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Liang Z, Guo H, Zhou G, et al. Metal-Organic-Framework-Supported Molecular Electrocatalysis for the Oxygen Reduction Reaction. Angew Chem Int Ed Engl. 2021;60(15):8472-8476doi: 10.1002/anie.202016024.
Liang, Z., Guo, H., Zhou, G., Guo, K., Wang, B., Lei, H., Zhang, W., Zheng, H., Apfel, U. P., & Cao, R. (2021). Metal-Organic-Framework-Supported Molecular Electrocatalysis for the Oxygen Reduction Reaction. Angewandte Chemie (International ed. in English), 60(15), 8472-8476. https://doi.org/10.1002/anie.202016024
Liang, Zuozhong, et al. "Metal-Organic-Framework-Supported Molecular Electrocatalysis for the Oxygen Reduction Reaction." Angewandte Chemie (International ed. in English) vol. 60,15 (2021): 8472-8476. doi: https://doi.org/10.1002/anie.202016024
Liang Z, Guo H, Zhou G, Guo K, Wang B, Lei H, Zhang W, Zheng H, Apfel UP, Cao R. Metal-Organic-Framework-Supported Molecular Electrocatalysis for the Oxygen Reduction Reaction. Angew Chem Int Ed Engl. 2021 Apr 06;60(15):8472-8476. doi: 10.1002/anie.202016024. Epub 2021 Mar 03. PMID: 33484092.
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Angew Chem Int Ed Engl. 2021 Apr 06;60(15):8472-8476. doi: 10.1002/anie.202016024. Epub 2021 Mar 03.

Metal-Organic-Framework-Supported Molecular Electrocatalysis for the Oxygen Reduction Reaction.

Angewandte Chemie (International ed. in English)

Zuozhong Liang, Hongbo Guo, Guojun Zhou, Kai Guo, Bin Wang, Haitao Lei, Wei Zhang, Haoquan Zheng, Ulf-Peter Apfel, Rui Cao

Affiliations

  1. Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an, 710119, China.
  2. Ruhr-Universität Bochum, Fakultät für Chemie und Biochemie, Anorganische Chemie I, Universitätsstrasse 150, 44801, Bochum, Germany.
  3. Fraunhofer UMSICHT, Energy Division, Osterfelder Strasse 3, 46047, Oberhausen, Germany.

PMID: 33484092 DOI: 10.1002/anie.202016024

Abstract

Synthesizing molecule@support hybrids is appealing to improve molecular electrocatalysis. We report herein metal-organic framework (MOF)-supported Co porphyrins for the oxygen reduction reaction (ORR) with improved activity and selectivity. Co porphyrins can be grafted on MOF surfaces through ligand exchange. A variety of porphyrin@MOF hybrids were made using this method. Grafted Co porphyrins showed boosted ORR activity with large (>70 mV) anodic shift of the half-wave potential compared to ungrafted porphyrins. By using active MOFs for peroxide reduction, the number of electrons transferred per O

© 2021 Wiley-VCH GmbH.

Keywords: metal-air battery; metal-organic framework; molecular electrocatalysis; oxygen reduction; porphyrin

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