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Showing 1 to 12 of 506 entries
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Perfluoroalkane functionalization of NU-1000 via solvent-assisted ligand incorporation: synthesis and CO2 adsorption studies.

Journal of the American Chemical Society

Deria P, Mondloch JE, Tylianakis E, Ghosh P, Bury W, Snurr RQ, Hupp JT, Farha OK.
PMID: 24175709
J Am Chem Soc. 2013 Nov 13;135(45):16801-4. doi: 10.1021/ja408959g. Epub 2013 Oct 31.

A new functionalization technique, solvent-assisted ligand incorporation (SALI), was developed to efficiently incorporate carboxylate-based functionalities in the Zr-based metal-organic framework, NU-1000. Unlike previous metal node functionalization strategies, which utilize dative bonding to coordinatively unsaturated metal sites, SALI introduces functional...

Optimizing Toxic Chemical Removal through Defect-Induced UiO-66-NH.

Chemistry (Weinheim an der Bergstrasse, Germany)

Peterson GW, Destefano MR, Garibay SJ, Ploskonka A, McEntee M, Hall M, Karwacki CJ, Hupp JT, Farha OK.
PMID: 28949042
Chemistry. 2017 Nov 13;23(63):15913-15916. doi: 10.1002/chem.201704525. Epub 2017 Oct 24.

For the first time, an increasing number of defects were introduced to the metal-organic framework UiO-66-NH

Reply.

Muscle & nerve

Farhad K, Brannagan TH.
PMID: 27701749
Muscle Nerve. 2017 Feb;55(2):291. doi: 10.1002/mus.25427. Epub 2016 Nov 04.

No abstract available.

Atomically Precise Growth of Catalytically Active Cobalt Sulfide on Flat Surfaces and within a Metal-Organic Framework via Atomic Layer Deposition.

ACS nano

Peters AW, Li Z, Farha OK, Hupp JT.
PMID: 26241521
ACS Nano. 2015 Aug 25;9(8):8484-90. doi: 10.1021/acsnano.5b03429. Epub 2015 Aug 04.

Atomic layer deposition (ALD) has been employed as a new synthetic route to thin films of cobalt sulfide on silicon and fluorine-doped tin oxide platforms. The self-limiting nature of the stepwise synthesis is established through growth rate studies at...

Visualization of Hyperconjugation and Subsequent Structural Distortions through 3D Printing of Crystal Structures.

Letters in organic chemistry

Mithila FJ, Oyola-Reynoso S, Thuo MM, Atkinson MB.
PMID: 28659727
Lett Org Chem. 2016;13(4):272-276. doi: 10.2174/1570178613666160204010454.

BACKGROUND: Structural distortions due to hyperconjugation in organic molecules, like norbornenes, are well captured through X-ray crystallographic data, but are sometimes difficult to visualize especially for those applying chemical knowledge and are not chemists.METHODS: Crystal structure from the Cambridge...

Clinical characterization and survival of patients with borderline elevation in pulmonary artery pressure.

Pulmonary circulation

Heresi GA, Minai OA, Tonelli AR, Hammel JP, Farha S, Parambil JG, Dweik RA.
PMID: 25006408
Pulm Circ. 2013 Dec;3(4):916-25. doi: 10.1086/674756.

Normal resting mean pulmonary artery pressure (PAP) is 8-20 mmHg. Pulmonary hypertension is defined as mean PAP of ≥25 mmHg. Borderline PAP levels of 21-24 mmHg are of unclear significance. We sought to determine the clinical characteristics and survival...

Ultrahigh surface area zirconium MOFs and insights into the applicability of the BET theory.

Journal of the American Chemical Society

Wang TC, Bury W, Gómez-Gualdrón DA, Vermeulen NA, Mondloch JE, Deria P, Zhang K, Moghadam PZ, Sarjeant AA, Snurr RQ, Stoddart JF, Hupp JT, Farha OK.
PMID: 25723400
J Am Chem Soc. 2015 Mar 18;137(10):3585-91. doi: 10.1021/ja512973b. Epub 2015 Mar 09.

An isoreticular series of metal-organic frameworks (MOFs) with the ftw topology based on zirconium oxoclusters and tetracarboxylate linkers with a planar core (NU-1101 through NU-1104) has been synthesized employing a linker expansion approach. In this series, NU-1103 has a...

Melt-Quenched Glasses of Metal-Organic Frameworks.

Journal of the American Chemical Society

Bennett TD, Yue Y, Li P, Qiao A, Tao H, Greaves NG, Richards T, Lampronti GI, Redfern SA, Blanc F, Farha OK, Hupp JT, Cheetham AK, Keen DA.
PMID: 26885940
J Am Chem Soc. 2016 Mar 16;138(10):3484-92. doi: 10.1021/jacs.5b13220. Epub 2016 Mar 02.

Crystalline solids dominate the field of metal-organic frameworks (MOFs), with access to the liquid and glass states of matter usually prohibited by relatively low temperatures of thermal decomposition. In this work, we give due consideration to framework chemistry and...

The Acute Impact of Smoking One Cigarette on Cardiac Hemodynamic Parameters.

Cardiology research

Farha KA, AbouFarha R, Bolt M.
PMID: 28348663
Cardiol Res. 2011 Apr;2(2):58-65. doi: 10.4021/cr24e. Epub 2011 Mar 25.

BACKGROUND: The acute impact of tobacco smoking on the cardiac hemodynamic parameters and its pathological implication in the process of arterial atherosclerosis need further exploration. This investigation was purposed to assess the acute impact of tobacco smoke on blood...

Correlation between QRS Duration, Pulmonary Insufficiency and Right Ventricle Performance in Totally Corrected Tetralogy of Fallot.

Iranian journal of pediatrics

Tanasan A, Kocharian A, Zanjani KS, Payravian FK, Torabian S.
PMID: 24800023
Iran J Pediatr. 2013 Oct;23(5):593-6.

OBJECTIVE: Despite progresses in surgical correction of Tetralogy of Fallot, pulmonary insufficiency and progressive dysfunction of the right ventricle impress its long-term prognosis. In this study we examined the correlations between QRS duration, pulmonary insufficiency and right ventricular performance...

MOF functionalization via solvent-assisted ligand incorporation: phosphonates vs carboxylates.

Inorganic chemistry

Deria P, Bury W, Hod I, Kung CW, Karagiaridi O, Hupp JT, Farha OK.
PMID: 25665089
Inorg Chem. 2015 Mar 02;54(5):2185-92. doi: 10.1021/ic502639v. Epub 2015 Feb 09.

Solvent-assisted ligand incorporation (SALI) is useful for functionalizing the channels of metal-organic framework (MOF) materials such as NU-1000 that offer substitutionally labile zirconium(IV) coordination sites for nonbridging ligands. Each of the 30 or so previous examples relied upon coordination...

Modulating the rate of charge transport in a metal-organic framework thin film using host:guest chemistry.

Chemical communications (Cambridge, England)

Hod I, Farha OK, Hupp JT.
PMID: 26666952
Chem Commun (Camb). 2016 Jan 28;52(8):1705-8. doi: 10.1039/c5cc09695b. Epub 2015 Dec 15.

Herein we demonstrate the use of host-guest chemistry to modulate rates of charge transport in metal-organic framework (MOF) films. The kinetics of site-to-site of charge hopping and, in turn, the overall redox conductivity, of a ferrocene-modified MOF can be...

Showing 1 to 12 of 506 entries