Display options
Cite
Zhang H, Zhang M, Lin P, et al. A Highly Energetic N-Rich Metal-Organic Framework as a New High-Energy-Density Material. Chemistry. 2015;22(3):1141-5doi: 10.1002/chem.201503561.
Zhang, H., Zhang, M., Lin, P., Malgras, V., Tang, J., Alshehri, S. M., Yamauchi, Y., Du, S., & Zhang, J. (2016). A Highly Energetic N-Rich Metal-Organic Framework as a New High-Energy-Density Material. Chemistry (Weinheim an der Bergstrasse, Germany), 22(3), 1141-5. https://doi.org/10.1002/chem.201503561
Zhang, Huabin, et al. "A Highly Energetic N-Rich Metal-Organic Framework as a New High-Energy-Density Material." Chemistry (Weinheim an der Bergstrasse, Germany) vol. 22,3 (2016): 1141-5. doi: https://doi.org/10.1002/chem.201503561
Zhang H, Zhang M, Lin P, Malgras V, Tang J, Alshehri SM, Yamauchi Y, Du S, Zhang J. A Highly Energetic N-Rich Metal-Organic Framework as a New High-Energy-Density Material. Chemistry. 2016 Jan 18;22(3):1141-5. doi: 10.1002/chem.201503561. Epub 2015 Dec 10. PMID: 26663482.
Copy Download .nbib Format: NLM
Share it on

Chemistry. 2016 Jan 18;22(3):1141-5. doi: 10.1002/chem.201503561. Epub 2015 Dec 10.

A Highly Energetic N-Rich Metal-Organic Framework as a New High-Energy-Density Material.

Chemistry (Weinheim an der Bergstrasse, Germany)

Huabin Zhang, Mingjian Zhang, Ping Lin, Victor Malgras, Jing Tang, Saad M Alshehri, Yusuke Yamauchi, Shaowu Du, Jian Zhang

Affiliations

  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences Fuzhou, Fujian, 350002, P. R. China.
  2. World Premier International (WPI) Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki, 305-0044, Japan.
  3. Faculty of Science and Engineering, Waseda University, 3-, 4-1 Okubo, Shinjuku, Tokyo, 169-0072, Japan.
  4. Department of Chemistry, College of Science, King Saud University, Riyadh, 11451, Saudi Arabia.
  5. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences Fuzhou, Fujian, 350002, P. R. China. [email protected].
  6. Faculty of Science and Engineering, Waseda University, 3-, 4-1 Okubo, Shinjuku, Tokyo, 169-0072, Japan. [email protected].
  7. Department of Chemistry, College of Science, King Saud University, Riyadh, 11451, Saudi Arabia. [email protected].
  8. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences Fuzhou, Fujian, 350002, P. R. China. [email protected].
  9. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences Fuzhou, Fujian, 350002, P. R. China. [email protected].

PMID: 26663482 DOI: 10.1002/chem.201503561

Abstract

Metal-organic framework (MOF)-based energetic material [Cu3 (MA)2 (N3 )3 ] (1; MA=melamine) was synthesized and structurally characterized (47.55 % N). The structural analysis revealed the existence of unusual multiwalled tubular channels and interweaving of single and double helical units in 1. The standard molar enthalpy of formation was found to be 1788.73 kJ mol(-1) , which is the highest value among previously reported MOF-based energetic materials. The calculated detonation properties showed that 1 can be used as a potential explosive. Sensitivity tests revealed that 1 is insensitive and thus can function as a high-energy-density material with a favorable level of safety.

© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: N ligands; helical structures; high-energy materials; hydrothermal synthesis; metal-organic frameworks

Publication Types