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Showing 1 to 12 of 1173 entries
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Thermodynamically metastable thiocyanato coordination polymer that shows slow relaxations of the magnetization.

Inorganic chemistry

Werner J, Rams M, Tomkowicz Z, Runčevski T, Dinnebier RE, Suckert S, Näther C.
PMID: 25741770
Inorg Chem. 2015 Mar 16;54(6):2893-901. doi: 10.1021/ic503029t. Epub 2015 Mar 05.

Reaction of cobalt thiocyanate with 4-acetylpyridine leads to the formation of [Co(NCS)2(4-acetylpyridine)2]n (3/I). In its crystal structure the Co cations are connected by pairs of μ-1,3-bridging thiocyanato ligands into dimers that are further connected into layers by single anionic...

A stereoselective thiocyanate conjugate addition to electron deficient alkynes and concomitant cyclization to N,S-heterocycles.

Chemical communications (Cambridge, England)

Dwivedi V, Rajesh M, Kumar R, Kant R, Sridhar Reddy M.
PMID: 28948277
Chem Commun (Camb). 2017 Oct 05;53(80):11060-11063. doi: 10.1039/c7cc06081e.

A regio- and stereoselective thiocyanate addition to ynones is achieved using KSCN in AcOH at 70 °C. The reaction is extendable to ynals, ynesulfones, ynoic acids and ynoates. Adducts from ynones were readily transformed into thiazine-2-thione derivatives under slightly...

Vibrational studies of flexible solid polymer electrolyte based on PCL-EC incorporated with proton conducting NH4SCN.

Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy

Woo HJ, Arof AK.
PMID: 26945998
Spectrochim Acta A Mol Biomol Spectrosc. 2016 May 15;161:44-51. doi: 10.1016/j.saa.2016.02.034. Epub 2016 Mar 02.

A flexible solid polymer electrolyte (SPE) system based on poly(ε-caprolactone) (PCL), a FDA approved non-toxic and biodegradable material in the effort to lower environmental impact was prepared. Ammonium thiocyanate (NH4SCN) and ethylene carbonate (EC) were incorporated as the source...

Iodide transport: implications for health and disease.

International journal of pediatric endocrinology

Pesce L, Kopp P.
PMID: 25009573
Int J Pediatr Endocrinol. 2014;2014(1):8. doi: 10.1186/1687-9856-2014-8. Epub 2014 May 30.

Disorders of the thyroid gland are among the most common conditions diagnosed and managed by pediatric endocrinologists. Thyroid hormone synthesis depends on normal iodide transport and knowledge of its regulation is fundamental to understand the etiology and management of...

Qualitative test for the detection of extraneous thiocyanate in milk.

Journal of food science and technology

Kanthale P, Kumar A, Upadhyay N, Lal D, Rathod G, Sharma V.
PMID: 25745243
J Food Sci Technol. 2015 Mar;52(3):1698-704. doi: 10.1007/s13197-013-1174-9. Epub 2013 Sep 27.

Thiocyanate is one of the three components of lactoperoxidase system for preserving the milk under the conditions where chilling facilities do not exist due to economic and technical reasons. In 1988, International Dairy Federation (IDF) has recommended the levels...

Spectroscopic signatures of ligand field states in {Ru(II)(imine)} complexes.

Dalton transactions (Cambridge, England : 2003)

Cadranel A, Pieslinger GE, Tongying P, Kuno MK, Baraldo LM, Hodak JH.
PMID: 26841245
Dalton Trans. 2016 Apr 07;45(13):5464-75. doi: 10.1039/c5dt04332h. Epub 2016 Feb 03.

Ligand field (LF) states have been present in discussions on the photophysics and photochemistry of ruthenium-iminic chromophores for decades, although there is very little documented direct evidence of them. We studied the picosecond transient absorption (TA) spectroscopy of four...

Comparative Genome Analysis of Three Thiocyanate Oxidizing .

Frontiers in microbiology

Berben T, Overmars L, Sorokin DY, Muyzer G.
PMID: 28293216
Front Microbiol. 2017 Feb 28;8:254. doi: 10.3389/fmicb.2017.00254. eCollection 2017.

Thiocyanate is a C1 compound containing carbon, nitrogen, and sulfur. It is a (by)product in a number of natural and industrial processes. Because thiocyanate is toxic to many organisms, including humans, its removal from industrial waste streams is an...

Synthesis of 2-Thiocarbohydrates and Their Binding to Concanavalin A.

The Journal of organic chemistry

Pavashe P, Elamparuthi E, Hettrich C, Möller HM, Linker T.
PMID: 27518032
J Org Chem. 2016 Sep 16;81(18):8595-603. doi: 10.1021/acs.joc.6b00987. Epub 2016 Aug 30.

A convenient and general synthesis of 2-thiocarbohydrates via cerium ammonium nitrate oxidation of the thiocyanate ion is described. Radical addition to glycals proceeds with excellent regio- and good stereoselectivities in only one step, deprotection affords water-soluble 2-thio saccharides. Binding...

Transient Raman spectra, structure, and thermochemistry of the thiocyanate dimer radical anion in water.

The Journal of chemical physics

Janik I, Carmichael I, Tripathi GNR.
PMID: 28595392
J Chem Phys. 2017 Jun 07;146(21):214305. doi: 10.1063/1.4984267.

Time-resolved resonance-enhanced Stokes and anti-Stokes Raman spectra of the thiocyanate dimer radical anion, (SCN)

Copper-Catalyzed Cyanation of N-Tosylhydrazones with Thiocyanate Salt as the "CN" Source.

The Journal of organic chemistry

Huang Y, Yu Y, Zhu Z, Zhu C, Cen J, Li X, Wu W, Jiang H.
PMID: 28656758
J Org Chem. 2017 Jul 21;82(14):7621-7627. doi: 10.1021/acs.joc.7b00836. Epub 2017 Jul 10.

A novel protocol for the synthesis of α-aryl nitriles has been successfully achieved via a copper-catalyzed cyanation of N-tosylhydrazones employing thiocyanate as the source of cyanide. The features of this method include a convenient operation, readily available substrates, low-toxicity...

Electronic Properties and Dissociative Photoionization of Thiocyanates, Part III. The Effect of the Group's Electronegativity in the Valence and Shallow-Core (Sulfur and Chlorine 2p) Regions of CCl.

The journal of physical chemistry. A

Rodríguez Pirani LS, Della Védova CO, Geronés M, Romano RM, Cavasso-Filho R, Ge M, Ma C, Erben MF.
PMID: 29096437
J Phys Chem A. 2017 Dec 07;121(48):9201-9210. doi: 10.1021/acs.jpca.7b08395. Epub 2017 Nov 27.

Both photoelectron spectroscopy (PES) data and PhotoElectron-PhotoIon-Coincidence (PEPICO) spectra obtained from a synchrotron facility have been used to examine the electronic structure and the dissociative ionization of halomethyl thiocyantes in the valence and shallow-core S 2p and Cl 2p...

Dielectric Relaxations of (Acetamide + Electrolyte) Deep Eutectic Solvents in the Frequency Window, 0.2 ≤ ν/GHz ≤ 50: Anion and Cation Dependence.

The journal of physical chemistry. B

Mukherjee K, Das A, Choudhury S, Barman A, Biswas R.
PMID: 26012789
J Phys Chem B. 2015 Jun 25;119(25):8063-71. doi: 10.1021/acs.jpcb.5b01502. Epub 2015 Jun 08.

Dielectric relaxation (DR) measurements in the frequency range 0.2 ≤ ν/GHz ≤ 50 have been carried out for neat molten acetamide and six different (acetamide + electrolyte) deep eutectic solvents (DESs) for investigating ion effects on DR dynamics in...

Showing 1 to 12 of 1173 entries