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Caging peroxide: anion-templated synthesis and characterization of a rare-earth cluster.

Inorganic chemistry

Gee WJ, MacLellan JG, Forsyth CM, Moubaraki B, Murray KS, Andrews PC, Junk PC.
PMID: 22857781
Inorg Chem. 2012 Aug 20;51(16):8661-3. doi: 10.1021/ic301382r. Epub 2012 Aug 02.

Sequestration of peroxide derived from molecular oxygen has resulted in the templated synthesis of a terbium picolinate cluster, isolated as a 2D sodiated network in the solid state. This first example of an air-stable rare-earth peroxide cluster represents key...

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Gee WJ, MacLellan JG, Forsyth CM, et al. Caging peroxide: anion-templated synthesis and characterization of a rare-earth cluster. Inorg Chem. 2012;51(16):8661-3doi: 10.1021/ic301382r.
Gee, W. J., MacLellan, J. G., Forsyth, C. M., Moubaraki, B., Murray, K. S., Andrews, P. C., & Junk, P. C. (2012). Caging peroxide: anion-templated synthesis and characterization of a rare-earth cluster. Inorganic chemistry, 51(16), 8661-3. https://doi.org/10.1021/ic301382r
Gee, William J, et al. "Caging peroxide: anion-templated synthesis and characterization of a rare-earth cluster." Inorganic chemistry vol. 51,16 (2012): 8661-3. doi: https://doi.org/10.1021/ic301382r
Gee WJ, MacLellan JG, Forsyth CM, Moubaraki B, Murray KS, Andrews PC, Junk PC. Caging peroxide: anion-templated synthesis and characterization of a rare-earth cluster. Inorg Chem. 2012 Aug 20;51(16):8661-3. doi: 10.1021/ic301382r. Epub 2012 Aug 02. PMID: 22857781.
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Ion-Exchange-Induced Selective Etching for the Synthesis of Amino-Functionalized Hollow Mesoporous Silica for Elevated-High-Temperature Fuel Cells.

ACS applied materials & interfaces

Zhang J, Liu J, Lu S, Zhu H, Aili D, De Marco R, Xiang Y, Forsyth M, Li Q, Jiang SP.
PMID: 28857542
ACS Appl Mater Interfaces. 2017 Sep 20;9(37):31922-31930. doi: 10.1021/acsami.7b09591. Epub 2017 Sep 07.

As differentiated from conventional synthetic processes, amino-functionalized hollow mesoporous silica (NH

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Zhang J, Liu J, Lu S, et al. Ion-Exchange-Induced Selective Etching for the Synthesis of Amino-Functionalized Hollow Mesoporous Silica for Elevated-High-Temperature Fuel Cells. ACS Appl Mater Interfaces. 2017;9(37):31922-31930doi: 10.1021/acsami.7b09591.
Zhang, J., Liu, J., Lu, S., Zhu, H., Aili, D., De Marco, R., Xiang, Y., Forsyth, M., Li, Q., & Jiang, S. P. (2017). Ion-Exchange-Induced Selective Etching for the Synthesis of Amino-Functionalized Hollow Mesoporous Silica for Elevated-High-Temperature Fuel Cells. ACS applied materials & interfaces, 9(37), 31922-31930. https://doi.org/10.1021/acsami.7b09591
Zhang, Jin, et al. "Ion-Exchange-Induced Selective Etching for the Synthesis of Amino-Functionalized Hollow Mesoporous Silica for Elevated-High-Temperature Fuel Cells." ACS applied materials & interfaces vol. 9,37 (2017): 31922-31930. doi: https://doi.org/10.1021/acsami.7b09591
Zhang J, Liu J, Lu S, Zhu H, Aili D, De Marco R, Xiang Y, Forsyth M, Li Q, Jiang SP. Ion-Exchange-Induced Selective Etching for the Synthesis of Amino-Functionalized Hollow Mesoporous Silica for Elevated-High-Temperature Fuel Cells. ACS Appl Mater Interfaces. 2017 Sep 20;9(37):31922-31930. doi: 10.1021/acsami.7b09591. Epub 2017 Sep 07. PMID: 28857542.
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New insights into the thermal behaviour of organic ionic plastic crystals: magnetic resonance imaging of polycrystalline morphology alterations induced by solid-solid phase transitions.

Physical chemistry chemical physics : PCCP

Romanenko K, Pringle JM, O'Dell LA, Forsyth M.
PMID: 26130025
Phys Chem Chem Phys. 2015 Jul 15;17(29):18991-9000. doi: 10.1039/c5cp03294f.

Organic ionic plastic crystals (OIPCs) show strong potential as solid-state electrolytes for lithium battery applications, demonstrating promising electrochemical performance and eliminating the need for a volatile and flammable liquid electrolyte. The ionic conductivity (σ) in these systems has recently...

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Romanenko K, Pringle JM, O'Dell LA, et al. New insights into the thermal behaviour of organic ionic plastic crystals: magnetic resonance imaging of polycrystalline morphology alterations induced by solid-solid phase transitions. Phys Chem Chem Phys. 2015;17(29):18991-9000doi: 10.1039/c5cp03294f.
Romanenko, K., Pringle, J. M., O'Dell, L. A., & Forsyth, M. (2015). New insights into the thermal behaviour of organic ionic plastic crystals: magnetic resonance imaging of polycrystalline morphology alterations induced by solid-solid phase transitions. Physical chemistry chemical physics : PCCP, 17(29), 18991-9000. https://doi.org/10.1039/c5cp03294f
Romanenko, Konstantin, et al. "New insights into the thermal behaviour of organic ionic plastic crystals: magnetic resonance imaging of polycrystalline morphology alterations induced by solid-solid phase transitions." Physical chemistry chemical physics : PCCP vol. 17,29 (2015): 18991-9000. doi: https://doi.org/10.1039/c5cp03294f
Romanenko K, Pringle JM, O'Dell LA, Forsyth M. New insights into the thermal behaviour of organic ionic plastic crystals: magnetic resonance imaging of polycrystalline morphology alterations induced by solid-solid phase transitions. Phys Chem Chem Phys. 2015 Jul 15;17(29):18991-9000. doi: 10.1039/c5cp03294f. PMID: 26130025.
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Ionic Liquid Adsorption and Nanotribology at the Silica-Oil Interface: Hundred-Fold Dilution in Oil Lubricates as Effectively as the Pure Ionic Liquid.

The journal of physical chemistry letters

Li H, Cooper PK, Somers AE, Rutland MW, Howlett PC, Forsyth M, Atkin R.
PMID: 26278938
J Phys Chem Lett. 2014 Dec 04;5(23):4095-9. doi: 10.1021/jz5021422. Epub 2014 Nov 17.

The remarkable physical properties of ionic liquids (ILs) make them potentially excellent lubricants. One of the challenges for using ILs as lubricants is their high cost. In this article, atomic force microscopy (AFM) nanotribology measurements reveal that a 1...

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Li H, Cooper PK, Somers AE, et al. Ionic Liquid Adsorption and Nanotribology at the Silica-Oil Interface: Hundred-Fold Dilution in Oil Lubricates as Effectively as the Pure Ionic Liquid. J Phys Chem Lett. 2014;5(23):4095-9doi: 10.1021/jz5021422.
Li, H., Cooper, P. K., Somers, A. E., Rutland, M. W., Howlett, P. C., Forsyth, M., & Atkin, R. (2014). Ionic Liquid Adsorption and Nanotribology at the Silica-Oil Interface: Hundred-Fold Dilution in Oil Lubricates as Effectively as the Pure Ionic Liquid. The journal of physical chemistry letters, 5(23), 4095-9. https://doi.org/10.1021/jz5021422
Li, Hua, et al. "Ionic Liquid Adsorption and Nanotribology at the Silica-Oil Interface: Hundred-Fold Dilution in Oil Lubricates as Effectively as the Pure Ionic Liquid." The journal of physical chemistry letters vol. 5,23 (2014): 4095-9. doi: https://doi.org/10.1021/jz5021422
Li H, Cooper PK, Somers AE, Rutland MW, Howlett PC, Forsyth M, Atkin R. Ionic Liquid Adsorption and Nanotribology at the Silica-Oil Interface: Hundred-Fold Dilution in Oil Lubricates as Effectively as the Pure Ionic Liquid. J Phys Chem Lett. 2014 Dec 04;5(23):4095-9. doi: 10.1021/jz5021422. Epub 2014 Nov 17. PMID: 26278938.
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Redox Chemistry of the Superoxide Ion in a Phosphonium-Based Ionic Liquid in the Presence of Water.

The journal of physical chemistry letters

Pozo-Gonzalo C, Torriero AA, Forsyth M, MacFarlane DR, Howlett PC.
PMID: 26283117
J Phys Chem Lett. 2013 Jun 06;4(11):1834-7. doi: 10.1021/jz400715r. Epub 2013 May 17.

Stable electrogenerated superoxide ion has been observed for the first time in a phosphonium-based ionic liquid in the presence of water, leading to a chemically reversible O2/O2(•-) redox couple instead of the disproportionation reaction that is usually observed. It...

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Pozo-Gonzalo C, Torriero AA, Forsyth M, et al. Redox Chemistry of the Superoxide Ion in a Phosphonium-Based Ionic Liquid in the Presence of Water. J Phys Chem Lett. 2013;4(11):1834-7doi: 10.1021/jz400715r.
Pozo-Gonzalo, C., Torriero, A. A., Forsyth, M., MacFarlane, D. R., & Howlett, P. C. (2013). Redox Chemistry of the Superoxide Ion in a Phosphonium-Based Ionic Liquid in the Presence of Water. The journal of physical chemistry letters, 4(11), 1834-7. https://doi.org/10.1021/jz400715r
Pozo-Gonzalo, Cristina, et al. "Redox Chemistry of the Superoxide Ion in a Phosphonium-Based Ionic Liquid in the Presence of Water." The journal of physical chemistry letters vol. 4,11 (2013): 1834-7. doi: https://doi.org/10.1021/jz400715r
Pozo-Gonzalo C, Torriero AA, Forsyth M, MacFarlane DR, Howlett PC. Redox Chemistry of the Superoxide Ion in a Phosphonium-Based Ionic Liquid in the Presence of Water. J Phys Chem Lett. 2013 Jun 06;4(11):1834-7. doi: 10.1021/jz400715r. Epub 2013 May 17. PMID: 26283117.
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New opportunities for quantitative and time efficient 3D MRI of liquid and solid electrochemical cell components: Sectoral Fast Spin Echo and SPRITE.

Journal of magnetic resonance (San Diego, Calif. : 1997)

Romanenko K, Forsyth M, O'Dell LA.
PMID: 25442778
J Magn Reson. 2014 Nov;248:96-104. doi: 10.1016/j.jmr.2014.09.017. Epub 2014 Oct 02.

The ability to image electrochemical processes in situ using nuclear magnetic resonance imaging (MRI) offers exciting possibilities for understanding and optimizing materials in batteries, fuel cells and supercapacitors. In these applications, however, the quality of the MRI measurement is...

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Romanenko K, Forsyth M, O'Dell LA. New opportunities for quantitative and time efficient 3D MRI of liquid and solid electrochemical cell components: Sectoral Fast Spin Echo and SPRITE. J Magn Reson. 2014;248:96-104doi: 10.1016/j.jmr.2014.09.017.
Romanenko, K., Forsyth, M., & O'Dell, L. A. (2014). New opportunities for quantitative and time efficient 3D MRI of liquid and solid electrochemical cell components: Sectoral Fast Spin Echo and SPRITE. Journal of magnetic resonance (San Diego, Calif. : 1997), 24896-104. https://doi.org/10.1016/j.jmr.2014.09.017
Romanenko, Konstantin, et al. "New opportunities for quantitative and time efficient 3D MRI of liquid and solid electrochemical cell components: Sectoral Fast Spin Echo and SPRITE." Journal of magnetic resonance (San Diego, Calif. : 1997) vol. 248 (2014): 96-104. doi: https://doi.org/10.1016/j.jmr.2014.09.017
Romanenko K, Forsyth M, O'Dell LA. New opportunities for quantitative and time efficient 3D MRI of liquid and solid electrochemical cell components: Sectoral Fast Spin Echo and SPRITE. J Magn Reson. 2014 Nov;248:96-104. doi: 10.1016/j.jmr.2014.09.017. Epub 2014 Oct 02. PMID: 25442778.
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A fluoride bridged {Cr(III)4Dy(III)4} single molecule magnet.

Dalton transactions (Cambridge, England : 2003)

Langley SK, Forsyth CM, Moubaraki B, Murray KS.
PMID: 25476806
Dalton Trans. 2015 Jan 21;44(3):912-5. doi: 10.1039/c4dt03100h.

The synthesis of a heterometallic octanuclear {Cr(III)4Dy(III)4} complex containing fluoride bridges displays SMM behaviour, with highly coercive magnetic hysteresis loops. Intriguingly multiple relaxation processes are revealed and the relaxation times are found to be longer compared to those of...

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Langley SK, Forsyth CM, Moubaraki B, et al. A fluoride bridged {Cr(III)4Dy(III)4} single molecule magnet. Dalton Trans. 2015;44(3):912-5doi: 10.1039/c4dt03100h.
Langley, S. K., Forsyth, C. M., Moubaraki, B., & Murray, K. S. (2015). A fluoride bridged {Cr(III)4Dy(III)4} single molecule magnet. Dalton transactions (Cambridge, England : 2003), 44(3), 912-5. https://doi.org/10.1039/c4dt03100h
Langley, Stuart K, et al. "A fluoride bridged {Cr(III)4Dy(III)4} single molecule magnet." Dalton transactions (Cambridge, England : 2003) vol. 44,3 (2015): 912-5. doi: https://doi.org/10.1039/c4dt03100h
Langley SK, Forsyth CM, Moubaraki B, Murray KS. A fluoride bridged {Cr(III)4Dy(III)4} single molecule magnet. Dalton Trans. 2015 Jan 21;44(3):912-5. doi: 10.1039/c4dt03100h. PMID: 25476806.
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Quararibea Metabolites. 4.(1) Total Synthesis and Conformational Studies of (+/-)-Funebrine and (+/-)-Funebral.

The Journal of organic chemistry

Dong Y, Niranjan N Pai N, Ablaza SL, Yu SX, Bolvig S, Forsyth DA, Le Quesne PW.
PMID: 11674333
J Org Chem. 1999 Apr 16;64(8):2657-2666. doi: 10.1021/jo981501u.

Syntheses of racemic forms of the main secondary metabolites of Quararibea funebris, (+/-)-funebrine, (+/-)-funebral, and their biogenetic precursor (+/-)-(2S,3S,4R)-gamma-hydroxyalloisoluecine lactone have been developed. In synthetic studies, a new variation of the Paal-Knorr condensation employing titanium isopropoxide was utilized to...

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Dong Y, Niranjan N Pai N, Ablaza SL, et al. Quararibea Metabolites. 4.(1) Total Synthesis and Conformational Studies of (+/-)-Funebrine and (+/-)-Funebral. J Org Chem. 1999;64(8):2657-2666doi: 10.1021/jo981501u.
Dong, Y., Niranjan N Pai, N., Ablaza, S. L., Yu, S. X., Bolvig, S., Forsyth, D. A., & Le Quesne, P. W. (1999). Quararibea Metabolites. 4.(1) Total Synthesis and Conformational Studies of (+/-)-Funebrine and (+/-)-Funebral. The Journal of organic chemistry, 64(8), 2657-2666. https://doi.org/10.1021/jo981501u
Dong, Ying, et al. "Quararibea Metabolites. 4.(1) Total Synthesis and Conformational Studies of (+/-)-Funebrine and (+/-)-Funebral." The Journal of organic chemistry vol. 64,8 (1999): 2657-2666. doi: https://doi.org/10.1021/jo981501u
Dong Y, Niranjan N Pai N, Ablaza SL, Yu SX, Bolvig S, Forsyth DA, Le Quesne PW. Quararibea Metabolites. 4.(1) Total Synthesis and Conformational Studies of (+/-)-Funebrine and (+/-)-Funebral. J Org Chem. 1999 Apr 16;64(8):2657-2666. doi: 10.1021/jo981501u. PMID: 11674333.
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Total Synthesis of the Marine Natural Product 7-Deoxy-okadaic Acid: A Potent Inhibitor of Serine/Threonine-Specific Protein Phosphatases.

Angewandte Chemie (International ed. in English)

Dounay AB, Urbanek RA, Sabes SF, Forsyth CJ.
PMID: 10425503
Angew Chem Int Ed Engl. 1999 Aug;38(15):2258-2262.

A small change to the structure of okadaic acid (1), the omission of the single hydroxy group at C7, facilitated substantially the first total synthesis of the derivative 7-deoxyokadaic acid (2). The conformation of 2 is in agreement with...

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Dounay AB, Urbanek RA, Sabes SF, et al. Total Synthesis of the Marine Natural Product 7-Deoxy-okadaic Acid: A Potent Inhibitor of Serine/Threonine-Specific Protein Phosphatases. Angew Chem Int Ed Engl. 1999;38(15):2258-2262
Dounay, A. B., Urbanek, R. A., Sabes, S. F., & Forsyth, C. J. (1999). Total Synthesis of the Marine Natural Product 7-Deoxy-okadaic Acid: A Potent Inhibitor of Serine/Threonine-Specific Protein Phosphatases. Angewandte Chemie (International ed. in English), 38(15), 2258-2262.
Dounay, et al. "Total Synthesis of the Marine Natural Product 7-Deoxy-okadaic Acid: A Potent Inhibitor of Serine/Threonine-Specific Protein Phosphatases." Angewandte Chemie (International ed. in English) vol. 38,15 (1999): 2258-2262.
Dounay AB, Urbanek RA, Sabes SF, Forsyth CJ. Total Synthesis of the Marine Natural Product 7-Deoxy-okadaic Acid: A Potent Inhibitor of Serine/Threonine-Specific Protein Phosphatases. Angew Chem Int Ed Engl. 1999 Aug;38(15):2258-2262. PMID: 10425503.
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Dual temperature and strain measurement with the combined fluorescence lifetime and Bragg wavelength shift approach in doped optical fiber.

Applied optics

Forsyth DI, Wade SA, Sun T, Chen X, Grattan KT.
PMID: 12412649
Appl Opt. 2002 Nov 01;41(31):6585-92. doi: 10.1364/ao.41.006585.

We have constructed fiber-optic sensors to measure temperature and strain by combining the properties of fiber Bragg gratings with the fluorescent lifetimes of various doped fibers. Sensors have been made with the fiber Bragg grating written directly into the...

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Forsyth DI, Wade SA, Sun T, et al. Dual temperature and strain measurement with the combined fluorescence lifetime and Bragg wavelength shift approach in doped optical fiber. Appl Opt. 2002;41(31):6585-92doi: 10.1364/ao.41.006585.
Forsyth, D. I., Wade, S. A., Sun, T., Chen, X., & Grattan, K. T. (2002). Dual temperature and strain measurement with the combined fluorescence lifetime and Bragg wavelength shift approach in doped optical fiber. Applied optics, 41(31), 6585-92. https://doi.org/10.1364/ao.41.006585
Forsyth, David I, et al. "Dual temperature and strain measurement with the combined fluorescence lifetime and Bragg wavelength shift approach in doped optical fiber." Applied optics vol. 41,31 (2002): 6585-92. doi: https://doi.org/10.1364/ao.41.006585
Forsyth DI, Wade SA, Sun T, Chen X, Grattan KT. Dual temperature and strain measurement with the combined fluorescence lifetime and Bragg wavelength shift approach in doped optical fiber. Appl Opt. 2002 Nov 01;41(31):6585-92. doi: 10.1364/ao.41.006585. PMID: 12412649.
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Use of ionic liquids for pi-conjugated polymer electrochemical devices.

Science (New York, N.Y.)

Lu W, Fadeev AG, Qi B, Smela E, Mattes BR, Ding J, Spinks GM, Mazurkiewicz J, Zhou D, Wallace GG, MacFarlane DR, Forsyth SA, Forsyth M.
PMID: 12098704
Science. 2002 Aug 09;297(5583):983-7. doi: 10.1126/science.1072651. Epub 2002 Jul 04.

pi-Conjugated polymers that are electrochemically cycled in ionic liquids have enhanced lifetimes without failure (up to 1 million cycles) and fast cycle switching speeds (100 ms). We report results for electrochemical mechanical actuators, electrochromic windows, and numeric displays made...

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Lu W, Fadeev AG, Qi B, et al. Use of ionic liquids for pi-conjugated polymer electrochemical devices. Science. 2002;297(5583):983-7doi: 10.1126/science.1072651.
Lu, W., Fadeev, A. G., Qi, B., Smela, E., Mattes, B. R., Ding, J., Spinks, G. M., Mazurkiewicz, J., Zhou, D., Wallace, G. G., MacFarlane, D. R., Forsyth, S. A., & Forsyth, M. (2002). Use of ionic liquids for pi-conjugated polymer electrochemical devices. Science (New York, N.Y.), 297(5583), 983-7. https://doi.org/10.1126/science.1072651
Lu, Wen, et al. "Use of ionic liquids for pi-conjugated polymer electrochemical devices." Science (New York, N.Y.) vol. 297,5583 (2002): 983-7. doi: https://doi.org/10.1126/science.1072651
Lu W, Fadeev AG, Qi B, Smela E, Mattes BR, Ding J, Spinks GM, Mazurkiewicz J, Zhou D, Wallace GG, MacFarlane DR, Forsyth SA, Forsyth M. Use of ionic liquids for pi-conjugated polymer electrochemical devices. Science. 2002 Aug 09;297(5583):983-7. doi: 10.1126/science.1072651. Epub 2002 Jul 04. PMID: 12098704.
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Effects of interparticle force on the packing of spherical granular material.

Physical review letters

Forsyth AJ, Hutton SR, Osborne CF, Rhodes MJ.
PMID: 11736504
Phys Rev Lett. 2001 Dec 10;87(24):244301. doi: 10.1103/PhysRevLett.87.244301. Epub 2001 Nov 26.

We present a study of the influence of interparticle cohesive forces on the packing of spheres. This is achieved by changing the external magnetic field on iron spheres in the millimeter size range. The force of cohesion between two...

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Forsyth AJ, Hutton SR, Osborne CF, et al. Effects of interparticle force on the packing of spherical granular material. Phys Rev Lett. 2001;87(24):244301doi: 10.1103/PhysRevLett.87.244301.
Forsyth, A. J., Hutton, S. R., Osborne, C. F., & Rhodes, M. J. (2001). Effects of interparticle force on the packing of spherical granular material. Physical review letters, 87(24), 244301. https://doi.org/10.1103/PhysRevLett.87.244301
Forsyth, A J, et al. "Effects of interparticle force on the packing of spherical granular material." Physical review letters vol. 87,24 (2001): 244301. doi: https://doi.org/10.1103/PhysRevLett.87.244301
Forsyth AJ, Hutton SR, Osborne CF, Rhodes MJ. Effects of interparticle force on the packing of spherical granular material. Phys Rev Lett. 2001 Dec 10;87(24):244301. doi: 10.1103/PhysRevLett.87.244301. Epub 2001 Nov 26. PMID: 11736504.
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Showing 1 to 12 of 309 entries