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Showing 1 to 12 of 151 entries
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From stoplight reports to time series: equipping boards and leadership teams to drive better decisions.

BMJ quality & safety

Mountford J, Wakefield D.
PMID: 27034338
BMJ Qual Saf. 2017 Jan;26(1):9-11. doi: 10.1136/bmjqs-2016-005303. Epub 2016 Mar 31.

No abstract available.

Bis(phenolate)amine-supported lanthanide borohydride complexes for styrene and trans-1,4-isoprene (co-)polymerisations.

Dalton transactions (Cambridge, England : 2003)

Bonnet F, Dyer HE, El Kinani Y, Dietz C, Roussel P, Bria M, Visseaux M, Zinck P, Mountford P.
PMID: 25997125
Dalton Trans. 2015 Jul 21;44(27):12312-25. doi: 10.1039/c5dt00252d.

New bis(phenolate)amine-supported neodymium borohydride complexes and their previously reported samarium analogues were tested as catalysts for the polymerisation of styrene and isoprene. Reaction of Na2O2N(L) (L = py, OMe, NMe2) with Nd(BH4)3(THF)3 afforded the borohydride complexes Nd(O2N(L))(BH4)(THF) (L =...

Hitchhiker's Guide to Voxel Segmentation for Partial Volume Correction of In Vivo Magnetic Resonance Spectroscopy.

Magnetic resonance insights

Quadrelli S, Mountford C, Ramadan S.
PMID: 27147822
Magn Reson Insights. 2016 Apr 27;9:1-8. doi: 10.4137/MRI.S32903. eCollection 2016.

Partial volume effects have the potential to cause inaccuracies when quantifying metabolites using proton magnetic resonance spectroscopy (MRS). In order to correct for cerebrospinal fluid content, a spectroscopic voxel needs to be segmented according to different tissue contents. This...

Synthesis and reactivity of calix[4]arene-supported group 4 imido complexes.

Chemistry (Weinheim an der Bergstrasse, Germany)

Dubberley SR, Friedrich A, Willman DA, Mountford P, Radius U.
PMID: 12898691
Chemistry. 2003 Aug 04;9(15):3634-54. doi: 10.1002/chem.200204656.

New mononuclear titanium and zirconium imido complexes [M(NR)(R'(2)calix)] [M=Ti, R'=Me, R=tBu (1), R=2,6-C(6)H(3)Me(2) (2), R=2,6-C(6)H(3)iPr(2) (3), R=2,4,6-C(6)H(2)Me(3) (4); M=Ti, R'=Bz, R=tBu (5), R=2,6-C(6)H(3)Me(2) (6), R=2,6-C(6)H(3)iPr(2) (7); M=Zr, R'=Me, R=2,6-C(6)H(3)iPr(2) (8)] supported by 1,3-diorganyl ether p-tert-butylcalix[4]arenes (R'(2)calix) were prepared in...

Recent developments in the non-cyclopentadienyl organometallic and related chemistry of scandium.

Chemical communications (Cambridge, England)

Mountford P, Ward BD.
PMID: 12931975
Chem Commun (Camb). 2003 Aug 07;(15):1797-803. doi: 10.1039/b212813f.

Up to the early to mid 1990s the organometallic chemistry of scandium was dominated by cyclopentadienyl derivatives. This present article highlights advances in the synthesis and reactivity of non-cyclopentadienyl organometallic and related compounds of scandium. These include: compounds containing...

Titanium tert-butyl- and trimethylsilyl-imido complexes with monopendant arm triazacyclononane ligands.

Inorganic chemistry

Gardner JD, Robson DA, Rees LH, Mountford P.
PMID: 11225131
Inorg Chem. 2001 Feb 12;40(4):820-4. doi: 10.1021/ic0009728.

No abstract available.

Vaccination against Schistosomiasis: The case for Lung-stage Antigens.

Parasitology today (Personal ed.)

Mountford AP, Harrop R.
PMID: 17040717
Parasitol Today. 1998 Mar;14(3):109-14. doi: 10.1016/s0169-4758(97)01169-1.

The development of an effective vaccine against human schistosomiasis remains a highly desirable yet elusive goal. In this article, Adrian Mountford and Richard Harrop focus attention on an approach that aims to identify proteins from Schistosoma mansoni that are...

New titanium imido synthons: syntheses and supramolecular structures.

Inorganic chemistry

Adams N, Bigmore HR, Blundell TL, Boyd CL, Dubberley SR, Sealey AJ, Cowley AR, Skinner ME, Mountford P.
PMID: 15819576
Inorg Chem. 2005 Apr 18;44(8):2882-94. doi: 10.1021/ic050011z.

Reactions of Ti(NMe(2))(2)Cl(2) with a wide range of primary alkyl and arylamines RNH(2) afforded the corresponding 5-coordinate imido titanium compounds Ti(NR)Cl(2)(NHMe(2))(2) (R = (t)Bu (1), (i)Pr (2), CH(2)Ph (3), Ph (4), 2,6-C(6)H(3)Me(2) (5), 2,6-C(6)H(3)(i)Pr(2) (6), 2,4,6-C(6)H(2)F(3) (7), 2,3,5,6-C(6)HF(4) (8),...

Single and double substrate insertion into the Ti=N(alpha) bonds of terminal titanium hydrazides.

Chemical communications (Cambridge, England)

Tiong PJ, Schofield AD, Selby JD, Nova A, Clot E, Mountford P.
PMID: 20024301
Chem Commun (Camb). 2010 Jan 07;46(1):85-7. doi: 10.1039/b920090h. Epub 2009 Nov 19.

Nitriles, CO(2) and isocyanates undergo net single or double insertion reactions into the Ti=N(alpha) multiple bonds of terminal titanium hydrazides. These are the first such examples of this type of reactivity for any transition metal hydrazide complex.

Imido titanium compounds bearing the 6-dimethylamino-1,4,6-trimethyl-1,4-diazacycloheptane ligand: synthesis, structures, solution dynamics and ethylene polymerisation capability.

Dalton transactions (Cambridge, England : 2003)

Hayday GJ, Wang C, Rees NH, Mountford P.
PMID: 18560662
Dalton Trans. 2008 Jul 07;(25):3301-10. doi: 10.1039/b802027b. Epub 2008 Apr 09.

Reaction of Me(4)DACH (6-dimethylamino-1,4,6-trimethyl-1,4-diazacycloheptane) with Ti(N(t)Bu)Cl(2)(py)(3) or Ti(N(t)Bu)Cl(2)(NHMe(2))(2) gave Ti(N(t)Bu)(Me(4)DACH)Cl(2) (1) which in CD(2)Cl(2) solution exists as a mixture of trans and cis isomers (defined with respect to the imido ligand and the exocyclic NMe(2) donor of Me(4)DACH). Aryl...

The synthesis, molecular structure and supramolecular architecture of complexes between the ammonia adduct of tris(pentafluorophenyl)boron and a series of mono and polydentate hydrogen-bond acceptors.

Dalton transactions (Cambridge, England : 2003)

Fuller AM, Mountford AJ, Coles SJ, Horton PN, Hughes DL, Hursthouse MB, Male L, Lancaster SJ.
PMID: 19002324
Dalton Trans. 2008 Dec 07;(45):6381-92. doi: 10.1039/b808208a. Epub 2008 Sep 30.

The ammonia adduct of tris(pentafluorophenyl)boron, (C6F5)3B.NH3, is a potentially tri-functional hydrogen-bond donor. Co-crystallisation with the bases acetonitrile, pyridine, tetrahydrofuran, tetramethylethylenediamine, 15-crown-5, 1,4-diazabicyclo[2.2.2]octane (DABCO), pyrazine and 4,4'-bipyridine results, not in donor exchange, but in the formation of supermolecules assembled through...

Heterobimetallic complexes containing Ca-Fe or Yb-Fe bonds: synthesis and molecular and electronic structures of [M{CpFe(CO)2}2(THF)3]2 (M = Ca or Yb).

Journal of the American Chemical Society

Blake MP, Kaltsoyannis N, Mountford P.
PMID: 21888401
J Am Chem Soc. 2011 Oct 05;133(39):15358-61. doi: 10.1021/ja207487j. Epub 2011 Sep 12.

Reaction of calcium or ytterbium amalgam with [CpFe(CO)(2)](2) (Fp(2)) gave the isostructural heavy alkaline earth or divalent rare earth compounds [MFp(2)(THF)(3)](2) (M = Ca or Yb) containing two direct Ca-Fe (3.0185(6) Å) or Yb-Fe (2.9892(4) Å) bonds. Density functional...

Showing 1 to 12 of 151 entries