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Matano Y, Saito A, Fukushima T, et al. Fusion of phosphole and 1,1'-biacenaphthene: phosphorus(V)-containing extended π-systems with high electron affinity and electron mobility. Angew Chem Int Ed Engl. 2011;50(35):8016-20doi: 10.1002/anie.201102782.
Matano, Y., Saito, A., Fukushima, T., Tokudome, Y., Suzuki, F., Sakamaki, D., Kaji, H., Ito, A., Tanaka, K., & Imahori, H. (2011). Fusion of phosphole and 1,1'-biacenaphthene: phosphorus(V)-containing extended π-systems with high electron affinity and electron mobility. Angewandte Chemie (International ed. in English), 50(35), 8016-20. https://doi.org/10.1002/anie.201102782
Matano, Yoshihiro, et al. "Fusion of phosphole and 1,1'-biacenaphthene: phosphorus(V)-containing extended π-systems with high electron affinity and electron mobility." Angewandte Chemie (International ed. in English) vol. 50,35 (2011): 8016-20. doi: https://doi.org/10.1002/anie.201102782
Matano Y, Saito A, Fukushima T, Tokudome Y, Suzuki F, Sakamaki D, Kaji H, Ito A, Tanaka K, Imahori H. Fusion of phosphole and 1,1'-biacenaphthene: phosphorus(V)-containing extended π-systems with high electron affinity and electron mobility. Angew Chem Int Ed Engl. 2011 Aug 22;50(35):8016-20. doi: 10.1002/anie.201102782. Epub 2011 Jun 22. PMID: 21698736.
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Angew Chem Int Ed Engl. 2011 Aug 22;50(35):8016-20. doi: 10.1002/anie.201102782. Epub 2011 Jun 22.

Fusion of phosphole and 1,1'-biacenaphthene: phosphorus(V)-containing extended π-systems with high electron affinity and electron mobility.

Angewandte Chemie (International ed. in English)

Yoshihiro Matano, Arihiro Saito, Tatsuya Fukushima, Yasuaki Tokudome, Furitsu Suzuki, Daisuke Sakamaki, Hironori Kaji, Akihiro Ito, Kazuyoshi Tanaka, Hiroshi Imahori

Affiliations

  1. Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Japan. [email protected]

PMID: 21698736 DOI: 10.1002/anie.201102782

Abstract

A profusion of phospholes: Diacenaphtho[1,2-b:1',2'-d]phospholes, a new class of arene-fused phosphole π-systems, were synthesized and their structural and electrochemical properties studied. The P-sulfide derivative has a high electron-transporting ability (μ(E) =2.4×10(-3) cm(2) V(-1) s(-1)) in a vacuum-deposited film.

Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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