2931-2941. doi: 10.1039/c6sc05551f. Epub 2017 Feb 01.

Ligand control of metal nanoparticles (MNPs) is rapidly gaining importance as ligands can stabilize the MNPs and regulate their catalytic properties. Herein we report the first example of Pt NPs ligated by imidazolium-amidinate ligands that bind strongly through the...

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Martínez-Prieto LM, Cano I, Márquez A, et al. Zwitterionic amidinates as effective ligands for platinum nanoparticle hydrogenation catalysts. Chem Sci. 2017;8(4):2931-2941doi: 10.1039/c6sc05551f.
Martínez-Prieto, L. M., Cano, I., Márquez, A., Baquero, E. A., Tricard, S., Cusinato, L., Del Rosal, I., Poteau, R., Coppel, Y., Philippot, K., Chaudret, B., Cámpora, J., & van Leeuwen, P. W. N. M. (2017). Zwitterionic amidinates as effective ligands for platinum nanoparticle hydrogenation catalysts. Chemical science, 8(4), 2931-2941. https://doi.org/10.1039/c6sc05551f
Martínez-Prieto, L M, et al. "Zwitterionic amidinates as effective ligands for platinum nanoparticle hydrogenation catalysts." Chemical science vol. 8,4 (2017): 2931-2941. doi: https://doi.org/10.1039/c6sc05551f
Martínez-Prieto LM, Cano I, Márquez A, Baquero EA, Tricard S, Cusinato L, Del Rosal I, Poteau R, Coppel Y, Philippot K, Chaudret B, Cámpora J, van Leeuwen PWNM. Zwitterionic amidinates as effective ligands for platinum nanoparticle hydrogenation catalysts. Chem Sci. 2017 Apr 01;8(4):2931-2941. doi: 10.1039/c6sc05551f. Epub 2017 Feb 01. PMID: 28451359; PMCID: PMC5376718.
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A combined theoretical/experimental study highlighting the formation of carbides on Ru nanoparticles during CO hydrogenation.

Nanoscale

Moraru IT, Martínez-Prieto LM, Coppel Y, Chaudret B, Cusinato L, Del Rosal I, Poteau R.
PMID: 33885491
Nanoscale. 2021 Apr 14;13(14):6902-6915. doi: 10.1039/d0nr08735a. Epub 2021 Apr 01.

Formation of stable carbides during CO bond dissociation on small ruthenium nanoparticles (RuNPs) is demonstrated, both by means of DFT calculations and by solid state

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Moraru IT, Martínez-Prieto LM, Coppel Y, et al. A combined theoretical/experimental study highlighting the formation of carbides on Ru nanoparticles during CO hydrogenation. Nanoscale. 2021;13(14):6902-6915doi: 10.1039/d0nr08735a.
Moraru, I. T., Martínez-Prieto, L. M., Coppel, Y., Chaudret, B., Cusinato, L., Del Rosal, I., & Poteau, R. (2021). A combined theoretical/experimental study highlighting the formation of carbides on Ru nanoparticles during CO hydrogenation. Nanoscale, 13(14), 6902-6915. https://doi.org/10.1039/d0nr08735a
Moraru, Ionut-Tudor, et al. "A combined theoretical/experimental study highlighting the formation of carbides on Ru nanoparticles during CO hydrogenation." Nanoscale vol. 13,14 (2021): 6902-6915. doi: https://doi.org/10.1039/d0nr08735a
Moraru IT, Martínez-Prieto LM, Coppel Y, Chaudret B, Cusinato L, Del Rosal I, Poteau R. A combined theoretical/experimental study highlighting the formation of carbides on Ru nanoparticles during CO hydrogenation. Nanoscale. 2021 Apr 14;13(14):6902-6915. doi: 10.1039/d0nr08735a. Epub 2021 Apr 01. PMID: 33885491.
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Comparative efficacy of tisagenlecleucel and lisocabtagene maraleucel among adults with relapsed/refractory large B-cell lymphomas: an indirect treatment comparison.

Leukemia & lymphoma

Schuster SJ, Zhang J, Yang H, Agarwal A, Tang W, Martinez-Prieto M, Bollu V, Kuzan D, Maziarz RT, Kersten MJ.
PMID: 34978255
Leuk Lymphoma. 2022 Jan 02;1-10. doi: 10.1080/10428194.2021.2010069. Epub 2022 Jan 02.

This study compared overall survival (OS), progression-free survival (PFS), complete response rate (CRR), and overall response rate (ORR) of tisagenlecleucel (tisa-cel) and lisocabtagene maraleucel (liso-cel) in relapsed or refractory large B-cell lymphomas (r/r LBCL). Using matching-adjusted indirect comparison (MAIC),...

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Schuster SJ, Zhang J, Yang H, et al. Comparative efficacy of tisagenlecleucel and lisocabtagene maraleucel among adults with relapsed/refractory large B-cell lymphomas: an indirect treatment comparison. Leuk Lymphoma. 2022;1-10doi: 10.1080/10428194.2021.2010069.
Schuster, S. J., Zhang, J., Yang, H., Agarwal, A., Tang, W., Martinez-Prieto, M., Bollu, V., Kuzan, D., Maziarz, R. T., & Kersten, M. J. (2022). Comparative efficacy of tisagenlecleucel and lisocabtagene maraleucel among adults with relapsed/refractory large B-cell lymphomas: an indirect treatment comparison. Leukemia & lymphoma, 1-10. https://doi.org/10.1080/10428194.2021.2010069
Schuster, Stephen J, et al. "Comparative efficacy of tisagenlecleucel and lisocabtagene maraleucel among adults with relapsed/refractory large B-cell lymphomas: an indirect treatment comparison." Leukemia & lymphoma vol. (2022): 1-10. doi: https://doi.org/10.1080/10428194.2021.2010069
Schuster SJ, Zhang J, Yang H, Agarwal A, Tang W, Martinez-Prieto M, Bollu V, Kuzan D, Maziarz RT, Kersten MJ. Comparative efficacy of tisagenlecleucel and lisocabtagene maraleucel among adults with relapsed/refractory large B-cell lymphomas: an indirect treatment comparison. Leuk Lymphoma. 2022 Jan 02;1-10. doi: 10.1080/10428194.2021.2010069. Epub 2022 Jan 02. PMID: 34978255.
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Long-chain NHC-stabilized RuNPs as versatile catalysts for one-pot oxidation/hydrogenation reactions.

Chemical communications (Cambridge, England)

Martínez-Prieto LM, Ferry A, Rakers L, Richter C, Lecante P, Philippot K, Chaudret B, Glorius F.
PMID: 26934988
Chem Commun (Camb). 2016 Apr 04;52(26):4768-71. doi: 10.1039/c6cc01130f. Epub 2016 Mar 03.

The synthesis and catalytic activity of long-chain NHC-stabilized RuNPs are presented. Full characterization of these novel nanostructures including surface state studies show that the ligand influences the number and the location of Ru active sites which impacts the NP...

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Martínez-Prieto LM, Ferry A, Rakers L, et al. Long-chain NHC-stabilized RuNPs as versatile catalysts for one-pot oxidation/hydrogenation reactions. Chem Commun (Camb). 2016;52(26):4768-71doi: 10.1039/c6cc01130f.
Martínez-Prieto, L. M., Ferry, A., Rakers, L., Richter, C., Lecante, P., Philippot, K., Chaudret, B., & Glorius, F. (2016). Long-chain NHC-stabilized RuNPs as versatile catalysts for one-pot oxidation/hydrogenation reactions. Chemical communications (Cambridge, England), 52(26), 4768-71. https://doi.org/10.1039/c6cc01130f
Martínez-Prieto, L M, et al. "Long-chain NHC-stabilized RuNPs as versatile catalysts for one-pot oxidation/hydrogenation reactions." Chemical communications (Cambridge, England) vol. 52,26 (2016): 4768-71. doi: https://doi.org/10.1039/c6cc01130f
Martínez-Prieto LM, Ferry A, Rakers L, Richter C, Lecante P, Philippot K, Chaudret B, Glorius F. Long-chain NHC-stabilized RuNPs as versatile catalysts for one-pot oxidation/hydrogenation reactions. Chem Commun (Camb). 2016 Apr 04;52(26):4768-71. doi: 10.1039/c6cc01130f. Epub 2016 Mar 03. PMID: 26934988.
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Characterization of secondary phosphine oxide ligands on the surface of iridium nanoparticles.

Physical chemistry chemical physics : PCCP

Cano I, Martínez-Prieto LM, Fazzini PF, Coppel Y, Chaudret B, van Leeuwen PWNM.
PMID: 28766603
Phys Chem Chem Phys. 2017 Aug 16;19(32):21655-21662. doi: 10.1039/c7cp03439c.

The synthesis of iridium nanoparticles (IrNPs) ligated by various secondary phosphine oxides (SPOs) is described. This highly reproducible and simple method via H

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Cano I, Martínez-Prieto LM, Fazzini PF, et al. Characterization of secondary phosphine oxide ligands on the surface of iridium nanoparticles. Phys Chem Chem Phys. 2017;19(32):21655-21662doi: 10.1039/c7cp03439c.
Cano, I., Martínez-Prieto, L. M., Fazzini, P. F., Coppel, Y., Chaudret, B., & van Leeuwen, P. W. N. M. (2017). Characterization of secondary phosphine oxide ligands on the surface of iridium nanoparticles. Physical chemistry chemical physics : PCCP, 19(32), 21655-21662. https://doi.org/10.1039/c7cp03439c
Cano, Israel, et al. "Characterization of secondary phosphine oxide ligands on the surface of iridium nanoparticles." Physical chemistry chemical physics : PCCP vol. 19,32 (2017): 21655-21662. doi: https://doi.org/10.1039/c7cp03439c
Cano I, Martínez-Prieto LM, Fazzini PF, Coppel Y, Chaudret B, van Leeuwen PWNM. Characterization of secondary phosphine oxide ligands on the surface of iridium nanoparticles. Phys Chem Chem Phys. 2017 Aug 16;19(32):21655-21662. doi: 10.1039/c7cp03439c. PMID: 28766603.
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Showing 1 to 12 of 28 entries