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Li L, Sakr AK, Schlöder T, et al. Searching for Monomeric Nickel Tetrafluoride: Unravelling Infrared Matrix Isolation Spectra of Higher Nickel Fluorides. Angew Chem Int Ed Engl. 2021;60(12):6391-6394doi: 10.1002/anie.202015501.
Li, L., Sakr, A. K., Schlöder, T., Klein, S., Beckers, H., Kitsaras, M. P., Snelling, H. V., Young, N. A., Andrae, D., & Riedel, S. (2021). Searching for Monomeric Nickel Tetrafluoride: Unravelling Infrared Matrix Isolation Spectra of Higher Nickel Fluorides. Angewandte Chemie (International ed. in English), 60(12), 6391-6394. https://doi.org/10.1002/anie.202015501
Li, Lin, et al. "Searching for Monomeric Nickel Tetrafluoride: Unravelling Infrared Matrix Isolation Spectra of Higher Nickel Fluorides." Angewandte Chemie (International ed. in English) vol. 60,12 (2021): 6391-6394. doi: https://doi.org/10.1002/anie.202015501
Li L, Sakr AK, Schlöder T, Klein S, Beckers H, Kitsaras MP, Snelling HV, Young NA, Andrae D, Riedel S. Searching for Monomeric Nickel Tetrafluoride: Unravelling Infrared Matrix Isolation Spectra of Higher Nickel Fluorides. Angew Chem Int Ed Engl. 2021 Mar 15;60(12):6391-6394. doi: 10.1002/anie.202015501. Epub 2021 Jan 28. PMID: 33300240; PMCID: PMC7986428.
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Angew Chem Int Ed Engl. 2021 Mar 15;60(12):6391-6394. doi: 10.1002/anie.202015501. Epub 2021 Jan 28.

Searching for Monomeric Nickel Tetrafluoride: Unravelling Infrared Matrix Isolation Spectra of Higher Nickel Fluorides.

Angewandte Chemie (International ed. in English)

Lin Li, Ahmed K Sakr, Tobias Schlöder, Siri Klein, Helmut Beckers, Marios-Petros Kitsaras, Howard V Snelling, Nigel A Young, Dirk Andrae, Sebastian Riedel

Affiliations

  1. Freie Universität Berlin, Institut für Chemie und Biochemie-Anorganische Chemie, Fabeckstrasse 34/36, 14195, Berlin, Germany.
  2. Department of Chemistry and Biochemistry, University of Hull, Kingston upon Hull, HU6 7RX, UK.
  3. Karlsruher Institut für Technologie, Institut für Nanotechnologie, Hermann-von-Helmholtz-Platz 1, 76344, Eggenstein-Leopoldshafen, Germany.
  4. Freie Universität Berlin, Institut für Chemie und Biochemie-Theoretische Chemie, Arnimallee 22, 14195, Berlin, Germany.
  5. Department of Physics and Mathematics, University of Hull, Kingston upon Hull, HU6 7RX, UK.

PMID: 33300240 PMCID: PMC7986428 DOI: 10.1002/anie.202015501

Abstract

Binary transition metal fluorides are textbook examples combining complex electronic features with most fundamental molecular structures. High-valent nickel fluorides are among the strongest known fluorinating and oxidizing agents, but there is a lack of experimental structural and spectroscopic investigations on molecular NiF

© 2020 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.

Keywords: IR spectroscopy; matrix isolation; nickel fluorides; tetrafluoride; trifluoride

References

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