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Yang Z, Ma X, Oswald RB, et al. Synthesis of an aluminum spirocyclic hybrid with an inorganic B2O3 and an organic C3N2 core. J Am Chem Soc. 2006;128(38):12406-7doi: 10.1021/ja064035w.
Yang, Z., Ma, X., Oswald, R. B., Roesky, H. W., & Noltemeyer, M. (2006). Synthesis of an aluminum spirocyclic hybrid with an inorganic B2O3 and an organic C3N2 core. Journal of the American Chemical Society, 128(38), 12406-7. https://doi.org/10.1021/ja064035w
Yang, Zhi, et al. "Synthesis of an aluminum spirocyclic hybrid with an inorganic B2O3 and an organic C3N2 core." Journal of the American Chemical Society vol. 128,38 (2006): 12406-7. doi: https://doi.org/10.1021/ja064035w
Yang Z, Ma X, Oswald RB, Roesky HW, Noltemeyer M. Synthesis of an aluminum spirocyclic hybrid with an inorganic B2O3 and an organic C3N2 core. J Am Chem Soc. 2006 Sep 27;128(38):12406-7. doi: 10.1021/ja064035w. PMID: 16984177.
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J Am Chem Soc. 2006 Sep 27;128(38):12406-7. doi: 10.1021/ja064035w.

Synthesis of an aluminum spirocyclic hybrid with an inorganic B2O3 and an organic C3N2 core.

Journal of the American Chemical Society

Zhi Yang, Xiaoli Ma, Rainer B Oswald, Herbert W Roesky, Mathias Noltemeyer

Affiliations

  1. Institut für Anorganische Chemie der Universität Göttingen, Tammannstrasse 4, D-37077 Göttingen, Germany.

PMID: 16984177 DOI: 10.1021/ja064035w

Abstract

The reaction of LAl (L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) or LAlH2 with PhB(OH)2 yields the unprecedented spirocyclic LAl[(OBPh)2O] compound. The former reaction proceeds under hydrogen formation and simultaneous oxidation of the aluminum(I).

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