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Williams DE, Dolgopolova EA, Godfrey DC, et al. Fulleretic Well-Defined Scaffolds: Donor-Fullerene Alignment Through Metal Coordination and Its Effect on Photophysics. Angew Chem Int Ed Engl. 2016;55(31):9070-4doi: 10.1002/anie.201603584.
Williams, D. E., Dolgopolova, E. A., Godfrey, D. C., Ermolaeva, E. D., Pellechia, P. J., Greytak, A. B., Smith, M. D., Avdoshenko, S. M., Popov, A. A., & Shustova, N. B. (2016). Fulleretic Well-Defined Scaffolds: Donor-Fullerene Alignment Through Metal Coordination and Its Effect on Photophysics. Angewandte Chemie (International ed. in English), 55(31), 9070-4. https://doi.org/10.1002/anie.201603584
Williams, Derek E, et al. "Fulleretic Well-Defined Scaffolds: Donor-Fullerene Alignment Through Metal Coordination and Its Effect on Photophysics." Angewandte Chemie (International ed. in English) vol. 55,31 (2016): 9070-4. doi: https://doi.org/10.1002/anie.201603584
Williams DE, Dolgopolova EA, Godfrey DC, Ermolaeva ED, Pellechia PJ, Greytak AB, Smith MD, Avdoshenko SM, Popov AA, Shustova NB. Fulleretic Well-Defined Scaffolds: Donor-Fullerene Alignment Through Metal Coordination and Its Effect on Photophysics. Angew Chem Int Ed Engl. 2016 Jul 25;55(31):9070-4. doi: 10.1002/anie.201603584. Epub 2016 Jun 06. PMID: 27265385; PMCID: PMC4957671.
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Angew Chem Int Ed Engl. 2016 Jul 25;55(31):9070-4. doi: 10.1002/anie.201603584. Epub 2016 Jun 06.

Fulleretic Well-Defined Scaffolds: Donor-Fullerene Alignment Through Metal Coordination and Its Effect on Photophysics.

Angewandte Chemie (International ed. in English)

Derek E Williams, Ekaterina A Dolgopolova, Danielle C Godfrey, Evgeniya D Ermolaeva, Perry J Pellechia, Andrew B Greytak, Mark D Smith, Stanislav M Avdoshenko, Alexey A Popov, Natalia B Shustova

Affiliations

  1. Department of Chemistry and Biochemistry, The University of South Carolina, 631 Sumter Street, Columbia, SC, 29208, USA.
  2. Leibniz Institute for Solid State and Materials Research, 01069, Dresden, Germany.
  3. Leibniz Institute for Solid State and Materials Research, 01069, Dresden, Germany. [email protected].
  4. Department of Chemistry and Biochemistry, The University of South Carolina, 631 Sumter Street, Columbia, SC, 29208, USA. [email protected].

PMID: 27265385 PMCID: PMC4957671 DOI: 10.1002/anie.201603584

Abstract

Herein, we report the first example of a crystalline metal-donor-fullerene framework, in which control of the donor-fullerene mutual orientation was achieved through chemical bond formation, in particular, by metal coordination. The (13) C cross-polarization magic-angle spinning NMR spectroscopy, X-ray diffraction, and time-resolved fluorescence spectroscopy were performed for comprehensive structural analysis and energy-transfer (ET) studies of the fulleretic donor-acceptor scaffold. Furthermore, in combination with photoluminescence measurements, the theoretical calculations of the spectral overlap function, Förster radius, excitation energies, and band structure were employed to elucidate the photophysical and ET processes in the prepared fulleretic material. We envision that the well-defined fulleretic donor-acceptor materials could contribute not only to the basic science of fullerene chemistry but would also be used towards effective development of organic photovoltaics and molecular electronics.

© 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

Keywords: charge transfer; coordination polymers; energy transfer; fullerenes; metal-organic frameworks

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