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Chakraborty D, Horchler S, Krätzner R, et al. Synthesis and structural characterization of functionalized dimeric aluminophosphonates and a monomeric gallophosphonate anion. Inorg Chem. 2001;40(11):2620-4doi: 10.1021/ic000797v.
Chakraborty, D., Horchler, S., Krätzner, R., Varkey, S. P., Pinkas, J., Roesky, H. W., Usón, I., Noltemeyer, M., & Schmidt, H. G. (2001). Synthesis and structural characterization of functionalized dimeric aluminophosphonates and a monomeric gallophosphonate anion. Inorganic chemistry, 40(11), 2620-4. https://doi.org/10.1021/ic000797v
Chakraborty, D, et al. "Synthesis and structural characterization of functionalized dimeric aluminophosphonates and a monomeric gallophosphonate anion." Inorganic chemistry vol. 40,11 (2001): 2620-4. doi: https://doi.org/10.1021/ic000797v
Chakraborty D, Horchler S, Krätzner R, Varkey SP, Pinkas J, Roesky HW, Usón I, Noltemeyer M, Schmidt HG. Synthesis and structural characterization of functionalized dimeric aluminophosphonates and a monomeric gallophosphonate anion. Inorg Chem. 2001 May 21;40(11):2620-4. doi: 10.1021/ic000797v. PMID: 11350243.
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Inorg Chem. 2001 May 21;40(11):2620-4. doi: 10.1021/ic000797v.

Synthesis and structural characterization of functionalized dimeric aluminophosphonates and a monomeric gallophosphonate anion.

Inorganic chemistry

D Chakraborty, S Horchler, R Krätzner, S P Varkey, J Pinkas, H W Roesky, I Usón, M Noltemeyer, H G Schmidt

Affiliations

  1. Institut für Anorganische Chemie der Universität Göttingen, Tammannstrasse 4, D-37077 Göttingen, Germany.

PMID: 11350243 DOI: 10.1021/ic000797v

Abstract

Reaction of t-BuP(O)(OSiMe(3))(OH) with Me(3)Al leads to the formation of [Me(2)Al(mu-O)(2)P(OSiMe(3))(t-Bu)](2) (1) whereas Me(2)AlCl reacts with Ph(2)P(O)(OH) to yield [(Cl)(Me)Al(mu-O)(2)PPh(2)](2) (2). These compounds represent the first examples of functionalized dimeric four-ring type aluminophosphonate systems. The double four-ring type gallophosphonate, namely, [t-BuPO(3)GaMe](4), reacts with n-Bu(4)NHF(2) under ambient conditions, resulting in the formation of a monomeric gallophosphonate [n-Bu(4)N][MeGa[t-BuPO(2)(OH)](3)] (3). These derivatives have been adequately characterized using various spectroscopic techniques and X-ray diffraction studies.

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