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Showing 1 to 12 of 36 entries
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Optical properties of protonated Rhodamine 19 isomers in solution and in the gas phase.

Physical chemistry chemical physics : PCCP

Chingin K, Balabin RM, Frankevich V, Chen H, Barylyuk K, Nieckarz R, Fedorov A, Zenobi R.
PMID: 20886159
Phys Chem Chem Phys. 2010 Nov 14;12(42):14121-7. doi: 10.1039/c0cp00482k. Epub 2010 Oct 01.

Visible light absorption and fluorescence of three positional isomers of protonated Rhodamine 19 (o-, m- and p-R19H(+)) were studied in solution and in the gas phase. In solution, strong solvatochromic effects lead to spectral shifts between rhodamine isomers. In...

On the chemistry of 1-pyrroline in solution and in the gas phase.

Scientific reports

Zhang X, Chingin K, Zhong D, Liang J, Ouyang Y, Chen H.
PMID: 28794423
Sci Rep. 2017 Aug 09;7(1):7675. doi: 10.1038/s41598-017-08217-1.

1-Pyrroline has a highly characteristic odor, which is employed by living organisms for chemical signaling and other purposes, but the mechanism whereby this odor is formed remains poorly understood. Here we used a combination of ambient mass spectrometry (AMS)...

Transient Ru-methyl formate intermediates generated with bifunctional transfer hydrogenation catalysts.

Proceedings of the National Academy of Sciences of the United States of America

Perry RH, Brownell KR, Chingin K, Cahill TJ, Waymouth RM, Zare RN.
PMID: 22315417
Proc Natl Acad Sci U S A. 2012 Feb 14;109(7):2246-50. doi: 10.1073/pnas.1118934109. Epub 2012 Feb 06.

Desorption electrospray ionization (DESI) coupled to high-resolution Orbitrap mass spectrometry (MS) was used to study the reactivity of a (β-amino alcohol)(arene)RuCl transfer hydrogenation catalytic precursor in methanol (CH(3)OH). By placing [(p-cymene)RuCl(2)](2) on a surface and spraying a solution of...

Enrichment of Surface-Active Compounds in Bursting Bubble Aerosols.

ACS omega

Chingin K, Yan R, Zhong D, Chen H.
PMID: 31459002
ACS Omega. 2018 Aug 07;3(8):8709-8717. doi: 10.1021/acsomega.8b01157. eCollection 2018 Aug 31.

The pronounced enrichment of surface-active compounds in the aerosols produced by bubble bursting plays a central role in the chemical transfer from the ocean into the atmosphere and has an important impact on the global Earth's climate. However, the...

Rapid detection of metal impurities on the surfaces of intact objects with irregular shapes using electrochemical mass spectrometry.

The Analyst

Song L, Xu J, Zhong D, Chingin K, Qu Y, Chen H.
PMID: 30984959
Analyst. 2019 May 28;144(11):3505-3510. doi: 10.1039/c8an02472c.

New approaches are demanded in daily life and industry for the rapid inspection of chemical impurities on various objects, particularly those with irregular shapes. Herein, an analytical strategy combining electrochemistry (EC) and mass spectrometry (MS) has been developed for...

The Role of Semaphorin 4D in Bone Remodeling and Cancer Metastasis.

Frontiers in endocrinology

Lontos K, Adamik J, Tsagianni A, Galson DL, Chirgwin JM, Suvannasankha A.
PMID: 29971044
Front Endocrinol (Lausanne). 2018 Jun 19;9:322. doi: 10.3389/fendo.2018.00322. eCollection 2018.

Semaphorin 4D (Sema4D; CD100) is a transmembrane homodimer 150-kDa glycoprotein member of the Semaphorin family. Semaphorins were first identified as chemorepellants that guide neural axon growth. Sema4D also possesses immune regulatory activity. Recent data suggest other Sema4D functions: inactivation...

Novel Therapeutic Strategies Applied to .

Materials (Basel, Switzerland)

Chirgwin ME, Dedloff MR, Holban AM, Gestal MC.
PMID: 31817881
Materials (Basel). 2019 Dec 07;12(24). doi: 10.3390/ma12244093.

Cystic fibrosis (CF) is one of the most prevalent genetic diseases and a total of 1700 different genetic mutations can cause this condition. Patients that suffer this disease have a thickening of the mucus, creating an environment that promotes...

Generation of Phenol and Molecular Hydrogen through Catalyst-Free C-H Activation of Benzene by Water Radical Cations.

Journal of the American Society for Mass Spectrometry

Mi D, Mao Y, Wei B, Li YC, Dong X, Chingin K.
PMID: 34936361
J Am Soc Mass Spectrom. 2022 Jan 05;33(1):68-73. doi: 10.1021/jasms.1c00268. Epub 2021 Dec 22.

Here, we report on the abundant formation of phenol and molecular hydrogen when benzene vapor was exposed to gas plasma generated by +5.5 kV corona discharge of water vapor in argon in the absence of oxygen. Systematic analysis using...

High ohmic resistor hyphenated gel loading tip nano-electrospray ionization source for mini mass spectrometer.

Talanta

Rahman MM, Wu D, Chingin K, Xu W, Chen H.
PMID: 31171225
Talanta. 2019 Sep 01;202:59-66. doi: 10.1016/j.talanta.2019.04.052. Epub 2019 Apr 20.

The deployment of mini mass spectrometers on the field strongly demands efficient ionization sources that are easy-to-operate. Nano-electrospray (nESI) ion source has been widely used in the field of chemistry, biology, medicine, pharmaceutical industry, clinical assessment and forensic science....

Sequential Formation of Analyte Ions Originated from Bulk Alloys for Ambient Mass Spectrometry Analysis.

Analytical chemistry

Xu J, Zhu T, Chingin K, Liu Y, Zhang H, Chen H.
PMID: 30406988
Anal Chem. 2018 Dec 04;90(23):13832-13836. doi: 10.1021/acs.analchem.8b04309. Epub 2018 Nov 14.

Rapid chemical decoding of bulk alloys to obtain both organic and elemental composition is of sustainable interest in multiple disciplines. Herein, an analytical strategy inherited from electrochemistry and mass spectrometry (MS) was developed for direct molecular characterization of alloys....

Interfacing capillary-based separations to mass spectrometry using desorption electrospray ionization.

Analytical chemistry

Barbula GK, Safi S, Chingin K, Perry RH, Zare RN.
PMID: 21319740
Anal Chem. 2011 Mar 15;83(6):1955-9. doi: 10.1021/ac102648k. Epub 2011 Feb 14.

The powerful hybrid analysis method of capillary-based separations followed by mass spectrometric analysis gives substantial chemical identity and structural information. It is usually carried out using electrospray ionization. However, the salts and detergents used in the mobile phase for...

Generation of Phenol and Molecular Hydrogen through Catalyst-Free C-H Activation of Benzene by Water Radical Cations.

Journal of the American Society for Mass Spectrometry

Mi D, Mao Y, Wei B, Li YC, Dong X, Chingin K.
PMID: 34936361
J Am Soc Mass Spectrom. 2021 Dec 22; doi: 10.1021/jasms.1c00268. Epub 2021 Dec 22.

Here, we report on the abundant formation of phenol and molecular hydrogen when benzene vapor was exposed to gas plasma generated by +5.5 kV corona discharge of water vapor in argon in the absence of oxygen. Systematic analysis using...

Showing 1 to 12 of 36 entries