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Yang H, Peng F, Schier DE, et al. Selective Crystallization of Rare-Earth Ions into Cationic Metal-Organic Frameworks for Rare-Earth Separation. Angew Chem Int Ed Engl. 2021;60(20):11148-11152doi: 10.1002/anie.202017042.
Yang, H., Peng, F., Schier, D. E., Markotic, S. A., Zhao, X., Hong, A. N., Wang, Y., Feng, P., & Bu, X. (2021). Selective Crystallization of Rare-Earth Ions into Cationic Metal-Organic Frameworks for Rare-Earth Separation. Angewandte Chemie (International ed. in English), 60(20), 11148-11152. https://doi.org/10.1002/anie.202017042
Yang, Huajun, et al. "Selective Crystallization of Rare-Earth Ions into Cationic Metal-Organic Frameworks for Rare-Earth Separation." Angewandte Chemie (International ed. in English) vol. 60,20 (2021): 11148-11152. doi: https://doi.org/10.1002/anie.202017042
Yang H, Peng F, Schier DE, Markotic SA, Zhao X, Hong AN, Wang Y, Feng P, Bu X. Selective Crystallization of Rare-Earth Ions into Cationic Metal-Organic Frameworks for Rare-Earth Separation. Angew Chem Int Ed Engl. 2021 May 10;60(20):11148-11152. doi: 10.1002/anie.202017042. Epub 2021 Apr 08. PMID: 33629459.
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Angew Chem Int Ed Engl. 2021 May 10;60(20):11148-11152. doi: 10.1002/anie.202017042. Epub 2021 Apr 08.

Selective Crystallization of Rare-Earth Ions into Cationic Metal-Organic Frameworks for Rare-Earth Separation.

Angewandte Chemie (International ed. in English)

Huajun Yang, Fang Peng, Danielle E Schier, Stipe A Markotic, Xiang Zhao, Anh N Hong, Yanxiang Wang, Pingyun Feng, Xianhui Bu

Affiliations

  1. Department of Chemistry and Biochemistry, California State University Long Beach, Long Beach, CA, 90840, USA.
  2. Department of Chemistry, University of California, Riverside, Riverside, CA, 92521, USA.

PMID: 33629459 DOI: 10.1002/anie.202017042

Abstract

For rare-earth separation, selective crystallization into metal-organic frameworks (MOFs) offers new opportunities. Especially important is the development of MOF platforms with high selectivity toward target ions. Here we report a MOF platform (CPM-66) with low-coordination-number environment for rare-earth ions. This platform is highly responsive to the size variation of rare-earth ions and shows exceptional ion-size selectivity during crystallization. CPM-66 family are based on M

© 2021 Wiley-VCH GmbH.

Keywords: MOFs; low-coordination number; rare-earth separation; trimer; urea solvents

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