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Isolated magnetic clusters of Co(II) and Ni(II) within 3-dimensional organic frameworks of 6-mercaptonicotinic acid: unique structural topologies based on selectivity for hard and soft coordination environments.

Inorganic chemistry

Humphrey SM, Mole RA, McPartlin M, McInnes EJ, Wood PT.
PMID: 16097815
Inorg Chem. 2005 Aug 22;44(17):5981-3. doi: 10.1021/ic050768q.

Hydrothermal reaction of the mixed thiolate-carboxylate-aromatic amine ligand, 6-mercaptonicotinic acid (6-mnaH2) with Co(II) and Ni(II) leads to two network coordination solids [M9(6-mna)8(mu3-O)2(OH3)2(OH2)6] (M = Co, Ni), 1, and [M2Ni12(6-mna)12(mu3-OH)2(OH2)6] x 8H2O (M = K, Rb, Cs), 2. These compounds...

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Humphrey SM, Mole RA, McPartlin M, et al. Isolated magnetic clusters of Co(II) and Ni(II) within 3-dimensional organic frameworks of 6-mercaptonicotinic acid: unique structural topologies based on selectivity for hard and soft coordination environments. Inorg Chem. 2005;44(17):5981-3doi: 10.1021/ic050768q.
Humphrey, S. M., Mole, R. A., McPartlin, M., McInnes, E. J., & Wood, P. T. (2005). Isolated magnetic clusters of Co(II) and Ni(II) within 3-dimensional organic frameworks of 6-mercaptonicotinic acid: unique structural topologies based on selectivity for hard and soft coordination environments. Inorganic chemistry, 44(17), 5981-3. https://doi.org/10.1021/ic050768q
Humphrey, Simon M, et al. "Isolated magnetic clusters of Co(II) and Ni(II) within 3-dimensional organic frameworks of 6-mercaptonicotinic acid: unique structural topologies based on selectivity for hard and soft coordination environments." Inorganic chemistry vol. 44,17 (2005): 5981-3. doi: https://doi.org/10.1021/ic050768q
Humphrey SM, Mole RA, McPartlin M, McInnes EJ, Wood PT. Isolated magnetic clusters of Co(II) and Ni(II) within 3-dimensional organic frameworks of 6-mercaptonicotinic acid: unique structural topologies based on selectivity for hard and soft coordination environments. Inorg Chem. 2005 Aug 22;44(17):5981-3. doi: 10.1021/ic050768q. PMID: 16097815.
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Studies of a molecular hourglass: synthesis and magnetic characterisation of a cyclic dodecanuclear {Cr10Cu2} complex.

Chemistry (Weinheim an der Bergstrasse, Germany)

Shanmugam M, Engelhardt LP, Larsen FK, Luban M, McInnes EJ, Muryn CA, Overgaard J, Rentschler E, Timco GA, Winpenny RE.
PMID: 17009364
Chemistry. 2006 Nov 06;12(32):8267-75. doi: 10.1002/chem.200600827.

The synthesis, structure, EPR, and magnetic studies of two dodecanuclear heterometallic cyclic clusters are reported. The compounds have the general formula [R(2)NH(2)](2)[Cr(10)Cu(2)F(14)(O(2)CCMe(3))(22)] (R=Me, 1 or iPr, 2). Both structures contain an array of metal centers which describe an approximate...

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Shanmugam M, Engelhardt LP, Larsen FK, et al. Studies of a molecular hourglass: synthesis and magnetic characterisation of a cyclic dodecanuclear {Cr10Cu2} complex. Chemistry. 2006;12(32):8267-75doi: 10.1002/chem.200600827.
Shanmugam, M., Engelhardt, L. P., Larsen, F. K., Luban, M., McInnes, E. J., Muryn, C. A., Overgaard, J., Rentschler, E., Timco, G. A., & Winpenny, R. E. (2006). Studies of a molecular hourglass: synthesis and magnetic characterisation of a cyclic dodecanuclear {Cr10Cu2} complex. Chemistry (Weinheim an der Bergstrasse, Germany), 12(32), 8267-75. https://doi.org/10.1002/chem.200600827
Shanmugam, Muralidharan, et al. "Studies of a molecular hourglass: synthesis and magnetic characterisation of a cyclic dodecanuclear {Cr10Cu2} complex." Chemistry (Weinheim an der Bergstrasse, Germany) vol. 12,32 (2006): 8267-75. doi: https://doi.org/10.1002/chem.200600827
Shanmugam M, Engelhardt LP, Larsen FK, Luban M, McInnes EJ, Muryn CA, Overgaard J, Rentschler E, Timco GA, Winpenny RE. Studies of a molecular hourglass: synthesis and magnetic characterisation of a cyclic dodecanuclear {Cr10Cu2} complex. Chemistry. 2006 Nov 06;12(32):8267-75. doi: 10.1002/chem.200600827. PMID: 17009364.
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Cosmos 954: search for airborne radioactivity on lichens in the crash area, northwest territories, Canada.

Science (New York, N.Y.)

Taylor HW, Hutchison EA, McInnes KL, Svoboda J.
PMID: 17732333
Science. 1979 Sep 28;205(4413):1383-5. doi: 10.1126/science.205.4413.1383.

The fission product radioactivity detected on lichens in the vicinity of the impact area of the Soviet satellite Cosmos 954 does not exceed the background levels found in the general area as a result of past nuclear explosions.

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Taylor HW, Hutchison EA, McInnes KL, et al. Cosmos 954: search for airborne radioactivity on lichens in the crash area, northwest territories, Canada. Science. 1979;205(4413):1383-5doi: 10.1126/science.205.4413.1383.
Taylor, H. W., Hutchison, E. A., McInnes, K. L., & Svoboda, J. (1979). Cosmos 954: search for airborne radioactivity on lichens in the crash area, northwest territories, Canada. Science (New York, N.Y.), 205(4413), 1383-5. https://doi.org/10.1126/science.205.4413.1383
Taylor, H W, et al. "Cosmos 954: search for airborne radioactivity on lichens in the crash area, northwest territories, Canada." Science (New York, N.Y.) vol. 205,4413 (1979): 1383-5. doi: https://doi.org/10.1126/science.205.4413.1383
Taylor HW, Hutchison EA, McInnes KL, Svoboda J. Cosmos 954: search for airborne radioactivity on lichens in the crash area, northwest territories, Canada. Science. 1979 Sep 28;205(4413):1383-5. doi: 10.1126/science.205.4413.1383. PMID: 17732333.
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Unconventional nonequilibrium dynamics in Ni10 magnetic molecules: evidence from NMR.

Physical review letters

Belesi M, Micotti E, Mariani M, Borsa F, Lascialfari A, Carretta S, Santini P, Amoretti G, McInnes EJ, Tidmarsh IS, Hawkett JR.
PMID: 19518820
Phys Rev Lett. 2009 May 01;102(17):177201. doi: 10.1103/PhysRevLett.102.177201. Epub 2009 Apr 28.

Crystals containing Ni10 magnetic molecules display an unprecedented form of out-of-equilibrium behavior of the bulk magnetization M at temperatures as high as 17 K. We have performed 1H NMR measurements to probe the local Ni magnetic moments and their...

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Belesi M, Micotti E, Mariani M, et al. Unconventional nonequilibrium dynamics in Ni10 magnetic molecules: evidence from NMR. Phys Rev Lett. 2009;102(17):177201doi: 10.1103/PhysRevLett.102.177201.
Belesi, M., Micotti, E., Mariani, M., Borsa, F., Lascialfari, A., Carretta, S., Santini, P., Amoretti, G., McInnes, E. J., Tidmarsh, I. S., & Hawkett, J. R. (2009). Unconventional nonequilibrium dynamics in Ni10 magnetic molecules: evidence from NMR. Physical review letters, 102(17), 177201. https://doi.org/10.1103/PhysRevLett.102.177201
Belesi, M, et al. "Unconventional nonequilibrium dynamics in Ni10 magnetic molecules: evidence from NMR." Physical review letters vol. 102,17 (2009): 177201. doi: https://doi.org/10.1103/PhysRevLett.102.177201
Belesi M, Micotti E, Mariani M, Borsa F, Lascialfari A, Carretta S, Santini P, Amoretti G, McInnes EJ, Tidmarsh IS, Hawkett JR. Unconventional nonequilibrium dynamics in Ni10 magnetic molecules: evidence from NMR. Phys Rev Lett. 2009 May 01;102(17):177201. doi: 10.1103/PhysRevLett.102.177201. Epub 2009 Apr 28. PMID: 19518820.
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Entanglement in supramolecular spin systems of two weakly coupled antiferromagnetic rings (purple-Cr7Ni).

Physical review letters

Candini A, Lorusso G, Troiani F, Ghirri A, Carretta S, Santini P, Amoretti G, Muryn C, Tuna F, Timco G, McInnes EJ, Winpenny RE, Wernsdorfer W, Affronte M.
PMID: 20366678
Phys Rev Lett. 2010 Jan 22;104(3):037203. doi: 10.1103/PhysRevLett.104.037203. Epub 2010 Jan 21.

We characterize supramolecular magnetic structures, consisting of two weakly coupled antiferromagnetic rings, by low-temperature specific heat, susceptibility, magnetization and electron paramagnetic resonance measurements. Intra- and inter-ring interactions are modeled through a microscopic spin-Hamiltonian approach that reproduces all the experimental...

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Candini A, Lorusso G, Troiani F, et al. Entanglement in supramolecular spin systems of two weakly coupled antiferromagnetic rings (purple-Cr7Ni). Phys Rev Lett. 2010;104(3):037203doi: 10.1103/PhysRevLett.104.037203.
Candini, A., Lorusso, G., Troiani, F., Ghirri, A., Carretta, S., Santini, P., Amoretti, G., Muryn, C., Tuna, F., Timco, G., McInnes, E. J., Winpenny, R. E., Wernsdorfer, W., & Affronte, M. (2010). Entanglement in supramolecular spin systems of two weakly coupled antiferromagnetic rings (purple-Cr7Ni). Physical review letters, 104(3), 037203. https://doi.org/10.1103/PhysRevLett.104.037203
Candini, A, et al. "Entanglement in supramolecular spin systems of two weakly coupled antiferromagnetic rings (purple-Cr7Ni)." Physical review letters vol. 104,3 (2010): 037203. doi: https://doi.org/10.1103/PhysRevLett.104.037203
Candini A, Lorusso G, Troiani F, Ghirri A, Carretta S, Santini P, Amoretti G, Muryn C, Tuna F, Timco G, McInnes EJ, Winpenny RE, Wernsdorfer W, Affronte M. Entanglement in supramolecular spin systems of two weakly coupled antiferromagnetic rings (purple-Cr7Ni). Phys Rev Lett. 2010 Jan 22;104(3):037203. doi: 10.1103/PhysRevLett.104.037203. Epub 2010 Jan 21. PMID: 20366678.
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Phenoxyl radicals: H-bonded and coordinated to Cu(II) and Zn(II).

Dalton transactions (Cambridge, England : 2003)

Benisvy L, Bill E, Blake AJ, Collison D, Davies ES, Garner CD, McArdle G, McInnes EJ, McMaster J, Ross SH, Wilson C.
PMID: 16357984
Dalton Trans. 2006 Jan 07;(1):258-67. doi: 10.1039/b513221p. Epub 2005 Nov 09.

Two pro-ligands ((R)LH) comprised of an o,p-di-tert-butyl-substituted phenol covalently bonded to a benzimidazole ((Bz)LH) or a 4,5-di-p-methoxyphenyl substituted imidazole ((PhOMe)LH), have been structurally characterised. Each possesses an intramolecular O-H[dot dot dot]N hydrogen bond between the phenolic O-H group and...

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Benisvy L, Bill E, Blake AJ, et al. Phenoxyl radicals: H-bonded and coordinated to Cu(II) and Zn(II). Dalton Trans. 2005;(1):258-67doi: 10.1039/b513221p.
Benisvy, L., Bill, E., Blake, A. J., Collison, D., Davies, E. S., Garner, C. D., McArdle, G., McInnes, E. J., McMaster, J., Ross, S. H., & Wilson, C. (2006). Phenoxyl radicals: H-bonded and coordinated to Cu(II) and Zn(II). Dalton transactions (Cambridge, England : 2003), (1), 258-67. https://doi.org/10.1039/b513221p
Benisvy, Laurent, et al. "Phenoxyl radicals: H-bonded and coordinated to Cu(II) and Zn(II)." Dalton transactions (Cambridge, England : 2003) vol. ,1 (2006): 258-67. doi: https://doi.org/10.1039/b513221p
Benisvy L, Bill E, Blake AJ, Collison D, Davies ES, Garner CD, McArdle G, McInnes EJ, McMaster J, Ross SH, Wilson C. Phenoxyl radicals: H-bonded and coordinated to Cu(II) and Zn(II). Dalton Trans. 2006 Jan 07;(1):258-67. doi: 10.1039/b513221p. Epub 2005 Nov 09. PMID: 16357984.
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Use of electronic personal health record systems to encourage HIV screening: an exploratory study of patient and provider perspectives.

BMC research notes

McInnes DK, Solomon JL, Bokhour BG, Asch SM, Ross D, Nazi KM, Gifford AL.
PMID: 21843313
BMC Res Notes. 2011 Aug 15;4:295. doi: 10.1186/1756-0500-4-295.

BACKGROUND: When detected, HIV can be effectively treated with antiretroviral therapy. Nevertheless in the U.S. approximately 25% of those who are HIV-infected do not know it. Much remains unknown about how to increase HIV testing rates. New Internet outreach...

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McInnes DK, Solomon JL, Bokhour BG, et al. Use of electronic personal health record systems to encourage HIV screening: an exploratory study of patient and provider perspectives. BMC Res Notes. 2011;4:295doi: 10.1186/1756-0500-4-295.
McInnes, D. K., Solomon, J. L., Bokhour, B. G., Asch, S. M., Ross, D., Nazi, K. M., & Gifford, A. L. (2011). Use of electronic personal health record systems to encourage HIV screening: an exploratory study of patient and provider perspectives. BMC research notes, 4295. https://doi.org/10.1186/1756-0500-4-295
McInnes, D Keith, et al. "Use of electronic personal health record systems to encourage HIV screening: an exploratory study of patient and provider perspectives." BMC research notes vol. 4 (2011): 295. doi: https://doi.org/10.1186/1756-0500-4-295
McInnes DK, Solomon JL, Bokhour BG, Asch SM, Ross D, Nazi KM, Gifford AL. Use of electronic personal health record systems to encourage HIV screening: an exploratory study of patient and provider perspectives. BMC Res Notes. 2011 Aug 15;4:295. doi: 10.1186/1756-0500-4-295. PMID: 21843313; PMCID: PMC3173346.
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Single pyramid magnets: Dy5 pyramids with slow magnetic relaxation to 40 K.

Angewandte Chemie (International ed. in English)

Blagg RJ, Muryn CA, McInnes EJ, Tuna F, Winpenny RE.
PMID: 21656622
Angew Chem Int Ed Engl. 2011 Jul 11;50(29):6530-3. doi: 10.1002/anie.201101932. Epub 2011 Jun 07.

No abstract available.

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Blagg RJ, Muryn CA, McInnes EJ, et al. Single pyramid magnets: Dy5 pyramids with slow magnetic relaxation to 40 K. Angew Chem Int Ed Engl. 2011;50(29):6530-3doi: 10.1002/anie.201101932.
Blagg, R. J., Muryn, C. A., McInnes, E. J., Tuna, F., & Winpenny, R. E. (2011). Single pyramid magnets: Dy5 pyramids with slow magnetic relaxation to 40 K. Angewandte Chemie (International ed. in English), 50(29), 6530-3. https://doi.org/10.1002/anie.201101932
Blagg, Robin J, et al. "Single pyramid magnets: Dy5 pyramids with slow magnetic relaxation to 40 K." Angewandte Chemie (International ed. in English) vol. 50,29 (2011): 6530-3. doi: https://doi.org/10.1002/anie.201101932
Blagg RJ, Muryn CA, McInnes EJ, Tuna F, Winpenny RE. Single pyramid magnets: Dy5 pyramids with slow magnetic relaxation to 40 K. Angew Chem Int Ed Engl. 2011 Jul 11;50(29):6530-3. doi: 10.1002/anie.201101932. Epub 2011 Jun 07. PMID: 21656622.
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Suppression of the Jahn-Teller distortion in a six-coordinate copper(II) complex by doping it into a host lattice.

Chemical communications (Cambridge, England)

Docherty R, Tuna F, Kilner CA, McInnes EJ, Halcrow MA.
PMID: 22434059
Chem Commun (Camb). 2012 Apr 28;48(34):4055-7. doi: 10.1039/c2cc30873h. Epub 2012 Mar 21.

The electronic structures of [Cu(terpy)(2)](2+) and [Cu(bpp)(2)](2+) (bpp = 2,6-di[pyrazol-1-yl]pyridine) are different, when doped into [M(bpp)(2)][BF(4)](2) (M(2+) = Fe(2+) or Zn(2+)). The [Cu(terpy)(2)](2+) dopant is a typical pseudo-Jahn-Teller elongated copper(II) center. However, the [Cu(bpp)(2)](2+) sites show EPR spectra consistent...

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Docherty R, Tuna F, Kilner CA, et al. Suppression of the Jahn-Teller distortion in a six-coordinate copper(II) complex by doping it into a host lattice. Chem Commun (Camb). 2012;48(34):4055-7doi: 10.1039/c2cc30873h.
Docherty, R., Tuna, F., Kilner, C. A., McInnes, E. J., & Halcrow, M. A. (2012). Suppression of the Jahn-Teller distortion in a six-coordinate copper(II) complex by doping it into a host lattice. Chemical communications (Cambridge, England), 48(34), 4055-7. https://doi.org/10.1039/c2cc30873h
Docherty, Rebecca, et al. "Suppression of the Jahn-Teller distortion in a six-coordinate copper(II) complex by doping it into a host lattice." Chemical communications (Cambridge, England) vol. 48,34 (2012): 4055-7. doi: https://doi.org/10.1039/c2cc30873h
Docherty R, Tuna F, Kilner CA, McInnes EJ, Halcrow MA. Suppression of the Jahn-Teller distortion in a six-coordinate copper(II) complex by doping it into a host lattice. Chem Commun (Camb). 2012 Apr 28;48(34):4055-7. doi: 10.1039/c2cc30873h. Epub 2012 Mar 21. PMID: 22434059.
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A triamido-uranium(V) inverse-sandwich 10π-toluene tetraanion arene complex.

Dalton transactions (Cambridge, England : 2003)

Patel D, Tuna F, McInnes EJ, McMaster J, Lewis W, Blake AJ, Liddle ST.
PMID: 23450280
Dalton Trans. 2013 Apr 21;42(15):5224-7. doi: 10.1039/c3dt50255d. Epub 2013 Feb 28.

Reduction of [U(Ts(Tol))(Cl)(μ-Cl)U(Ts(Tol))(THF)2] [2, Ts(Tol) = HC(SiMe2NAr')3; Ar' = 4-MeC6H4)] with KC8 in toluene afforded the new arene-bridged diuranium complex [{U(Ts(Tol))}2(μ-η(6):η(6)-C6H5Me)] (3); combined structural, spectroscopic, magnetic, and computational analyses unambiguously confirm that the uranium centres in 3 are in...

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Patel D, Tuna F, McInnes EJ, et al. A triamido-uranium(V) inverse-sandwich 10π-toluene tetraanion arene complex. Dalton Trans. 2013;42(15):5224-7doi: 10.1039/c3dt50255d.
Patel, D., Tuna, F., McInnes, E. J., McMaster, J., Lewis, W., Blake, A. J., & Liddle, S. T. (2013). A triamido-uranium(V) inverse-sandwich 10π-toluene tetraanion arene complex. Dalton transactions (Cambridge, England : 2003), 42(15), 5224-7. https://doi.org/10.1039/c3dt50255d
Patel, Dipti, et al. "A triamido-uranium(V) inverse-sandwich 10π-toluene tetraanion arene complex." Dalton transactions (Cambridge, England : 2003) vol. 42,15 (2013): 5224-7. doi: https://doi.org/10.1039/c3dt50255d
Patel D, Tuna F, McInnes EJ, McMaster J, Lewis W, Blake AJ, Liddle ST. A triamido-uranium(V) inverse-sandwich 10π-toluene tetraanion arene complex. Dalton Trans. 2013 Apr 21;42(15):5224-7. doi: 10.1039/c3dt50255d. Epub 2013 Feb 28. PMID: 23450280.
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Nanoporous anodic aluminium oxide membranes with layered surface chemistry.

Chemical communications (Cambridge, England)

Mutalib Md Jani A, Anglin EJ, McInnes SJ, Losic D, Shapter JG, Voelcker NH.
PMID: 19462087
Chem Commun (Camb). 2009 Jun 07;(21):3062-4. doi: 10.1039/b901745c. Epub 2009 Apr 14.

A new and facile method is described to prepare Janus-like nanoporous anodic aluminium oxide (AAO) membranes with distinctly different internal and external surface chemistry.

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Mutalib Md Jani A, Anglin EJ, McInnes SJ, et al. Nanoporous anodic aluminium oxide membranes with layered surface chemistry. Chem Commun (Camb). 2009;(21):3062-4doi: 10.1039/b901745c.
Mutalib Md Jani, A., Anglin, E. J., McInnes, S. J., Losic, D., Shapter, J. G., & Voelcker, N. H. (2009). Nanoporous anodic aluminium oxide membranes with layered surface chemistry. Chemical communications (Cambridge, England), (21), 3062-4. https://doi.org/10.1039/b901745c
Mutalib Md Jani, Abdul, et al. "Nanoporous anodic aluminium oxide membranes with layered surface chemistry." Chemical communications (Cambridge, England) vol. ,21 (2009): 3062-4. doi: https://doi.org/10.1039/b901745c
Mutalib Md Jani A, Anglin EJ, McInnes SJ, Losic D, Shapter JG, Voelcker NH. Nanoporous anodic aluminium oxide membranes with layered surface chemistry. Chem Commun (Camb). 2009 Jun 07;(21):3062-4. doi: 10.1039/b901745c. Epub 2009 Apr 14. PMID: 19462087.
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Exploring the structure and properties of transition metal templated {VM17(VO4)2} Dawson-like capsules.

Inorganic chemistry

Miras HN, Stone D, Long DL, McInnes EJ, Kögerler P, Cronin L.
PMID: 21793492
Inorg Chem. 2011 Sep 05;50(17):8384-91. doi: 10.1021/ic200943s. Epub 2011 Jul 27.

Vanadate(V)-templated Dawson-type capsules {V(IV)M(VI)(17)(VO(4))(2)} (M = Mo, W; 1-2) have been synthesized and investigated by electrochemical methods in aqueous and organic media using spectroscopic techniques, EPR, UV-vis/NIR, IR, and CSI-MS (cryospray ionization mass spec.), and the clusters have been...

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Miras HN, Stone D, Long DL, et al. Exploring the structure and properties of transition metal templated {VM17(VO4)2} Dawson-like capsules. Inorg Chem. 2011;50(17):8384-91doi: 10.1021/ic200943s.
Miras, H. N., Stone, D., Long, D. L., McInnes, E. J., Kögerler, P., & Cronin, L. (2011). Exploring the structure and properties of transition metal templated {VM17(VO4)2} Dawson-like capsules. Inorganic chemistry, 50(17), 8384-91. https://doi.org/10.1021/ic200943s
Miras, Haralampos N, et al. "Exploring the structure and properties of transition metal templated {VM17(VO4)2} Dawson-like capsules." Inorganic chemistry vol. 50,17 (2011): 8384-91. doi: https://doi.org/10.1021/ic200943s
Miras HN, Stone D, Long DL, McInnes EJ, Kögerler P, Cronin L. Exploring the structure and properties of transition metal templated {VM17(VO4)2} Dawson-like capsules. Inorg Chem. 2011 Sep 05;50(17):8384-91. doi: 10.1021/ic200943s. Epub 2011 Jul 27. PMID: 21793492.
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