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Opt Lett. 2017 Jun 01;42(11):2157-2160. doi: 10.1364/OL.42.002157.

Electro-optical effects of high aspect ratio P3HT nanofibers colloid in polymer micro-fluid cells.

Optics letters

G S Lobov, A Marinins, R Zandi Shafagh, Y Zhao, W van der Wijngaart, L Wosinski, L Thylen, M S Toprak, T Haraldsson, M Östling, S Popov

PMID: 28569870 DOI: 10.1364/OL.42.002157

Abstract

This Letter reports the electro-optical (EO) effect of Poly(3-hexylthiophene-2,5-diyl) (P3HT) nanofibers colloid in a polymer micro-fluidic EO cell. P3HT nanofibers are high aspect ratio semiconducting nanostructures, and can be collectively aligned by an external alternating electric field. Optical transmission modulated by the electric field is a manifestation of the electro-optical effect due to high inner crystallinity of P3HT nanofibers. According to our results, the degree of alignment reaches a maximum at 0.6 V/μm of electric field strength, implying a big polarizability value due to geometry and electrical properties of P3HT nanofibers. We believe that one-dimensional crystalline organic nanostructures have a large potential in EO devices due to their significant anisotropy, wide variety of properties, low actuation voltages, and opportunity to be tailored via adjustment of the fabrication process.

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