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Showing 1 to 12 of 209 entries
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Atmospheric pressure soft ionization for gas chromatography with dielectric barrier discharge ionization-mass spectrometry (GC-DBDI-MS).

The Analyst

Mirabelli MF, Wolf JC, Zenobi R.
PMID: 28443843
Analyst. 2017 May 30;142(11):1909-1915. doi: 10.1039/c7an00245a.

In this study, a gas chromatography (GC) system was interfaced to a high-resolution Orbitrap mass spectrometer by means of an active capillary plasma ionization source, based on dielectric barrier discharge ionization (DBDI). This allowed highly efficient soft ionization of...

Letters.

Nursing older people

Chan Z.
PMID: 27707346
Nurs Older People. 2003 Jul 01;15(5):34. doi: 10.7748/nop.15.5.34.s16.

I was delighted to read your editorial highlighting good care and would like to add my own example. My grandmother-in-law is 93, has lost visual and hearing functioning completely and lives in an old age care home where the...

Direct gas-phase detection of nerve and blister warfare agents utilizing active capillary plasma ionization mass spectrometry.

European journal of mass spectrometry (Chichester, England)

Wolf JC, Schaer M, P Siegenthaler P, Zenobi R.
PMID: 26307710
Eur J Mass Spectrom (Chichester). 2015;21(3):305-12. doi: 10.1255/ejms.1347.

Ultrasensitive direct gas-phase detection of chemical warfare agents (CWAs) is demonstrated utilizing active capillary plasma ionization and triple quadrupole mass spectrometry (MS) instrumentation. Four G- agents, two V-agents and various blistering agents [including sulfur mustard (HD)] were detected directly...

Minimally invasive characterization of covalent monolayer sheets using tip-enhanced Raman spectroscopy.

ACS nano

Opilik L, Payamyar P, Szczerbiński J, Schütz AP, Servalli M, Hungerland T, Schlüter AD, Zenobi R.
PMID: 25803562
ACS Nano. 2015 Apr 28;9(4):4252-9. doi: 10.1021/acsnano.5b00629. Epub 2015 Mar 31.

Synthetic covalent monolayer sheets and their subclass, two-dimensional polymers are of particular interest in materials science because of their special dimensionality which renders them very different from any bulk matter. However, structural analysis of such entities is rather challenging,...

Towards an Accurate and Precise Chronology for the Colonization of Australia: The Example of Riwi, Kimberley, Western Australia.

PloS one

Wood R, Jacobs Z, Vannieuwenhuyse D, Balme J, O'Connor S, Whitau R.
PMID: 27655174
PLoS One. 2016 Sep 21;11(9):e0160123. doi: 10.1371/journal.pone.0160123. eCollection 2016.

An extensive series of 44 radiocarbon (14C) and 37 optically stimulated luminescence (OSL) ages have been obtained from the site of Riwi, south central Kimberley (NW Australia). As one of the earliest known Pleistocene sites in Australia, with archaeologically...

A Radical-Mediated Pathway for the Formation of [M + H](+) in Dielectric Barrier Discharge Ionization.

Journal of the American Society for Mass Spectrometry

Wolf JC, Gyr L, Mirabelli MF, Schaer M, Siegenthaler P, Zenobi R.
PMID: 27380388
J Am Soc Mass Spectrom. 2016 Sep;27(9):1468-75. doi: 10.1007/s13361-016-1420-2. Epub 2016 Jul 05.

Active capillary plasma ionization is a highly efficient ambient ionization method. Its general principle of ion formation is closely related to atmospheric pressure chemical ionization (APCI). The method is based on dielectric barrier discharge ionization (DBDI), and can be...

Non-linear photoelectron effect contributes to the formation of negative matrix ions in UV-MALDI.

Physical chemistry chemical physics : PCCP

Alonso E, Zenobi R.
PMID: 27181273
Phys Chem Chem Phys. 2016 Jul 20;18(29):19574-87. doi: 10.1039/c6cp00649c.

The mechanism of negative ion formation in matrix-assisted laser desorption/ionization (MALDI) is less well understood than that of positive ions: electron capture, disproportionation, and liberation of negatively charged sample molecules or clusters have been proposed to produce the initial...

Scanning Near-Field Optical Microscopy and Spectroscopy as a Tool for Chemical Analysis.

Angewandte Chemie (International ed. in English)

Zenobi R, Deckert V.
PMID: 10934352
Angew Chem Int Ed Engl. 2000 May 15;39(10):1746-1756. doi: 10.1002/(sici)1521-3773(20000515)39:10<1746::aid-anie1746>3.0.co;2-q.

Research into the nanometer-scale region is currently of relevance in many branches of modern science and engineering, such as in microelectronics, supramolecular chemistry, and in a biological context. A great deal of attention is given to the design of...

Deceleration of high-energy matrix-assisted laser desorption/ionization ions in an open cell for Fourier transform ion cyclotron resonance mass spectrometry.

Rapid communications in mass spectrometry : RCM

Frankevich V, Zenobi R.
PMID: 11675671
Rapid Commun Mass Spectrom. 2001;15(21):2035-40. doi: 10.1002/rcm.474.

A new method of ion deceleration in a Fourier transform ion cyclotron resonance (FTICR) open cell is described that improves the performance of FTICR-MS instruments equipped with an internal source for laser desorption/ionization. Ion deceleration occurs in the front...

Internal energies of analyte ions generated from different matrix-assisted laser desorption/ionization matrices.

Journal of mass spectrometry : JMS

Stevenson E, Breuker K, Zenobi R.
PMID: 10973003
J Mass Spectrom. 2000 Aug;35(8):1035-41. doi: 10.1002/1096-9888(200008)35:8<1035::AID-JMS34>3.0.CO;2-V.

A transfer of energy into the internal modes of the matrix and analyte is expected to occur during matrix-assisted laser desorption/ioniziation (MALDI) processes. Both the physical and thermochemical properties of the MALDI matrix used can influence the ion internal...

MALDI ionization: the role of in-plume processes.

Chemical reviews

Knochenmuss R, Zenobi R.
PMID: 12580638
Chem Rev. 2003 Feb;103(2):441-52. doi: 10.1021/cr0103773.

No abstract available.

A mass spectrometry and electron paramagnetic resonance study of photochemical and thermal aging of triterpenoid varnishes.

Analytical chemistry

Dietemann P, Kälin M, Zumbühl S, Knochenmuss R, Wülfert S, Zenobi R.
PMID: 11354495
Anal Chem. 2001 May 01;73(9):2087-96. doi: 10.1021/ac000754w.

Photochemical and thermal aging of triterpenoid dammar and mastic resins used as varnishes on paintings were studied using graphite-assisted laser desorption/ionization mass spectrometry. This extends an earlier study on similar materials (Zumbühl et al., Anal. Chem. 1998, 70, 707-715)...

Showing 1 to 12 of 209 entries