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J Colloid Interface Sci. 2015 Jun 15;448:564-72. doi: 10.1016/j.jcis.2015.02.056. Epub 2015 Feb 28.

Hierarchical Bi based nanobundles: an excellent photocatalyst for visible-light degradation of Rhodamine B dye.

Journal of colloid and interface science

Fangfang Gao, Yan Zhao, Yawen Li, Gongjuan Wu, Yan Lu, Yuehong Song, Zhifang Huang, Na Li, Jingzhe Zhao

Affiliations

  1. College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, PR China.
  2. College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, PR China. Electronic address: [email protected].

PMID: 25792479 DOI: 10.1016/j.jcis.2015.02.056

Abstract

Hierarchical Bi based nanobundles were self-assembled via an aqueous reduction approach using hydrazine hydrate as reductive agent, and were used as photocatalysts for the degradation of Rhodamine B (RhB) under visible light. PVP molecules were designed as inducing agent to construct the Bi based nanobundles. The as-obtained samples were characterized by X-ray diffraction (XRD), energy dispersive X-ray (EDX), thermogravimetric-differential thermal analyzer (TG-DTA), infrared spectroscopy (IR) and field emission scanning electron microscopy (FESEM) to get clear information of the crystals. A possible formation mechanism for the interesting architectures was proposed in the paper. The Bi based nanobundles exhibited excellent photocatalytic activity and good cycling performance towards photodegradation of RhB under visible light. The pH-sensitive degradation can reach 96% in degradation rate after 90 min, which indicates potential applications of the Bi based nanobundles on the degradation of organic pollutants. Degradation mechanism is proposed on the combination of Bi and BiOCl crystals.

Copyright © 2015 Elsevier Inc. All rights reserved.

Keywords: Aqueous synthesis; Bi based nanobundles; Visible-light induced degradation

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