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Pöppler AC, Demers JP, Malon M, et al. Ultrafast Magic-Angle Spinning: Benefits for the Acquisition of Ultrawide-Line NMR Spectra of Heavy Spin-1/2 Nuclei. Chemphyschem. 2016;17(6):812-6doi: 10.1002/cphc.201501136.
Pöppler, A. C., Demers, J. P., Malon, M., Singh, A. P., Roesky, H. W., Nishiyama, Y., & Lange, A. (2016). Ultrafast Magic-Angle Spinning: Benefits for the Acquisition of Ultrawide-Line NMR Spectra of Heavy Spin-1/2 Nuclei. Chemphyschem : a European journal of chemical physics and physical chemistry, 17(6), 812-6. https://doi.org/10.1002/cphc.201501136
Pöppler, Ann-Christin, et al. "Ultrafast Magic-Angle Spinning: Benefits for the Acquisition of Ultrawide-Line NMR Spectra of Heavy Spin-1/2 Nuclei." Chemphyschem : a European journal of chemical physics and physical chemistry vol. 17,6 (2016): 812-6. doi: https://doi.org/10.1002/cphc.201501136
Pöppler AC, Demers JP, Malon M, Singh AP, Roesky HW, Nishiyama Y, Lange A. Ultrafast Magic-Angle Spinning: Benefits for the Acquisition of Ultrawide-Line NMR Spectra of Heavy Spin-1/2 Nuclei. Chemphyschem. 2016 Mar 16;17(6):812-6. doi: 10.1002/cphc.201501136. Epub 2016 Jan 28. PMID: 26699375.
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Chemphyschem. 2016 Mar 16;17(6):812-6. doi: 10.1002/cphc.201501136. Epub 2016 Jan 28.

Ultrafast Magic-Angle Spinning: Benefits for the Acquisition of Ultrawide-Line NMR Spectra of Heavy Spin-1/2 Nuclei.

Chemphyschem : a European journal of chemical physics and physical chemistry

Ann-Christin Pöppler, Jean-Philippe Demers, Michal Malon, Amit Pratap Singh, Herbert W Roesky, Yusuke Nishiyama, Adam Lange

Affiliations

  1. Department for NMR-based Structural Biology, Max Planck Institute for Biophysical Chemistry, Am Fassberg 11, 37077, Göttingen, Germany.
  2. Department of Molecular Biophysics, Leibniz-Institut für Molekulare Pharmakologie (FMP), 13125, Berlin, Germany.
  3. Institut für Biologie, Humboldt-Universität zu Berlin, 10115, Berlin, Germany.
  4. Department for NMR-based Structural Biology, Max Planck Institute for Biophysical Chemistry, Am Fassberg 11, 37077, Göttingen, Germany. [email protected].
  5. Department of Molecular Biophysics, Leibniz-Institut für Molekulare Pharmakologie (FMP), 13125, Berlin, Germany. [email protected].
  6. Institut für Biologie, Humboldt-Universität zu Berlin, 10115, Berlin, Germany. [email protected].
  7. JEOL RESONANCE Inc., 3-1-2 Musashino, Akishima, Tokyo, 196-8558, Japan.
  8. RIKEN CLST-JEOL Collaboration Center, Suehiro-cho, Tsurumi, Yokohama, Kanagawa, 230-0045, Japan.
  9. Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077, Göttingen, Germany.
  10. JEOL RESONANCE Inc., 3-1-2 Musashino, Akishima, Tokyo, 196-8558, Japan. [email protected].
  11. RIKEN CLST-JEOL Collaboration Center, Suehiro-cho, Tsurumi, Yokohama, Kanagawa, 230-0045, Japan. [email protected].
  12. Department for NMR-based Structural Biology, Max Planck Institute for Biophysical Chemistry, Am Fassberg 11, 37077, Göttingen, Germany. [email protected].
  13. Department of Molecular Biophysics, Leibniz-Institut für Molekulare Pharmakologie (FMP), 13125, Berlin, Germany. [email protected].
  14. Institut für Biologie, Humboldt-Universität zu Berlin, 10115, Berlin, Germany. [email protected].

PMID: 26699375 DOI: 10.1002/cphc.201501136

Abstract

The benefits of the ultrafast magic-angle spinning (MAS) approach for the acquisition of ultrawide-line NMR spectra-spectral simplification, increased mass sensitivity allowing the fast study of small amounts of material, efficient excitation, and application to multiple heavy nuclei-are demonstrated for tin(II) oxide (SnO) and the tin complex [(LB)Sn(II) Cl](+) [Sn(II) Cl3 ](-) [LB=2,6-diacetylpyridinebis(2,6-diisopropylanil)] containing two distinct tin environments. The ultrafast MAS experiments provide optimal conditions for the extraction of the chemical-shift anisotropy tensor parameters, anisotropy, and asymmetry for heavy spin-1/2 nuclei.

© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: NMR spectroscopy; chemical shift anisotropy; heavy spin-1/2 nuclei; magic angle spinning; tin

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