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Ni H, Qiu Z, Xie Z. Photoarylation of Iodocarboranes with Unactivated (Hetero)Arenes: Facile Synthesis of 1,2-[(Hetero)Aryl]. Angew Chem Int Ed Engl. 2016;56(3):712-716doi: 10.1002/anie.201610810.
Ni, H., Qiu, Z., & Xie, Z. (2017). Photoarylation of Iodocarboranes with Unactivated (Hetero)Arenes: Facile Synthesis of 1,2-[(Hetero)Aryl]. Angewandte Chemie (International ed. in English), 56(3), 712-716. https://doi.org/10.1002/anie.201610810
Ni, Hangcheng, et al. "Photoarylation of Iodocarboranes with Unactivated (Hetero)Arenes: Facile Synthesis of 1,2-[(Hetero)Aryl]." Angewandte Chemie (International ed. in English) vol. 56,3 (2017): 712-716. doi: https://doi.org/10.1002/anie.201610810
Ni H, Qiu Z, Xie Z. Photoarylation of Iodocarboranes with Unactivated (Hetero)Arenes: Facile Synthesis of 1,2-[(Hetero)Aryl]. Angew Chem Int Ed Engl. 2017 Jan 16;56(3):712-716. doi: 10.1002/anie.201610810. Epub 2016 Dec 19. PMID: 27990728.
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Angew Chem Int Ed Engl. 2017 Jan 16;56(3):712-716. doi: 10.1002/anie.201610810. Epub 2016 Dec 19.

Photoarylation of Iodocarboranes with Unactivated (Hetero)Arenes: Facile Synthesis of 1,2-[(Hetero)Aryl].

Angewandte Chemie (International ed. in English)

Hangcheng Ni, Zaozao Qiu, Zuowei Xie

Affiliations

  1. Department of Chemistry and State Key Laboratory of Synthetic Chemistry, The Chinese University of Hong Kong, Shatin, N.T., Hong Kong, China.
  2. Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, China.

PMID: 27990728 DOI: 10.1002/anie.201610810

Abstract

Photoarylation of iodocarboranes with unactivated arenes/heteroarenes at room temperature has been achieved, for the first time, thus leading to the facile synthesis of a large variety of cage carbon mono(hetero)arylated and di(hetero)arylated o-carboranes. This work represents a clean, efficient, transition-metal-free, and cheap synthesis of functionalized carboranes, which has significant advantages over the known methods.

© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: arenes; carboranes; cross-coupling; photochemistry; radicals

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