Display options
Share it on

Polymers (Basel). 2021 Oct 27;13(21). doi: 10.3390/polym13213709.

Determination of the Tensile Properties and Biodegradability of Cornstarch-Based Biopolymers Plasticized with Sorbitol and Glycerol.

Polymers

M M Harussani, S M Sapuan, A H M Firdaus, Yaser A El-Badry, Enas E Hussein, Zeinhom M El-Bahy

Affiliations

  1. Advanced Engineering Materials and Composites Research Centre (AEMC), Department of Mechanical and Manufacturing Engineering, Universiti Putra Malaysia (UPM), Serdang 43400, Selangor, Malaysia.
  2. Laboratory of Biocomposite Technology, Institute of Tropical Forestry and Forest Products, Universiti Putra Malaysia (UPM), Serdang 43400, Selangor, Malaysia.
  3. Chemistry Department, Faculty of Science, Taif University, Khurma, P.O. Box 11099, Taif 21944, Saudi Arabia.
  4. National Water Research Center, P.O. Box 74, Shubra El-Kheima 13411, Egypt.
  5. Department of Chemistry, Faculty of Science, Al-Azhar University, Nasr City, Cairo 11884, Egypt.

PMID: 34771264 PMCID: PMC8587433 DOI: 10.3390/polym13213709

Abstract

In this study, the effects of various quantities of sorbitol and glycerol plasticizers (0%, 30%, 45%, and 60%) on cornstarch-based film were examined to develop a novel polymer for usage with biodegradable materials. The film was prepared using the casting process. According to the test findings, the application of the plasticizer concentrations affected the thickness, moisture content, and water absorption of the film. When plasticizer concentrations were increased to 60%, the tensile stress and Young's modulus of plasticized films dropped regardless of plasticizer type. However, the thin film with addition of 30% sorbitol plasticizer demonstrated a steady value of Young's modulus (60.17 MPa) with an increase in tensile strength (13.61 MPa) of 46%, while the lowest combination of tensile strength and Young's modulus is the film that was plasticized with 60% glycerol, with 2.33 MPa and 16.23 MPa, respectively. In summary, the properties and performance of cornstarch-based film were greatly influenced by plasticizer types and concentrations. The finest set of features in this research appeared in the film plasticized with 30% sorbitol, which achieved the best mechanical properties for food packaging applications.

Keywords: biodegradable film; cornstarch biopolymers; physical properties; plasticizers; tensile properties; thermal properties

References

  1. Polymers (Basel). 2021 Jun 30;13(13): - PubMed
  2. Food Chem. 2017 Sep 1;230:516-523 - PubMed
  3. Polymers (Basel). 2021 Apr 18;13(8): - PubMed
  4. Polymers (Basel). 2021 Mar 26;13(7): - PubMed
  5. Sci Total Environ. 2020 Nov 10;742:140565 - PubMed
  6. Bioresour Technol. 2009 Nov;100(21):5196-202 - PubMed
  7. Polymers (Basel). 2021 Jan 12;13(2): - PubMed
  8. Polymers (Basel). 2021 May 24;13(11): - PubMed
  9. Food Chem. 2012 May 1;132(1):344-50 - PubMed
  10. Nanomaterials (Basel). 2020 Apr 15;10(4): - PubMed
  11. Food Chem. 2011 Jul 15;127(2):541-6 - PubMed
  12. Sci Total Environ. 2022 Jan 10;803:149911 - PubMed
  13. Carbohydr Polym. 2013 Jul 1;96(1):39-46 - PubMed
  14. Ultrason Sonochem. 2017 Mar;35(Pt B):531-540 - PubMed
  15. Carbohydr Polym. 2013 Oct 15;98(1):1117-26 - PubMed
  16. J Food Sci Technol. 2016 Jan;53(1):326-36 - PubMed
  17. Polymers (Basel). 2020 Aug 31;12(9): - PubMed

Publication Types

Grant support