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Showing 1 to 12 of 25 entries
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A Molecular Boroauride: A Donor-Acceptor Complex of Anionic Gold.

Angewandte Chemie (International ed. in English)

Taylor JW, McSkimming A, Moret ME, Harman WH.
PMID: 28589611
Angew Chem Int Ed Engl. 2017 Aug 21;56(35):10413-10417. doi: 10.1002/anie.201703235. Epub 2017 Jun 27.

Gold is unique among the transition metals in that it is stable as an isolated anion (auride). Despite this fact, the coordination chemistry of anionic gold is virtually nonexistent, and this unique oxidation state is not readily exploited in...

An Anthracene-Based Photochromic System That Responds to Two Chemical Inputs We thank the EPSRC (UK) for the award of a project studentship (to G.M.).

Angewandte Chemie (International ed. in English)

McSkimming G, Tucker JH, Bouas-Laurent H, Desvergne JP.
PMID: 10941050
Angew Chem Int Ed Engl. 2000 Jun 16;39(12):2167-2169. doi: 10.1002/1521-3773(20000616)39:12<2167::aid-anie2167>3.0.co;2-9.

No abstract available.

Selective nuclear export of mRNAs is promoted by DRBD18 in Trypanosoma brucei.

Molecular microbiology

Mishra A, Kaur JN, McSkimming DI, Hegedűsová E, Dubey AP, Ciganda M, Paris Z, Read LK.
PMID: 34146438
Mol Microbiol. 2021 Sep;116(3):827-840. doi: 10.1111/mmi.14773. Epub 2021 Jul 04.

Kinetoplastids, including Trypanosoma brucei, control gene expression primarily at the posttranscriptional level. Nuclear mRNA export is an important, but understudied, step in this process. The general heterodimeric export factors, Mex67/Mtr2, function in the export of mRNAs and tRNAs in...

Correction: Yoo, J.Y., et al. Gut Microbiota and Immune System Interactions. .

Microorganisms

Yoo JY, Groer M, Dutra SVO, Sarkar A, McSkimming DI.
PMID: 33371530
Microorganisms. 2020 Dec 21;8(12). doi: 10.3390/microorganisms8122046.

Corrections have been made to "Gut Microbiota and Immune System Interactions" [...].

Complexation and redox chemistry of neptunium, plutonium and americium with a hydroxylaminato ligand.

Chemical science

Su J, Cheisson T, McSkimming A, Goodwin CAP, DiMucci IM, Albrecht-Schönzart T, Scott BL, Batista ER, Gaunt AJ, Kozimor SA, Yang P, Schelter EJ.
PMID: 34777753
Chem Sci. 2021 Sep 03;12(40):13343-13359. doi: 10.1039/d1sc03905a. eCollection 2021 Oct 20.

There is significant interest in ligands that can stabilize actinide ions in oxidation states that can be exploited to chemically differentiate 5f and 4f elements. Applications range from developing large-scale actinide separation strategies for nuclear industry processing to carrying...

CO.

Chemical science

Taylor JW, McSkimming A, Essex LA, Harman WH.
PMID: 31827750
Chem Sci. 2019 Aug 06;10(39):9084-9090. doi: 10.1039/c9sc02792k. eCollection 2019 Oct 21.

Borohydrides are widely used reducing agents in chemical synthesis and have emerging energy applications as hydrogen storage materials and reagents for the reduction of CO

Substantial Differences in the Subgingival Microbiome Measured by 16S Metagenomics According to Periodontitis Status in Older Women.

Dentistry journal

LaMonte MJ, Genco RJ, Zheng W, McSkimming DI, Andrews CA, Hovey KM, Li L, Sun Y, Buck MJ, Millen AE, Falkner KL, Wactawski-Wende J.
PMID: 30347640
Dent J (Basel). 2018 Oct 19;6(4). doi: 10.3390/dj6040058.

Aging invokes physiological changes, such as immunosenescence and inflammation, that could increase host susceptibility to oral microbiome shifts that enable periodontitis progression in later life. At present, there is a dearth of studies specifically evaluating the oral microbiome and...

Multiple Bonding in Lanthanides and Actinides: Direct Comparison of Covalency in Thorium(IV)- and Cerium(IV)-Imido Complexes.

Journal of the American Chemical Society

Cheisson T, Kersey KD, Mahieu N, McSkimming A, Gau MR, Carroll PJ, Schelter EJ.
PMID: 31117665
J Am Chem Soc. 2019 Jun 12;141(23):9185-9190. doi: 10.1021/jacs.9b04061. Epub 2019 Jun 03.

A series of thorium(IV)-imido complexes was synthesized and characterized. Extensive experimental and computational comparisons with the isostructural cerium(IV)-imido complexes revealed a notably more covalent bonding arrangement for the Ce═N bond compared with the more ionic Th═N bond. The thorium-imido...

Gut Microbiota and Immune System Interactions.

Microorganisms

Yoo JY, Groer M, Dutra SVO, Sarkar A, McSkimming DI.
PMID: 33076307
Microorganisms. 2020 Oct 15;8(10). doi: 10.3390/microorganisms8101587.

Dynamic interactions between gut microbiota and a host's innate and adaptive immune systems play key roles in maintaining intestinal homeostasis and inhibiting inflammation. The gut microbiota metabolizes proteins and complex carbohydrates, synthesize vitamins, and produce an enormous number of...

Unconjugated p-cresol activates macrophage macropinocytosis leading to increased LDL uptake.

JCI insight

Chaves LD, Abyad S, Honan AM, Bryniarski MA, McSkimming DI, Stahura CM, Wells SC, Ruszaj DM, Morris ME, Quigg RJ, Yacoub R.
PMID: 33914709
JCI Insight. 2021 Jun 08;6(11). doi: 10.1172/jci.insight.144410.

Patients with chronic kidney disease (CKD) and end-stage renal disease suffer from increased cardiovascular events and cardiac mortality. Prior studies have demonstrated that a portion of this enhanced risk can be attributed to the accumulation of microbiota-derived toxic metabolites,...

Photoinduced formation of a cryptand from a coronand: an unexpected switch in cation binding affinity.

Chemistry (Weinheim an der Bergstrasse, Germany)

McSkimming G, Tucker JH, Bouas-Laurent H, Desvergne JP, Coles SJ, Hursthouse MB, Light ME.
PMID: 12203314
Chemistry. 2002 Aug 02;8(15):3331-42. doi: 10.1002/1521-3765(20020802)8:15<3331::AID-CHEM3331>3.0.CO;2-C.

Aza-crown ethers 2 and 3 with anthracene-containing pendant arms have been synthesised and characterised. Both compounds bind Group 1 metal cations in solution, forming complexes of 1:1 stoichiometry. The properties of compound 2 and its complexes have been studied...

The coordination chemistry of organo-hydride donors: new prospects for efficient multi-electron reduction.

Chemical Society reviews

McSkimming A, Colbran SB.
PMID: 23507957
Chem Soc Rev. 2013 Jun 21;42(12):5439-88. doi: 10.1039/c3cs35466k.

In biological reduction processes the dihydronicotinamides NAD(P)H often transfer hydride to an unsaturated substrate bound within an enzyme active site. In many cases, metal ions in the active site bind, polarize and thereby activate the substrate to direct attack...

Showing 1 to 12 of 25 entries