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J Org Chem. 2019 Mar 15;84(6):3045-3054. doi: 10.1021/acs.joc.8b02462. Epub 2019 Mar 06.

Dithiolation of [70]Fullerene with Aliphatic Primary Thiols in the Presence of n-Butylamine via Aerobic Oxidation Reaction.

The Journal of organic chemistry

Sheng-Li Wu, Zong-Jun Li, Xiang Gao

Affiliations

  1. State Key Laboratory of Electroanalytical Chemistry , Changchun Institute of Applied Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences , 5625 Renmin Street , Changchun , Jilin 130022 , China.

PMID: 30794405 DOI: 10.1021/acs.joc.8b02462

Abstract

Aerobic oxidation reaction of [70]fullerene with aliphatic primary thiols in the presence of n-butylamine was studied. The reaction afforded both the fullerene dithiol (2) and dithiol epoxide (3) compounds, which were characterized by

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