Display options
Cite
Mizugaki T, Togo K, Maeno Z, et al. New Routes for Refinery of Biogenic Platform Chemicals Catalyzed by Cerium Oxide-supported Ruthenium Nanoparticles in Water. Sci Rep. 2017;7(1):14007doi: 10.1038/s41598-017-14373-1.
Mizugaki, T., Togo, K., Maeno, Z., Mitsudome, T., Jitsukawa, K., & Kaneda, K. (2017). New Routes for Refinery of Biogenic Platform Chemicals Catalyzed by Cerium Oxide-supported Ruthenium Nanoparticles in Water. Scientific reports, 7(1), 14007. https://doi.org/10.1038/s41598-017-14373-1
Mizugaki, Tomoo, et al. "New Routes for Refinery of Biogenic Platform Chemicals Catalyzed by Cerium Oxide-supported Ruthenium Nanoparticles in Water." Scientific reports vol. 7,1 (2017): 14007. doi: https://doi.org/10.1038/s41598-017-14373-1
Mizugaki T, Togo K, Maeno Z, Mitsudome T, Jitsukawa K, Kaneda K. New Routes for Refinery of Biogenic Platform Chemicals Catalyzed by Cerium Oxide-supported Ruthenium Nanoparticles in Water. Sci Rep. 2017 Oct 25;7(1):14007. doi: 10.1038/s41598-017-14373-1. PMID: 29070900; PMCID: PMC5656575.
Copy Download .nbib Format: NLM
Share it on

Sci Rep. 2017 Oct 25;7(1):14007. doi: 10.1038/s41598-017-14373-1.

New Routes for Refinery of Biogenic Platform Chemicals Catalyzed by Cerium Oxide-supported Ruthenium Nanoparticles in Water.

Scientific reports

Tomoo Mizugaki, Keito Togo, Zen Maeno, Takato Mitsudome, Koichiro Jitsukawa, Kiyotomi Kaneda

Affiliations

  1. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka, 560-8531, Japan.
  2. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka, 560-8531, Japan. [email protected].
  3. Research Center for Solar Energy Chemistry, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka, 560-8531, Japan. [email protected].

PMID: 29070900 PMCID: PMC5656575 DOI: 10.1038/s41598-017-14373-1

Abstract

Highly selective hydrogenative carbon-carbon bond scission of biomass-derived platform oxygenates was achieved with a cerium oxide-supported ruthenium nanoparticle catalyst in water. The present catalyst enabled the selective cleavage of carbon-carbon σ bonds adjacent to carboxyl, ester, and hydroxymethyl groups, opening new eight synthetic routes to valuable chemicals from biomass derivatives. The high selectivity for such carbon-carbon bond scission over carbon-oxygen bonds was attributed to the multiple catalytic roles of the Ru nanoparticles assisted by the in situ formed Ce(OH)

References

  1. J Am Chem Soc. 2012 Jun 6;134(22):9400-5 - PubMed
  2. Green Chem. 2017;19(7):1624-1627 - PubMed
  3. Phys Chem Chem Phys. 2016 Jun 22;18(25):16621-8 - PubMed
  4. ACS Appl Mater Interfaces. 2016 Sep 7;8(35):22988-96 - PubMed
  5. ChemSusChem. 2016 Jun 22;9(12):1355-85 - PubMed
  6. Angew Chem Int Ed Engl. 2008;47(48):9200-11 - PubMed
  7. Green Chem. 2017;19(1):164-168 - PubMed
  8. J Am Chem Soc. 2004 May 12;126(18):5662-3 - PubMed
  9. Chem Commun (Camb). 2013 Jan 11;49(3):252-4 - PubMed
  10. Chem Soc Rev. 2015 Jun 7;44(11):3808-33 - PubMed
  11. ChemSusChem. 2015 Apr 13;8(7):1114-32 - PubMed
  12. ChemSusChem. 2013 Aug;6(8):1345-7 - PubMed
  13. Chem Rev. 2014 Feb 12;114(3):1827-70 - PubMed
  14. ChemSusChem. 2016 Mar 21;9(6):562-82 - PubMed
  15. J Am Chem Soc. 2015 Jul 15;137(27):8672-5 - PubMed
  16. Chem Rev. 2007 Jun;107(6):2411-502 - PubMed
  17. J Am Chem Soc. 2013 Jan 30;135(4):1506-15 - PubMed
  18. Chem Rev. 2013 Jun 12;113(6):4136-63 - PubMed

Publication Types