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Desai SP, Malonzo CD, Webber T, et al. Assembly of dicobalt and cobalt-aluminum oxide clusters on metal-organic framework and nanocast silica supports. Faraday Discuss. 2017;201:287-302doi: 10.1039/c7fd00055c.
Desai, S. P., Malonzo, C. D., Webber, T., Duan, J., Thompson, A. B., Tereniak, S. J., DeStefano, M. R., Buru, C. T., Li, Z., Penn, R. L., Farha, O. K., Hupp, J. T., Stein, A., & Lu, C. C. (2017). Assembly of dicobalt and cobalt-aluminum oxide clusters on metal-organic framework and nanocast silica supports. Faraday discussions, 201287-302. https://doi.org/10.1039/c7fd00055c
Desai, Sai Puneet, et al. "Assembly of dicobalt and cobalt-aluminum oxide clusters on metal-organic framework and nanocast silica supports." Faraday discussions vol. 201 (2017): 287-302. doi: https://doi.org/10.1039/c7fd00055c
Desai SP, Malonzo CD, Webber T, Duan J, Thompson AB, Tereniak SJ, DeStefano MR, Buru CT, Li Z, Penn RL, Farha OK, Hupp JT, Stein A, Lu CC. Assembly of dicobalt and cobalt-aluminum oxide clusters on metal-organic framework and nanocast silica supports. Faraday Discuss. 2017 Sep 01;201:287-302. doi: 10.1039/c7fd00055c. Epub 2017 Jun 20. PMID: 28631795.
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Faraday Discuss. 2017 Sep 01;201:287-302. doi: 10.1039/c7fd00055c. Epub 2017 Jun 20.

Assembly of dicobalt and cobalt-aluminum oxide clusters on metal-organic framework and nanocast silica supports.

Faraday discussions

Sai Puneet Desai, Camille D Malonzo, Thomas Webber, Jiaxin Duan, Anthony B Thompson, Stephen J Tereniak, Matthew R DeStefano, Cassandra T Buru, Zhanyong Li, R Lee Penn, Omar K Farha, Joseph T Hupp, Andreas Stein, Connie C Lu

Affiliations

  1. Department of Chemistry, University of Minnesota, Minneapolis, Minnesota 55455, USA. [email protected] [email protected].

PMID: 28631795 DOI: 10.1039/c7fd00055c

Abstract

NU-1000, a mesoporous metal-organic framework (MOF) featuring hexazirconium oxide nodes and 3 nm wide channels, was infiltrated with a reactive dicobalt complex to install dicobalt active sites onto the MOF nodes. The anchoring of the dicobalt complex onto NU-1000 occurred with a nearly ideal stoichiometry of one bimetallic complex per node and with the cobalt evenly distributed throughout the MOF particle. To access thermally robust multimetallic sites on an all-inorganic support, the modified NU-1000 materials containing either the dicobalt complex, or an analogous cobalt-aluminum species, were nanocast with silica. The resulting materials feature Co

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