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Van Caemelbecke E, Will S, Autret M, et al. Electrochemical and Spectral Characterization of Iron Corroles in High and Low Oxidation States:  First Structural Characterization of an Iron(IV) Tetrapyrrole π Cation Radical. Inorg Chem. 1996;35(1):184-192doi: 10.1021/ic9509037.
Van Caemelbecke, E., Will, S., Autret, M., Adamian, V. A., Lex, J., Gisselbrecht, J. P., Gross, M., Vogel, E., & Kadish, K. M. (1996). Electrochemical and Spectral Characterization of Iron Corroles in High and Low Oxidation States:  First Structural Characterization of an Iron(IV) Tetrapyrrole π Cation Radical. Inorganic chemistry, 35(1), 184-192. https://doi.org/10.1021/ic9509037
Van Caemelbecke, Eric, et al. "Electrochemical and Spectral Characterization of Iron Corroles in High and Low Oxidation States:  First Structural Characterization of an Iron(IV) Tetrapyrrole π Cation Radical." Inorganic chemistry vol. 35,1 (1996): 184-192. doi: https://doi.org/10.1021/ic9509037
Van Caemelbecke E, Will S, Autret M, Adamian VA, Lex J, Gisselbrecht JP, Gross M, Vogel E, Kadish KM. Electrochemical and Spectral Characterization of Iron Corroles in High and Low Oxidation States:  First Structural Characterization of an Iron(IV) Tetrapyrrole π Cation Radical. Inorg Chem. 1996 Jan 03;35(1):184-192. doi: 10.1021/ic9509037. PMID: 29350036.
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Inorg Chem. 1996 Jan 03;35(1):184-192. doi: 10.1021/ic9509037.

Electrochemical and Spectral Characterization of Iron Corroles in High and Low Oxidation States:  First Structural Characterization of an Iron(IV) Tetrapyrrole π Cation Radical.

Inorganic chemistry

Eric Van Caemelbecke, Stefan Will, Marie Autret, Victor A Adamian, Johann Lex, Jean-Paul Gisselbrecht, Maurice Gross, Emanuel Vogel, Karl M Kadish

Affiliations

  1. Department of Chemistry, University of Houston, Houston, Texas 77204-5641, Institut für Organische Chemie, Universität zu Köln, Greinstrasse 4, D-50939 Köln, Germany, and Département de Chimie, URA CNRS 405, Université Louis Pasteur, 67000 Strasbourg, France.

PMID: 29350036 DOI: 10.1021/ic9509037

Abstract

The electrochemistry and spectroscopic properties of three iron corroles were examined in benzonitrile, dichloromethane, and pyridine containing 0.1 M tetra-n-butylammonium perchlorate or tetra-n-ethylammonium hexafluorophosphate as supporting electrolyte. The investigated compounds are represented as (OEC)Fe

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