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Chen Q, Feng R, Xu J, et al. Kinetic and Thermodynamic Control of Structure Transformations in a Family of Cobalt(II)-Organic Frameworks. ACS Appl Mater Interfaces. 2017;9(40):35141-35149doi: 10.1021/acsami.7b12925.
Chen, Q., Feng, R., Xu, J., Jia, Y. Y., Wang, T. T., Chang, Z., & Bu, X. H. (2017). Kinetic and Thermodynamic Control of Structure Transformations in a Family of Cobalt(II)-Organic Frameworks. ACS applied materials & interfaces, 9(40), 35141-35149. https://doi.org/10.1021/acsami.7b12925
Chen, Qiang, et al. "Kinetic and Thermodynamic Control of Structure Transformations in a Family of Cobalt(II)-Organic Frameworks." ACS applied materials & interfaces vol. 9,40 (2017): 35141-35149. doi: https://doi.org/10.1021/acsami.7b12925
Chen Q, Feng R, Xu J, Jia YY, Wang TT, Chang Z, Bu XH. Kinetic and Thermodynamic Control of Structure Transformations in a Family of Cobalt(II)-Organic Frameworks. ACS Appl Mater Interfaces. 2017 Oct 11;9(40):35141-35149. doi: 10.1021/acsami.7b12925. Epub 2017 Oct 02. PMID: 28920665.
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ACS Appl Mater Interfaces. 2017 Oct 11;9(40):35141-35149. doi: 10.1021/acsami.7b12925. Epub 2017 Oct 02.

Kinetic and Thermodynamic Control of Structure Transformations in a Family of Cobalt(II)-Organic Frameworks.

ACS applied materials & interfaces

Qiang Chen, Rui Feng, Jian Xu, Yan-Yuan Jia, Ting-Ting Wang, Ze Chang, Xian-He Bu

Affiliations

  1. School of Materials Science and Engineering, National Institute for Advanced Materials, and TKL of Metal and Molecule-Based Material Chemistry, Nankai University , Tianjin 300350, China.
  2. Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education) and State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University , Tianjin 300071, China.
  3. Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University , Tianjin 300071, China.

PMID: 28920665 DOI: 10.1021/acsami.7b12925

Abstract

Dynamic metal-organic frameworks (MOFs) that respond to external stimuli have recently attracted great attention. However, the subtle control of dynamic processes as well as the illustration of the underlying mechanism, which is crucial for the targeted construction and modulation purpose, is extremely challenging. Herein, we report the achievement of simultaneous kinetic and thermodynamic modulation of the structure transformation processes of a family of cobalt(II)-organic frameworks, through the rational combination of coligand replacement, solvent molecule substitution, and ligand-based solid solution strategies. On the basis of the systematic investigation of the structural transformation behaviors, the underlying response mechanism and principles for modulation were illustrated. It is expected that this work can provide valuable hints for the study and further development of dynamic materials.

Keywords: dynamic materials; kinetic control; metal−organic frameworks; sensing; structure transformation; thermodynamic control

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