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Chemistry. 2017 Apr 27;23(24):5830-5841. doi: 10.1002/chem.201700757. Epub 2017 Apr 05.

Highly Electron-Rich β-Diketiminato Systems: Synthesis and Coordination Chemistry of Amino-Functionalized "N-nacnac" Ligands.

Chemistry (Weinheim an der Bergstrasse, Germany)

Dinh Cao Huan Do, Ailsa Keyser, Andrey V Protchenko, Brant Maitland, Indrek Pernik, Haoyu Niu, Eugene L Kolychev, Arnab Rit, Dragoslav Vidovic, Andreas Stasch, Cameron Jones, Simon Aldridge

Affiliations

  1. Department of Chemistry, University of Oxford, Inorganic Chemistry Laboratory, South Parks Road, OX1 3QR, Oxford, UK.
  2. School of Chemistry, Monash University, PO Box 23, Melbourne, Victoria, 3800, Australia.
  3. SPMS-CBC, Nanyang Technological University, 21 Nanyang Link, Singapore, 637371, Singapore.
  4. Present address: EaStCHEM School of Chemistry, University of St Andrews, North Haugh, St Andrews, KY16 9ST, UK.

PMID: 28256015 DOI: 10.1002/chem.201700757

Abstract

The synthesis of a class of electron-rich amino-functionalized β-diketiminato (N-nacnac) ligands is reported, with two synthetic methodologies having been developed for systems bearing backbone NMe

© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: coordination chemistry; electron-rich compounds; ligand design; main group chemistry; nacnac ligands

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